2'-bromo-4,4"-bis(mercaptomethyl)-1,1':3',1"-terphenyl | 162971-22-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2'-bromo-4,4"-bis(mercaptomethyl)-1,1':3',1"-terphenyl
• 英文别名: [4-[2-Bromo-3-[4-(sulfanylmethyl)phenyl]phenyl]phenyl]methanethiol
• CAS: 162971-22-4
• 化学式: C₂₀H₁₇BrS₂
• 分子量: 401.391
• InChiKey: RYKIZWVELWIYOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2'-bromo-4,4"-bis(mercaptomethyl)-1,1':3',1"-terphenyl 在 sodium hydride 、 溶剂黄146 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  CN115925749

  摘要：

  公开号：
• 作为产物：
  描述：

  2'-bromo-4,4''-bis(bromomethyl)-1,1':3',1''-terphenyl 以 四氢呋喃 、 氢氧化钾 为溶剂， 反应 35.0h， 生成 2'-bromo-4,4"-bis(mercaptomethyl)-1,1':3',1"-terphenyl
  参考文献：
  名称：

  2′-Substituted meta-terphenyls as building blocks for cyclophanes with intra-annular functionality

  摘要：

  2'-Substituted m-terphenyls containing chloromethyl and/or thiomethyl groups at the 4,4'' or 3,3'' positions are used as building blocks for cyclophanes with intra-annular functionality. Syntheses are short and yields are good. The methodology, capable of wide structural variation, has been adapted to bi- and tricyclic cyclophanes.

  DOI：

  10.1016/0040-4020(94)01016-s

文献信息

• The synthesis of spirophanes from a pentaerythrityl core
  作者：Perumal Rajakumar、Karuppannan Sekar、Kannupal Srinivasan

  DOI：10.1016/j.tetlet.2005.01.085

  日期：2005.3

  Various thia- and oxa-spirobicyclic cyclophanes were synthesized from a pentaerythrityl building block and appropriate dithiols/bisphenols. (C) 2005 Elsevier Ltd. All rights reserved.
• Meta-terphenyls as building blocks for pyridinophanes
  作者：T.K. Vinod、Perumal Rajakumar、Harold Hart

  DOI：10.1016/0040-4020(94)01109-d

  日期：1995.2

  Pyridinophanes 6 and 7 were prepared in good yield from bis(thiomethyl)-m-terphenyls 2 and 12 and bis (chloromethyl) pyridine derivative 11.
• 2′-Substituted meta-terphenyls as building blocks for cyclophanes with intra-annular functionality
  作者：Harold Hart、Perumal Rajakumar

  DOI：10.1016/0040-4020(94)01016-s

  日期：1995.1

  2'-Substituted m-terphenyls containing chloromethyl and/or thiomethyl groups at the 4,4'' or 3,3'' positions are used as building blocks for cyclophanes with intra-annular functionality. Syntheses are short and yields are good. The methodology, capable of wide structural variation, has been adapted to bi- and tricyclic cyclophanes.
• CN115925749
  申请人：——

  公开号：——

  公开（公告）日：——