1-(2-methylpropyl)-2,3,3-trimethylindoleninium iodide | 1236035-51-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-(2-methylpropyl)-2,3,3-trimethylindoleninium iodide
• 英文别名: 2,3,3-Trimethyl-1-(2-methylpropyl)indol-1-ium;iodide
• CAS: 1236035-51-0
• 化学式: C₁₅H₂₂N*I
• 分子量: 343.251
• InChiKey: MXCXDZQKDILNEB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.74
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(2-methylpropyl)-2,3,3-trimethylindoleninium iodide 在 potassium hydroxide 作用下， 以 水 为溶剂， 反应 0.5h， 以1.28 g的产率得到1-isobutyl-3,3-dimethyl-2-methyleneindoline
  参考文献：
  名称：

  Synthesis of Green Colored Photochromic 6′-Arylamino Spiro [2H]Naphth[1,2-b]oxazines

  摘要：

  The published route to a series of 6'-arylamino substituted photochromic spirooxazines has been investigated with improvements made to perform the synthesis in satisfactory yield. The route has been exemplified with several novel derivatives prepared (including hydroxyl functionalised). Additionally, a one-pot procedure for the conversion of suitably functionalized 1,2-naphthoquinones into the photochromic compounds is reported.

  DOI：

  10.1080/00397910903457423
• 作为产物：
  描述：

  2,3,3-三甲基-3H-吲哚 、 碘代异丁烷 以 正丁醇 为溶剂， 生成 1-(2-methylpropyl)-2,3,3-trimethylindoleninium iodide
  参考文献：
  名称：

  1-N-alkyl-5'-[(N'-(un)substituted)amido]spiroindolinonaphthoxazines, their preparation, compositions and (co)polymer matrices containing them

  摘要：

  本发明的目的是新型的螺合吲哚萘氧嗪化合物，以及含有它们的组合物和（共）聚合物基质。所述化合物具有有趣的光致变色性能。本发明的另一个目的是一种制备上述新型化合物的方法。

  公开号：

  EP1044978A3

文献信息

• Photo- and thermochromic spirans 37.* New symmetrical bisspiropyrans of the indoline series
  作者：N. A. Voloshin、E. V. Solov’eva、S. O. Bezugliy、A. V. Metelitsa、V. I. Minkin

  DOI：10.1007/s10593-012-1145-5

  日期：2012.12

  New symmetrical bisspiropyrans of the indoline series, which have photochromic properties and are characterized by substantially higher absorption capacity of cyclic isomers in comparison to the monospiropyrans, were obtained on the basis of 4,6-dihydroxy-5-methylisophthalaldehyde.

  在4，6-二羟基-5-甲基间苯二甲醛的基础上，获得了新的吲哚啉系列对称双螺并吡喃，其具有光致变色特性，并且与单螺并吡喃相比，具有环状异构体的吸收能力高得多的特征。
• Spiropyrans and spirooxazines 5. Synthesis of photochromic 8-(4,5-diphenyl-1,3-oxazol-2-y1)-substituted spiro[indoline-benzopyrans]
  作者：N. A. Voloshin、E. B. Gaeva、A. V. Chernyshev、A. V. Metelitsa、V. I. Minkin

  DOI：10.1007/s11172-009-0024-4

  日期：2009.1

  Photochromic spiro[indoline-benzopyrans] containing 4,5-diphenyloxazolyl group at position 8 of the benzopyran fragment have been obtained. New diphenyloxazolyl-substituted spiropyrans manifest considerably higher thermal stability of the merocyanine isomers than their naphthopyran analogs.

  在苯并吡喃片段的第 8 位含有 4,5-二苯基恶唑基团的光致变色螺[吲哚啉-苯并吡喃]已经问世。与萘吡喃类似物相比，新的二苯基恶唑基取代的螺[吲哚啉-苯并吡喃]表现出更高的美拉德异构体热稳定性。
• Spiropyrans and spirooxazines 8. 5′-(1,3-Benzothiazol-2-yl)-substituted spiro[indoline-2,3′-naphthopyrans]: synthesis and spectral and photochromic properties
  作者：N. A. Voloshin、A. V. Chernyshev、A. V. Metelitsa、E. B. Gaeva、V. I. Minkin

  DOI：10.1007/s11172-011-0289-2

  日期：2011.9

  Novel photochromic 5′-(1,3-benzothiazol-2-yl)-substituted spiro[indoline-2,3′-naphthopyrans] possessing luminescence properties in both the cyclic and merocyanine forms were synthesized. Unlike the 8′-(1,3-benzothiazol-2-yl)-substituted benzopyran analogs, the synthesized compounds are characterized by the lower relative stability of the merocyanine isomers.

  合成了新型光致变色的 5′-(1,3-苯并噻唑-2-基)取代螺[吲哚啉-2,3′-萘并吡喃]，其环状和经花青素形式均具有发光特性。与 8′-(1,3-苯并噻唑-2-基)取代的苯并吡喃类似物不同，所合成的化合物的特点是经花青素异构体的相对稳定性较低。
• Photochromic and thermochromic spiranes. 34.* synthesis of photochromic 5-(4,5-diphenyl-1,3-oxazol-2-yl)-substituted spirobenzochromeneindolines
  作者：N. A. Voloshin、A. V. Chernyshev、A. V. Metelitsa、V. I. Minkin

  DOI：10.1007/s10593-011-0848-3

  日期：2011.10

  A simple and effective method is proposed for the synthesis of 4,5-diphenyloxazolyl-substituted o-hydroxynaphthaldehydes. Photochromic spirobenzochromeneindolines containing a 4,5-diphenyl-oxazole group at position 5 of the benzochromene fragment were obtained. In the cyclic form the new (diphenyloxazolyl)-substituted spiropyrans exhibit luminescent properties.