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3'-chloro-biphenyl-3,4'-diol | 920283-79-0

中文名称
——
中文别名
——
英文名称
3'-chloro-biphenyl-3,4'-diol
英文别名
2-Chloro-4-(3-hydroxyphenyl)phenol
3'-chloro-biphenyl-3,4'-diol化学式
CAS
920283-79-0
化学式
C12H9ClO2
mdl
——
分子量
220.655
InChiKey
APYWPRBHPJTLAU-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    390.2±32.0 °C(Predicted)
  • 密度:
    1.349±0.06 g/cm3(Predicted)

计算性质

  • 辛醇/水分配系数(LogP):
    3.5
  • 重原子数:
    15
  • 可旋转键数:
    1
  • 环数:
    2.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    40.5
  • 氢给体数:
    2
  • 氢受体数:
    2

反应信息

  • 作为反应物:
    描述:
    3'-chloro-biphenyl-3,4'-diol4-二甲氨基吡啶 、 palladium 10% on activated carbon 、 氢气N,N'-二环己基碳二亚胺 作用下, 以 四氢呋喃二氯甲烷 为溶剂, 反应 22.0h, 生成 3'-chloro-3,4'-biphenyldiyl bis(4-hydroxybenzoate)
    参考文献:
    名称:
    Synthesis, Characterization, and Electro-Optic Properties of Novel Bent-Core Mesogens Based on Cinnamoyloxy Derivatives
    摘要:
    The new series of bent-core molecules based on a 3,4'-biphenyldiol central core has been synthesized. The influence of the central core as well as that of a fluorine and chlorine substituent on the diphenyl rings in the bent-core compound has also been examined. A few novel series of bent-core compounds containing cinnamoyloxy or -methylcinnamoyloxy groups in the side arms have been synthesized, and the mesophases exhibited by them have been compared. The mesophases under discussion were investigated by means of polarizing microscopy, differential scanning calorimetry, X-ray diffraction, as well as electro-optical experiments. The influence of the molecular structure on the occurrence of the SmCP phase was investigated. Finally, the electro-optical properties of the SmCP phase, such as voltage-transmittance effect, tilt angle, dielectric permittivity, and switching behavior, were also measured. As a consequence, the correlation between their electro-optical properties and chemical structures of these compounds is investigated.
    DOI:
    10.1080/15421406.2010.526563
  • 作为产物:
    参考文献:
    名称:
    宽温度范围SmCP相的含水杨基亚胺基的非手性弯曲核心液晶分子的合成与表征
    摘要:
    据报道,基于包含水杨醛亚胺基和两个末端十四烷氧基尾巴的3,4'-联苯二醇中心核,设计了一系列弯曲核材料。此外,还研究了联苯核上3'-位的侧向取代基(R = F和Cl)的作用。这些取代基在降低清除温度和增加SmCP相的温度范围方面具有重要影响。在各向同性液体冷却过程中,化合物SB-Cl的最低转变温度为180°C,最宽的SmCP相范围为129°C。通过偏光显微镜(POM),差示扫描量热法(DSC),X射线衍射(XRD)和电光(EO)测量在中间相温度范围内研究了中间相行为。
    DOI:
    10.1002/jccs.201000020
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文献信息

  • Synthesis and Characterization of Achiral Bent-Core Liquid Crystalline Molecules Containing Salicylaldimine-Based with a Wide Temperature Range of SmCP Phase
    作者:Chien-Tung Liao、Jung-Yo Liu、Sing-Fang Zou、Nien-Chieh Wu、Zheng-Long Wu、Jiunn-Yih Lee
    DOI:10.1002/jccs.201000020
    日期:2010.2
    of SmCP phase. Upon cooling process the isotropic liquid, compound SB‐Cl exhibits the lowest clearing transition temperature of 180°C and the widest SmCP phase range of 129°C. The mesophase behaviour were investigated by polarizing optical microscopy (POM), differential scanning calorimetry (DSC), X‐ray diffraction (XRD), and electro‐optical (EO) measurements in the mesophase temperature range.
    据报道,基于包含水杨醛亚胺基和两个末端十四烷氧基尾巴的3,4'-联苯二醇中心核,设计了一系列弯曲核材料。此外,还研究了联苯核上3'-位的侧向取代基(R = F和Cl)的作用。这些取代基在降低清除温度和增加SmCP相的温度范围方面具有重要影响。在各向同性液体冷却过程中,化合物SB-Cl的最低转变温度为180°C,最宽的SmCP相范围为129°C。通过偏光显微镜(POM),差示扫描量热法(DSC),X射线衍射(XRD)和电光(EO)测量在中间相温度范围内研究了中间相行为。
  • Synthesis, Characterization, and Electro-Optic Properties of Novel Bent-Core Mesogens Based on Cinnamoyloxy Derivatives
    作者:Chien-Tung Liao、Jiunn-Yih Lee、Chiu-Chun Lai
    DOI:10.1080/15421406.2010.526563
    日期:2011.1.13
    The new series of bent-core molecules based on a 3,4'-biphenyldiol central core has been synthesized. The influence of the central core as well as that of a fluorine and chlorine substituent on the diphenyl rings in the bent-core compound has also been examined. A few novel series of bent-core compounds containing cinnamoyloxy or -methylcinnamoyloxy groups in the side arms have been synthesized, and the mesophases exhibited by them have been compared. The mesophases under discussion were investigated by means of polarizing microscopy, differential scanning calorimetry, X-ray diffraction, as well as electro-optical experiments. The influence of the molecular structure on the occurrence of the SmCP phase was investigated. Finally, the electro-optical properties of the SmCP phase, such as voltage-transmittance effect, tilt angle, dielectric permittivity, and switching behavior, were also measured. As a consequence, the correlation between their electro-optical properties and chemical structures of these compounds is investigated.
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