11H-茚并[2,1-f]喹啉 | 238-88-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 中文名称: 11H-茚并[2,1-f]喹啉
• 英文名称: 11H-indeno[2,1-f]quinoline
• 英文别名: 11H-Indeno[2,1-f]chinolin；11H-Indeno[2,1-f]quinoline
• CAS: 238-88-0
• 化学式: C₁₆H₁₁N
• 分子量: 217.27
• InChiKey: PHKJFMDISHEWEY-UHFFFAOYSA-N

物化性质

• 沸点：
  410.6±14.0 °C(Predicted)
• 密度：
  1.236±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-菲基胺 在 chromium(VI) oxide 、 氢氧化钾 、 sodium hydroxide 、 硫酸 、 水 、 一水合肼 、 iron(II) sulfate 、 溶剂黄146 、 硝基苯 、 1,3-丙二醇 作用下， 生成 11H-茚并[2,1-f]喹啉
  参考文献：
  名称：

  36.茚并喹啉的合成

  摘要：

  DOI：

  10.1039/jr9570000207

文献信息

• A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes
  作者：Wai Chung Fu、Fuk Yee Kwong

  DOI：10.1039/c9sc04062e

  日期：——

  cascade for the modular and regioselective synthesis of polysubstituted fluorenes. Hydrazone facilitates the Pd(II) to Pd(IV) oxidative addition in a Catellani pathway and is also the methylene synthon in the proposed reaction. Aryl iodides and 2-bromoarylaldehyde hydrazones undergo a norbornene-controlled tandem reaction sequence to give a broad scope of fluorenes in the presence of a palladium catalyst

  我们在此报道了用于多取代芴的模块化和区域选择性合成的脱氮钯催化的级联反应。dra可促进Catellani途径中的Pd（II）到Pd（IV）氧化加成反应，并且也是拟议反应中的亚甲基合成子。在钯催化剂的存在下，芳基碘化物和2-溴芳基醛经历降冰片烯控制的串联反应序列，从而得到宽范围的芴。所描述的方法是可扩展的并且适用于with基团的原位生成的三组分反应。已经进行了初步的机械研究。
• Steroid receptor modulator compounds and methods
  申请人：——

  公开号：US20040186132A1

  公开（公告）日：2004-09-23

  Non-steroidal compounds which are high affinity, high selectivity modulators for steroid receptors are disclosed. Also disclosed are pharmaceutical compositions incorporating such compounds, methods for employing the disclosed compounds and compositions for treating patients requiring steroid receptor agonist or antagonist therapy, intermediates useful in the preparation of the compounds and processes for the preparation of the steroid receptor modulator compounds.

  本文披露了高亲和力、高选择性的非类固醇化合物，可作为类固醇受体调节剂。同时也披露了包含这些化合物的药物组合物，以及使用这些化合物和组合物治疗需要类固醇受体激动剂或拮抗剂治疗的患者的方法，还包括制备这些化合物的中间体和制备类固醇受体调节剂化合物的方法。
• Methods for the preparation of coumarine derivatives
  申请人：LIGAND PHARMACEUTICALS INCORPORATED

  公开号：EP1041071A1

  公开（公告）日：2000-10-04

  Non-steroidal compounds which are high affinity, high selectivity modulators for steroid receptors are disclosed. Also disclosed are pharmaceutical compositions incorporating such compounds, methods for employing the disclosed compounds and compositions for treating patients requiring steroid receptor agonist or antagonist therapy, intermediates useful in the preparation of the compounds and processes for the preparation of the steroid receptor modulator compounds.

  本发明公开了对类固醇受体具有高亲和力、高选择性调节作用的非类固醇化合物。还公开了含有此类化合物的药物组合物、使用所公开化合物和组合物治疗需要类固醇受体激动剂或拮抗剂治疗的患者的方法、制备化合物时有用的中间体以及制备类固醇受体调节剂化合物的工艺。
• INK COMPOSITION FOR ORGANIC LIGHT-EMITTING ELEMENT, AND ORGANIC LIGHT-EMITTING ELEMENT USING SAME
  申请人：DIC Corporation

  公开号：EP3232486A1

  公开（公告）日：2017-10-18

  From a viewpoint of achieving a high-performance organic light-emitting element, ensuring a certain degree of flatness in a coating film obtained by a wet film forming method may not be sufficient. As a result, a desired performance of an organic light-emitting element to be obtained, may not be obtained. Therefore, an object of the present invention is to provide an ink composition for an organic light-emitting element, which can prevent the generation of waviness. There is provided an ink composition for an organic light-emitting element, including: an organic light-emitting element material; a leveling agent; and a solvent, in which the leveling agent is a block copolymer formed by performing copolymerization of at least a siloxane monomer and a hydrophobic monomer.

  从实现高性能有机发光元件的角度来看，确保通过湿膜形成方法获得的涂膜具有一定程度的平整度可能是不够的。因此，可能无法获得所需的有机发光元件性能。因此，本发明的目的是提供一种用于有机发光元件的油墨组合物，它可以防止产生波浪状。本发明提供了一种用于有机发光元件的油墨组合物，包括：有机发光元件材料；匀染剂；和溶剂，其中匀染剂是至少由硅氧烷单体和疏水性单体共聚而成的嵌段共聚物。
• INK COMPOSITION FOR ORGANIC LIGHT EMITTING DEVICE, AND ORGANIC LIGHT EMITTING ELEMENT
  申请人：DIC Corporation

  公开号：EP3261144A1

  公开（公告）日：2017-12-27

  There is provided an ink composition for an organic light-emitting device which can easily form a light-emitting layer having more excellent uniformity and which is suitable for forming a light-emitting layer by a wet method. An ink composition for an organic light-emitting device includes a light-emitting material, a binder resin, and a solvent, the binder resin containing a multi-branched copolymer of a monovinyl compound composed of a styrene-based monomer as an essential component with a multifunctional vinyl compound containing two or more ethylenically unsaturated double bonds, and the copolymer having a weight-average absolute molecular weight within a range of 200,000 to 800,000 determined by gel permeation chromatography using a multi-angle laser light scattering detector and a degree of branching within a range of 0.20 to 0.55 determined from an inertial radius. An organic light-emitting device includes a positive electrode, a light-emitting layer, and a negative electrode, the light-emitting layer containing the binder resin.

  本发明提供了一种用于有机发光器件的油墨组合物，该组合物可轻松形成具有更佳均匀性的发光层，并且适用于通过湿法形成发光层。一种用于有机发光器件的油墨组合物包括发光材料、粘合剂树脂和溶剂，粘合剂树脂含有单乙烯基化合物的多支链共聚物，该共聚物由苯乙烯基单体作为基本成分与含有两个或两个以上乙烯基不饱和双键的多功能乙烯基化合物组成、该共聚物通过使用多角度激光光散射检测器的凝胶渗透色谱法测定，其重量平均绝对分子量在 200,000 至 800,000 之间，支化度在 0.20 至 0.55 之间。20至0.55的范围内。有机发光器件包括正极、发光层和负极，发光层含有粘结树脂。