4-[3-(4-Carbonochloridoylphenoxy)propoxy]benzoyl chloride | 69703-37-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[3-(4-Carbonochloridoylphenoxy)propoxy]benzoyl chloride
• CAS: 69703-37-3
• 化学式: C₁₇H₁₄Cl₂O₄
• 分子量: 353.202
• InChiKey: UEEUKWSLZPTQCM-UHFFFAOYSA-N

物化性质

• 沸点：
  490.3±25.0 °C(Predicted)
• 密度：
  1.319±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-[3-(4-Carbonochloridoylphenoxy)propoxy]benzoyl chloride 、 邻苯二胺 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 12.0h， 以35%的产率得到16,20-Dioxa-3,10-diazatetracyclo[19.2.2.212,15.04,9]heptacosa-1(24),4,6,8,12,14,21(25),22,26-nonaene-2,11-dione
  参考文献：
  名称：

  Synthesis, characterization and ion transportation studies of some novel cyclophane amides

  摘要：

  Various novel cyclophane amides with a large cavity have been synthesized. The structures of cyclophane amides 14 and 15 were resolved using XRD studies. Cyclophane amide 28 shows a shift in lambda(max) in the UV/Vis. spectra when treated with Cu (II) ion as well as with Ph(II) ion. Ion transportation studies were carried out with cyclophane amide 14 which proved that the Na+ ion passes through the cavity while K+ ions are retained. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.064
• 作为产物：
  描述：

  1,3-双(4-羧基苯氧基)丙烷 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 4-[3-(4-Carbonochloridoylphenoxy)propoxy]benzoyl chloride
  参考文献：
  名称：

  Synthesis, characterization and ion transportation studies of some novel cyclophane amides

  摘要：

  Various novel cyclophane amides with a large cavity have been synthesized. The structures of cyclophane amides 14 and 15 were resolved using XRD studies. Cyclophane amide 28 shows a shift in lambda(max) in the UV/Vis. spectra when treated with Cu (II) ion as well as with Ph(II) ion. Ion transportation studies were carried out with cyclophane amide 14 which proved that the Na+ ion passes through the cavity while K+ ions are retained. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.064

文献信息

• Mndshojan et al., Doklady Akademii Nauk Armyanskoi SSR, 1954, vol. 18, p. 111,115
  作者：Mndshojan et al.

  DOI：——

  日期：——
• Aguilera, C.; Ahmad, S.; Bartulin, J., Molecular Crystals and Liquid Crystals (1969-1991), 1988, vol. 162, p. 277 - 282
  作者：Aguilera, C.、Ahmad, S.、Bartulin, J.、Mueller, H. J.

  DOI：——

  日期：——
• Roetz, Uwe; Lindau, Juergen; Diele, Siegmar, Molecular Crystals and Liquid Crystals (1969-1991), 1990, vol. 193, p. 229 - 234
  作者：Roetz, Uwe、Lindau, Juergen、Diele, Siegmar、Reinhold, Guenter、Kuschel, Frank

  DOI：——

  日期：——