4-(anthracen-9-ylmethyl)morpholin-2-one | 1253424-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4-(anthracen-9-ylmethyl)morpholin-2-one
• 英文别名: 4-(Anthracen-9-ylmethyl)morpholin-2-one
• CAS: 1253424-09-7
• 化学式: C₁₉H₁₇NO₂
• 分子量: 291.349
• InChiKey: XMHIVTVDXYVUMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (1H-苯并咪唑-2-亚甲基)胺 、 4-(anthracen-9-ylmethyl)morpholin-2-one 以 四氢呋喃 为溶剂， 反应 4.0h， 以90%的产率得到N-((1H-benzo[d]imidazol-2-yl)methyl)-2-((anthracen-9-ylmethyl)(2-hydroxyethyl)amino)acetamide
  参考文献：
  名称：

  Selective sensing of Cu (II) by a simple anthracene-based tripodal chemosensor

  摘要：

  A new and an easy-to-make simple tripodal shaped chemosensor 1 has been designed and synthesised for metal ions. In CH3CN containing 0.04% DMSO, upon excitation at 370nm, chemosensor 1 exhibited structured emission centred at 418nm, which increased to a significant extent upon complexation of Cu (II). The other metal ions except Zn2+ and Hg2+ examined in this study did not exhibit any marked change in emission of 1 under a similar condition. Although Cu2+ ion showed strong interaction with 1, Zn2+ and Hg2+ ions exhibited moderate binding.

  DOI：

  10.1080/10610278.2010.544735
• 作为产物：
  描述：

  9-蒽甲醛 在 sodium tetrahydroborate 、 potassium carbonate 作用下， 以 甲醇 、 丙酮 为溶剂， 反应 19.0h， 生成 4-(anthracen-9-ylmethyl)morpholin-2-one
  参考文献：
  名称：

  Selective sensing of Cu (II) by a simple anthracene-based tripodal chemosensor

  摘要：

  A new and an easy-to-make simple tripodal shaped chemosensor 1 has been designed and synthesised for metal ions. In CH3CN containing 0.04% DMSO, upon excitation at 370nm, chemosensor 1 exhibited structured emission centred at 418nm, which increased to a significant extent upon complexation of Cu (II). The other metal ions except Zn2+ and Hg2+ examined in this study did not exhibit any marked change in emission of 1 under a similar condition. Although Cu2+ ion showed strong interaction with 1, Zn2+ and Hg2+ ions exhibited moderate binding.

  DOI：

  10.1080/10610278.2010.544735

文献信息

• Selective sensing of Zn(II) ion by a simple anthracene-based tripodal chemosensor
  作者：Kumaresh Ghosh、Indrajit Saha

  DOI：10.1016/j.tetlet.2010.07.070

  日期：2010.9

  A new and an easy-to-make simple tripodal shaped chemosensor 1, comprising an anthracene moiety as a fluorophore and amide, alcohol functionalities as ligating groups has been designed and synthesized for Zn(II). In CH3CN containing 0.1% DMSO, upon excitation at 370 nm, the chemosensor 1 exhibited an emission at 412 nm, which increased to a large extent upon complexation of Zn(II). Among the other metal ions examined in the study, Cd2+ moderately perturbed the emission of 1 under similar conditions. (C) 2010 Elsevier Ltd. All rights reserved.
• Selective sensing of Cu (II) by a simple anthracene-based tripodal chemosensor
  作者：Kumaresh Ghosh、Tanmay Sarkar

  DOI：10.1080/10610278.2010.544735

  日期：2011.6.1

  A new and an easy-to-make simple tripodal shaped chemosensor 1 has been designed and synthesised for metal ions. In CH3CN containing 0.04% DMSO, upon excitation at 370nm, chemosensor 1 exhibited structured emission centred at 418nm, which increased to a significant extent upon complexation of Cu (II). The other metal ions except Zn2+ and Hg2+ examined in this study did not exhibit any marked change in emission of 1 under a similar condition. Although Cu2+ ion showed strong interaction with 1, Zn2+ and Hg2+ ions exhibited moderate binding.