Hg(C6H2(OCH3)2-2,3-CH2NMe2-6)2 | 167031-66-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Hg(C6H2(OCH3)2-2,3-CH2NMe2-6)2
• CAS: 167031-66-5
• 化学式: C₂₂H₃₂HgN₂O₄
• 分子量: 589.097
• InChiKey: IQNLUJVETDAIFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [((η(5)-C5H5)Mo(μ-I)(I)(NO))2] 、 Hg(C6H2(OCH3)2-2,3-CH2NMe2-6)2 以 二氯甲烷 为溶剂， 以15%的产率得到[(η(5)-C5H5)Mo(C6H2(OCH3)2-2,3-CH2NMe2-6)(I)(NO)]-0.5CH2Cl2
  参考文献：
  名称：

  Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]

  摘要：

  The reaction of {(eta(5)-C5H5)Mo(mu-I)(I)(NO)}(2)] with the Hg derivatives of substituted N,N-dimethylbenzylamines [Hg(Q dmba)(2)] (HQ = substituted N,N-dimethylbenzylamine affords the organomolybdenum complexes [(eta(5)-C5H5)Mo(Qdmba)(I)(NO)] (2a-2e) in nearly quantitative yield as a racemic mixture of both enantiomers. When the reaction is carried out with Hg{S-C6H4C(H)(Me)NMe(2)}(2), a 1:1 mixture of both diastereoisomers [(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f-2g) is obtained. The resolution of this mixture can be accomplished by fractional crystallization in CH2Cl2/hexane. The X-ray crystal structure of the complexes (SPY-5-15-A,C)-[(eta(5)-C5H5)Mo{C6H2-(OCH2O)-2,3-CH(2)NMe(2)-6}(I)(NO)] (2b) and (SPY-5-15-C)-[(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f) are reported.

  DOI：

  10.1016/0022-328x(95)05429-s
• 作为产物：
  描述：

  N,N-dimethyl-3,4-dimethoxybenzylamine 、 mercury dichloride 在 BuLi 作用下， 以 乙醚 为溶剂， 生成 Hg(C6H2(OCH3)2-2,3-CH2NMe2-6)2
  参考文献：
  名称：

  Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]

  摘要：

  The reaction of {(eta(5)-C5H5)Mo(mu-I)(I)(NO)}(2)] with the Hg derivatives of substituted N,N-dimethylbenzylamines [Hg(Q dmba)(2)] (HQ = substituted N,N-dimethylbenzylamine affords the organomolybdenum complexes [(eta(5)-C5H5)Mo(Qdmba)(I)(NO)] (2a-2e) in nearly quantitative yield as a racemic mixture of both enantiomers. When the reaction is carried out with Hg{S-C6H4C(H)(Me)NMe(2)}(2), a 1:1 mixture of both diastereoisomers [(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f-2g) is obtained. The resolution of this mixture can be accomplished by fractional crystallization in CH2Cl2/hexane. The X-ray crystal structure of the complexes (SPY-5-15-A,C)-[(eta(5)-C5H5)Mo{C6H2-(OCH2O)-2,3-CH(2)NMe(2)-6}(I)(NO)] (2b) and (SPY-5-15-C)-[(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f) are reported.

  DOI：

  10.1016/0022-328x(95)05429-s