dichlorotris(trimethylphosphine)cobalt | 59400-70-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: dichlorotris(trimethylphosphine)cobalt
• 英文别名: dichlorocobalt;trimethylphosphane
• CAS: 59400-70-3
• 化学式: C₉H₂₇Cl₂CoP₃
• 分子量: 358.134
• InChiKey: RVYJHLFIBRHACZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.45
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  ethene tris(trimethylphospine)cobalt 、 dichlorotris(trimethylphosphine)cobalt 以 四氢呋喃 为溶剂， 以95%的产率得到chlorotris(trimethylphosphane)cobalt(I)
  参考文献：
  名称：

  Klein, Hans-Friedrich; Helwig, Michael; Karnop, Michael, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1993, vol. 48, # 6, p. 785 - 793

  摘要：

  DOI：

文献信息

• Reduction of 2-nitrophenols by low-valent trimethylphosphine complexes of cobalt
  作者：Hans-Friedrich Klein、Andreas Schmidt、Ulrich Flörke、Hans-Jürgen Haupt

  DOI：10.1016/s0020-1693(02)01144-1

  日期：2003.1

  6 H 3 R 4 R 6 (NO 2 )OH] react with Co(PMe 3 ) 4 to afford 2-nitrosophenolatocobalt (I) compounds Co[η 2 - N , O ][C 6 H 2 R 4 R 6 (NO)O](PMe 3 ) 3 ( 1 : R 4 =R 6 =H; 2 : R 4 =Me, R 6 =CMe 3 ). In the molecular structure of 2 the cobalt atom is centered in a trigonalbipyramid of axial O , P and equatorial N , P 2 donor atoms, whereas an isosteric molecule Ni[η 2 - C , O ][C 6 H 2 R 4 R 6 (CO)O](PMe

  2-硝基苯酚[C 6 H 3 R 4 R 6（NO 2）OH]与Co（PMe 3）4反应得到2-亚硝基苯酚钴（I）化合物Co [η2-N，O] [C 6 H 2 R 4 R 6（NO）O]（PMe 3）3（1：R 4 ＝ R 6 ＝ H； 2：R 4 ＝ Me，R 6 ＝ CMe 3）。在2的分子结构中，钴原子位于轴向O，P和赤道N，P 2供体原子的三角双锥体中，而等排分子Ni [η2-C，O] [C 6 H 2 R 4 R 6含有轴向C，P和赤道O，P 2供体原子的（CO）O]（PMe 3）3（2C：R 4 ＝ Me，R 6 ＝ CMe 3）在不同的空间群中结晶。由2-硝基萘酚-1或2-硝基sonaphthol-1与Co（PMe 3）4形成亚硝基钴（I）络合物Co [η2-N，O] [C 10 H 6（NO）O]（PMe 3）3（ 3）。2-Nitronaphthol-1与过量的Co（PMe
• Klein, Hans-Friedrich; Ellrich, Klaus; Lamac, Susanne, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985, vol. 40, # 10, p. 1377 - 1382
  作者：Klein, Hans-Friedrich、Ellrich, Klaus、Lamac, Susanne、Lull, Goetz、Zsolnai, Laszlo、Huttner, Gottfried

  DOI：——

  日期：——
• Synthesis and crystal structures of η²-sulfenamido complexes of ruthenium and nickel, and of chromium imido and cobalt iminophosphorane complexes via sulfenamido rearrangement
  作者：Danielle M. Hankin、Andreas A. Danopoulos、Geoffrey Wilkinson、Tracy K. N. Sweet、Michael B. Hursthouse

  DOI：10.1039/dt9960004063

  日期：——

  The interaction of [Ru(eta-C(5)Me(5))Cl-2](2) with Li(Bu(t)NSPh), gave two products, Ru(eta(4)-C(5)Me(4)CH(2))(eta(2)-Bu(t)NSPh)Cl 1 and the dimer Cl(eta-C(5)Me(5))Ru(mu-NBu(t))(mu-SPh)Ru(eta-C(5)Me(5)) 2; the former is best described as a eta(4)-tetramethylfulvene ruthenium(II) complex, while in the latter the bridging tert-butylimido and benzene-thiolato groups were formed by S-N cleavage of sulfenamido species. A similar cleavage resulted in the formation of Cr-V(eta-C(5)Me(5))(NBu(t))(SPh)(2) 3, in the interaction of Li(Bu(t)NSPh) with [Cr(eta-C(5)Me(5))Br-2](2). Interaction of CoCl2(PMe(3))(3) with Li(p-MeC(6)H(4)NSPh) gave the iminophosphorane complex Co(p-MeC(6)H(4)NPMe(3))(2)(SPh)(2) 4. Interaction of NiCl2(PMe(3))(2) with Li(Bu(t)NSPh) gave Ni(eta(2)-Bu(t)NSPh)(2)(PMe(3)) 5. The structures of compounds 1-5 have been confirmed by X-ray crystallography.
• Karsch, Hans H.; Milewski-Mahrla, Beatrix; Besenhard, Jürgen O., Inorganic Chemistry, 1986, vol. 25, # 21, p. 3811 - 3821
  作者：Karsch, Hans H.、Milewski-Mahrla, Beatrix、Besenhard, Jürgen O.、Hofmann, Peter、Stauffert, Peter、Albright, Thomas A.

  DOI：——

  日期：——
• Alnagi, Omar; Zinoune, Mohamed; Gleizes, Alain, Nouveau Journal de Chimie, 1980, vol. 4, p. 707 - 710
  作者：Alnagi, Omar、Zinoune, Mohamed、Gleizes, Alain、Dartiguenave, Michele、Dartiguenave, Yves

  DOI：——

  日期：——