1,1,13-tridecanetricarboxylic acid | 81588-38-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,1,13-tridecanetricarboxylic acid
• 英文别名: tridecane-1,1,13-tricarboxylic acid；Tridecan-1,1,13-tricarbonsaeure
• CAS: 81588-38-7
• 化学式: C₁₆H₂₈O₆
• 分子量: 316.395
• InChiKey: CMXPNRUFNVRVFM-UHFFFAOYSA-N

物化性质

• 熔点：
  149 °C (decomp)
• 沸点：
  534.1±25.0 °C(Predicted)
• 密度：
  1.142±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,1,13-tridecanetricarboxylic acid 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Buu-Hoi; Cagniant, Bulletin de la Societe Chimique de France, 1942, vol. <5> 9, p. 99,103

  摘要：

  DOI：
• 作为产物：
  描述：

  13-溴十三烷酸 在 乙醇 、 硫酸 作用下， 生成 1,1,13-tridecanetricarboxylic acid
  参考文献：
  名称：

  Buu-Hoi; Cagniant, Bulletin de la Societe Chimique de France, 1942, vol. <5> 9, p. 99,103

  摘要：

  DOI：

文献信息

• OXIDATION OF COMPOUNDS USING GENETICALLY MODIFIED CANDIDA
  申请人：SYNTHEZYME LLC

  公开号：US20150218486A1

  公开（公告）日：2015-08-06

  An α-carboxyl-ω-hydroxyl fatty acid oxidized from a substantially pure Candida host cell, wherein the substantially pure Candida host cell is characterized by a first genetic modification class that comprises one or more genetic modifications that collectively or individually disrupt an alcohol dehydrogenase gene, and a second genetic modification class, wherein the second genetic modification class comprises an insertion of a first gene into the Candida host cell genome.

  一种从基本纯的Candida宿主细胞氧化的α-羧基-ω-羟基脂肪酸，其中基本纯的Candida宿主细胞的特征是具有第一遗传修饰类，该类包括一个或多个遗传修饰，这些修饰共同或个别地破坏了醇脱氢酶基因，以及第二遗传修饰类，其中第二遗传修饰类包括将第一基因插入到Candida宿主细胞基因组中。
• BIOTRANSFORMATION USING GENETICALLY MODIFIED CANDIDA
  申请人：Ness Jon E.

  公开号：US20150094483A1

  公开（公告）日：2015-04-02

  A substantially pure Candida host cell is provided for the biotransformation of a substrate to a product wherein the host cell is characterized by a first genetic modification class that comprises one or more genetic modifications that collectively or individually disrupt at least one alcohol dehydrogenase gene in the substantially pure Candida host cell.

  提供了一种基本纯净的Candida宿主细胞，用于将底物生物转化为产物，其中该宿主细胞的特征是具有第一遗传修饰类别，该类别包括一个或多个遗传修饰，这些修饰共同或单独破坏了至少一个酒精脱氢酶基因在基本纯净的Candida宿主细胞中。
• Zakharkin, L. I.; Guseva, V. V., Journal of Organic Chemistry USSR (English Translation), 1982, vol. 18, p. 281 - 284
  作者：Zakharkin, L. I.、Guseva, V. V.

  DOI：——

  日期：——
• ZAXARKIN, L. I.;GUSEVA, V. V., ZH. ORGAN. XIMII, 1982, 18, N 2, 326-330
  作者：ZAXARKIN, L. I.、GUSEVA, V. V.

  DOI：——

  日期：——
• BIOSYNTHETIC ROUTES TO LONG-CHAIN ALPHA,OMEGA-HYDROXYACIDS, DIACIDS AND THEIR CONVERSION TO OLIGOMERS AND POLYMERS
  申请人：Gross Richard A.

  公开号：US20100285545A1

  公开（公告）日：2010-11-11

  A substantially pure Candida host cell for the production of a α-carboxyl-ω-hydroxy fatty acid having a carbon chain length in the range from C6 to C22, a α,ω-dicarboxylic fatty acid having a carbon chain length in the range from C6 to C22, or mixtures thereof, is provided. The Candida host cell is characterized by a first genetic modification class and a second genetic modification class. The first genetic modification class comprises one or more genetic modifications that disrupt the peroxisomal β-oxidation pathway. The second genetic modification class comprises one or more genetic modifications that collectively or individually disrupt at least one gene selected from the group consisting of a CYP52A type cytochrome P450, a fatty alcohol oxidase, and an alcohol dehydrogenase.