n-hexyl-2-methylbut-2-enylsulfide | 175603-24-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: n-hexyl-2-methylbut-2-enylsulfide
• 英文别名: 1-(3-Methylbut-2-enylsulfanyl)hexane
• CAS: 175603-24-4
• 化学式: C₁₁H₂₂S
• 分子量: 186.362
• InChiKey: OLPSWZVCCTYCQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  n-hexyl-2-methylbut-2-enylsulfide 在 (1+)*CH3COO(1-) 氢气 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 80.0 ℃ 、405.3 kPa 条件下， 反应 2.0h， 以35%的产率得到N-(2-isopentylthioethyl)butane
  参考文献：
  名称：

  Low Pressure Hydrogenation of Unsaturated Sulphides with Homogeneous and Heterogeneous Ruthenium Catalysts

  摘要：

  Ru2O . nH(2)O and [Ru3O(AcO)(6)(H2O)(3)](AcO-)-Ac-+ were examined for catalytic activity in the hydrogenation of a series of unsaturated sulphides under heterogeneous and homogeneous conditions, respectively. By the appropriate combination of these two methodologies, a number of saturated sulphides could be synthesized in satisfactory to good yields, thus minimizing side reactions.

  DOI：

  10.1080/00397919608003694
• 作为产物：
  描述：

  n-hexyl(vinyl)sulfide 在 ruthenium(IV) oxide 乙醇 、 氢气 、 sodium 作用下， 以 甲醇 为溶剂， 25.0~60.0 ℃ 、810.6 kPa 条件下， 反应 48.0h， 生成 n-hexyl-2-methylbut-2-enylsulfide
  参考文献：
  名称：

  Low Pressure Hydrogenation of Unsaturated Sulphides with Homogeneous and Heterogeneous Ruthenium Catalysts

  摘要：

  Ru2O . nH(2)O and [Ru3O(AcO)(6)(H2O)(3)](AcO-)-Ac-+ were examined for catalytic activity in the hydrogenation of a series of unsaturated sulphides under heterogeneous and homogeneous conditions, respectively. By the appropriate combination of these two methodologies, a number of saturated sulphides could be synthesized in satisfactory to good yields, thus minimizing side reactions.

  DOI：

  10.1080/00397919608003694

文献信息

• Catalytic Activation of Diazo Compounds Using Electron-Rich, Defined Iron Complexes for Carbene-Transfer Reactions
  作者：Michael S. Holzwarth、Isabel Alt、Bernd Plietker

  DOI：10.1002/anie.201201409

  日期：2012.5.29

  transfer: The electron‐rich iron complex Bu4N[Fe(CO)3(NO)] efficiently catalyzes different carbene‐transfer reactions. Various diazo compounds can be used. The high stability of the employed iron complexes is demonstrated by the generation of the diazo reagent in situ and a sequential iron‐catalyzed allylic sulfenylation/Doyle–Kirmse reaction.

  碳转移：富电子的铁络合物Bu 4 N [Fe（CO）3（NO）]有效催化不同的卡宾转移反应。可以使用各种重氮化合物。重氮试剂的原位生成和连续的铁催化的烯丙基亚磺酰化/道尔-柯尔姆斯反应证明了所用铁配合物的高稳定性。
• Low Pressure Hydrogenation of Unsaturated Sulphides with Homogeneous and Heterogeneous Ruthenium Catalysts
  作者：Vanda Cerè、Franco Massaccesi、Salvatore Pollicino、Alfredo Ricci

  DOI：10.1080/00397919608003694

  日期：1996.3

  Ru2O . nH(2)O and [Ru3O(AcO)(6)(H2O)(3)](AcO-)-Ac-+ were examined for catalytic activity in the hydrogenation of a series of unsaturated sulphides under heterogeneous and homogeneous conditions, respectively. By the appropriate combination of these two methodologies, a number of saturated sulphides could be synthesized in satisfactory to good yields, thus minimizing side reactions.