4-(carboxymethoxynaphthalen-1-yloxy) acetic acid | 130055-59-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(carboxymethoxynaphthalen-1-yloxy) acetic acid
• 英文别名: 1,4-naphthalene di(2-oxyacetate)；naphthalene-1,4-diyldioxy-di-acetic acid；Naphthalin-1,4-diyldioxy-di-essigsaeure；2-[4-(Carboxymethoxy)naphthalen-1-yl]oxyacetic acid；2-[4-(carboxymethoxy)naphthalen-1-yl]oxyacetic acid
• CAS: 130055-59-3
• 化学式: C₁₄H₁₂O₆
• 分子量: 276.246
• InChiKey: BDECCFNPFMMKMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-(carboxymethoxynaphthalen-1-yloxy) acetic acid 、 cadmium(II) acetate dihydrate 在 pyrazole 作用下， 以 甲醇 、 水 为溶剂， 以78%的产率得到[Cd(H2O)6][Cd3(4-carboxymethoxynaphthalen-1-yloxy)acetate)4(μ-H2O)2(H2O)2]*4H2O
  参考文献：
  名称：

  Coordination polymers of cadmium with (4-carbomethoxy-naphthalen-1-yloxy) acetic acid derivatives

  摘要：

  Three cadmium coordination polymers derived from the dianions of (4-carboxymethoxy-naphthalen-1-yloxy) acetic acid (LH2) and (4-carboxymethoxy-2,3-bis-arylsulfanyl naphthalene-1-yloxy) acetic acid (L1H2), in which the dianions of the corresponding acids act as a spacer to cadmium nodes, have been prepared and characterized. The coordination polymer of the dianion of (4-carboxy-methoxy-2,3-bis-arylsulfanylnaphthalene-1-yloxy) acetic acid with cadmium is a 3-D coordination polymer, whereas the dimensionality of the coordination polymer of the dianion of (4-carboxymethoxy-naphthalen-1-yloxy) acetic acid is dependent on the ancillary ligand. The presence of the chelating ligand 1,10-phenan-throline gave a 1-D polymer of the dicarboxylate anion L but in the absence of a chelating ligand a 2-D coordination polymer encapsulating hexa-aquacadmium(II) ions was obtained. The latter two coordination polymers show fluorescence emission in the solid state. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.034
• 作为产物：
  描述：

  1,4-二羟基萘 在 氢氧化钾 、 potassium carbonate 、 丙酮 、 potassium iodide 作用下， 生成 4-(carboxymethoxynaphthalen-1-yloxy) acetic acid
  参考文献：
  名称：

  Janczewski et al., Przemysl Chemiczny, 1958, vol. 37, p. 784,786

  摘要：

  DOI：

文献信息

• Linear to spiral coordination polymers of 1,4-naphthalene di-(2-oxyacetate) of cobalt, manganese and copper
  作者：Bigyan R. Jali、Jubaraj B. Baruah

  DOI：10.1016/j.inoche.2011.05.042

  日期：2011.9

  Different types of structure among the transition metal complexes of 1,4-naphthalene di-(2-oxyacetate) (L) are observed. Cobalt(II) 1,4-naphthalene di-(2-oxyacetate) complex is a tetranuclear complex. This tetranuclear complex is formed by interlinking two dinuclear cobalt cores having aqua and carboxylate bridges. Dinuclear cores of this complex break down on reaction with pyridine (py) molecules to

  摘要 1,4-萘二-(2-氧乙酸)(L)的过渡金属配合物之间存在不同类型的结构。Cobalt(II) 1,4-naphthalene di-(2-oxyacetate) 络合物是一种四核络合物。这种四核复合物是通过将具有水键和羧酸键的两个双核钴核相互连接而形成的。该复合物的双核核在与吡啶 (py) 分子反应时分解，形成具有单核重复单元的配位聚合物。L 的羧酸根基团之一桥接锰 (II) 1,4-萘二-(2-氧乙酸酯) 配位聚合物的两个锰离子，配体的其他羧酸根端保持未配位。制备并表征了具有[Cu(H2O)(py)2]作为连接L的单齿羧酸盐两端的连接节点的螺旋五配位羧酸盐配位聚合物。