二甲基吩嗪-1,6-二羧酸酯 | 23531-24-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 中文名称: 二甲基吩嗪-1,6-二羧酸酯
• 英文名称: dimethyl phenazine-1,6-dicarboxylate
• 英文别名: 1,6-dicarbomethoxy-phenazine；1,6-dicarbomethoxyphenazine；phencomycin methyl ester；phenazine-1,6-dicarboxylic acid dimethyl ester；Phenazin-1,6-dicarbonsaeure-dimethylester；Phenazin-1,6-dicarbonsaeuredimethylester
• CAS: 23531-24-0
• 化学式: C₁₆H₁₂N₂O₄
• 分子量: 296.282
• InChiKey: BKKXRPZAWAUFKA-UHFFFAOYSA-N

物化性质

• 沸点：
  482.3±15.0 °C(Predicted)
• 密度：
  1.347±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  78.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  二甲基吩嗪-1,6-二羧酸酯 在 镍 氢气 作用下， 以 乙醇 为溶剂， 反应 5.0h， 生成 dimethyl 5,10-dihydrophenazine-1,6-dicarboxylate
  参考文献：
  名称：

  Buckland, Paul R.; Gulliford, Stephen P.; Herbert, Richard B., Journal of Chemical Research, Miniprint, 1981, # 12, p. 4201 - 4224

  摘要：

  DOI：
• 作为产物：
  描述：

  methyl 6-bromophenazine-1-carboxylate 在 硫酸 作用下， 以 乙醚 、 二甲基亚砜 为溶剂， 反应 3.0h， 生成 二甲基吩嗪-1,6-二羧酸酯
  参考文献：
  名称：

  Buckland, Paul R.; Gulliford, Stephen P.; Herbert, Richard B., Journal of Chemical Research, Miniprint, 1981, # 12, p. 4201 - 4224

  摘要：

  DOI：

文献信息

• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• A new route to phenazines
  作者：Takahiro Emoto、Nobuo Kubosaki、Yoshiro Yamagiwa、Tadao Kamikawa

  DOI：10.1016/s0040-4039(99)02061-4

  日期：2000.1

  Phenazines were prepared by the palladium(II)-catalyzed intramolecular amination of aryl bromides 8, which were prepared with o-bromonitrobenzenes 3 and anilines 4 or 3 and o-bromoanilines 5 using palladium(II)-catalyzed aniline arylation.

  通过钯（II）催化的芳基溴化物8的分子内胺化反应制备吩嗪，这些芳基溴化物是由邻溴代硝基苯3和苯胺4或3和邻溴代苯胺5使用钯（II）催化的苯胺芳基化反应制备的。
• Marine Bacteria. IX. Dihydrophencomycin Methyl Ester, a New Phenazine Derivative from a Marine Streptomycetet.
  作者：KLAUS PUSECKER、HARTMUT LAATSCH、ELISABETH HELMKE、HORST WEYLAND

  DOI：10.7164/antibiotics.50.479

  日期：——

  The novel 5,10-dihydrophencomycin methyl ester (4) and the known microbial metabolites (2-hydroxyphenyl)-acetamide (1), menaquinone MK9 (II, III, VIII, IX-H8) (2), and phencomycin (3a) were isolated from an unidentified marine Streptomyces sp. and the structures were elucidated by NMR methods. Compound 4 shows weak antibiotic activity against Escherichia coli and Bacillus subtilis.

  新型5,10-二氢酚霉素甲酯（4）和已知的微生物代谢物（2-羟苯基）-乙酰胺（1），甲萘醌MK9（II，III，VIII，IX-H8）（2）和酚霉素（3a）分离的身份不明的海洋链霉菌。并通过NMR方法阐明了结构。化合物4显示出对大肠杆菌和枯草芽孢杆菌的弱抗生素活性。
• AROMATIC POLYESTER
  申请人：Muroran Institute of Technology

  公开号：EP2479203A1

  公开（公告）日：2012-07-25

  The present invention provides an aromatic polyester which is substantially free from the occurrence of coloration and retains significantly high transparency even after being thermally processed at high temperature and which has high flowability. The aromatic polyester contains a polyhydric phenol residue and a residue of any one of aromatic polycarboxylic acid, halide thereof, and anhydride thereof, and terminals of the aromatic polyester have a structure represented by the formula -C(O)-R. The aromatic polyester has an end-capping rate of 90% or higher and a weight average molecular weight (Mw) ranging from 3,000 to 1,000,000.

  本发明提供了一种芳香族聚酯，该聚酯基本上不会发生着色，即使在高温热加工后仍能保持明显的高透明度，并且具有高流动性。芳香族聚酯含有多羟基苯酚残留物和芳香族多羧酸、其卤化物和其酸酐中任意一种的残留物，芳香族聚酯的端基具有式 -C(O)-R 所代表的结构。芳香族聚酯的端盖率为 90% 或更高，重量平均分子量（Mw）为 3,000 至 1,000,000 之间。
• Rosum, Ukrainskij Khimicheskij Zhurnal, 1955, vol. 21, p. 361,364
  作者：Rosum

  DOI：——

  日期：——

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