2-o-tolylsulfanyl-ethanol | 13290-18-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-o-tolylsulfanyl-ethanol
• 英文别名: 2-o-Tolylmercapto-aethanol；2-<2-Hydroxy-ethylmercapto>-toluol；2-o-Tolylthio-ethanol；2-[(2-Methylphenyl)thio]ethanol；2-(2-methylphenyl)sulfanylethanol
• CAS: 13290-18-1
• 化学式: C₉H₁₂OS
• 分子量: 168.26
• InChiKey: XKFXYEGHYIEBPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-o-tolylsulfanyl-ethanol 在 吡啶 、 氢氧化钾 、 氯化亚砜 作用下， 生成 2-methylphenyl vinyl sulfide
  参考文献：
  名称：

  Angeletti et al., Gazzetta Chimica Italiana, 1957, vol. 87, p. 1115,1122

  摘要：

  DOI：
• 作为产物：
  描述：

  2-溴甲苯 、 2-巯基乙醇 在 nickel dibromide poly(ethylene glycol) 400 、 sodium hydroxide 、 锌 作用下， 反应 11.0h， 以81%的产率得到2-o-tolylsulfanyl-ethanol
  参考文献：
  名称：

  无溶剂PEG400和镍催化芳基硫化物的简便制备

  摘要：

  摘要 以芳基溴化物与硫醇为原料，以PEG400和镍为催化剂，在碱性条件下，无溶剂合成了多种芳基硫化物。本文报道了一种简单方便的形成芳硫键的方法。

  DOI：

  10.1080/00397910801914111

文献信息

• [EN] COMPOSITION FOR TIN-SILVER ALLOY ELECTROPLATING COMPRISING A COMPLEXING AGENT<br/>[FR] COMPOSITION POUR L'ÉLECTROGALVANISATION D'ALLIAGE D'ÉTAIN ET D'ARGENT COMPRENANT UN AGENT COMPLEXANT
  申请人：BASF SE

  公开号：WO2021052817A1

  公开（公告）日：2021-03-25

  An aqueous composition comprising (a) metal ions comprising or consisting of tin ions and silver ions and (b) at least one complexing agent of formula (C11): RC12-XC11-RC11 and their salts, wherein XC11 is selected from (a) a divalent 5 or 6 membered aromatic N-heterocyclic group comprising (i) a single N atom; or (ii) a first N atom and a second heteroatom selected from N and S, wherein the first N atom and the second heteroatom are separated by at least one C atom; or (iii) a triazole or thiadiazole; (b) a divalent 6 membered aromatic carbocyclic group; (c) a divalent 5 or 6 membered aliphatic N-heterocyclic group comprising one N atom and optionally a second heteroatom selected from N and O; all of which may be unsubstituted or substituted by one or more OH or one or more RC14; RC11 is selected from (a) -XC12-S [-XC13-DC11]n-RC13, (b), and (c); RC12 is selected from RC11, XC11-RC11, H, OH, NRC14 2, C1 to C10 alkyl, and C1 to C10 alkoxy; XC12 is a chemical bond or a linear, branched or cyclic C1-C6 alkanediyl, which may be unsubstituted or substituted by OH, with the proviso that if XC11 is (a) a divalent 5 or 6 membered aromatic N-heterocyclic group and (b) RC13 is substituted by one OH and (c) RC12 is not RC11, then XC12 is a chemical bond; XC13 is a linear, branched or cyclic C1-C6 alkanediyl, which may be unsubstituted or substituted by OH; XC14 is a chemical bond or a linear or branched C1-C4 alkanediyl; DC11 is selected from S and O; RC13 is selected from (a) a linear, branched or cyclic C1-C6 alkyl, which may be unsubstituted or substituted by one or more OH, (b) if XC11 is not an aromatic carbocyclic group, Ph, XC14- Ph, with Ph=phenyl, and (c) a C2 to C4 polyoxyalkylene group; with the proviso that if XC11 is a divalent 5 or 6 membered aromatic N-heterocyclic group, then RC13 is unsubstituted or substituted by one OH with the exception that if XC11 is a divalent 5 or 6 membered aromatic N-heterocyclic group comprising a first N atom and a second heteroatom selected from N, then RC13 is unsubstituted. RC14 is selected from H and a linear, branched or cyclic C1-C6 alkyl; n is 0 or an integer of from 1 to 5.
• Angeletti et al., Gazzetta Chimica Italiana, 1957, vol. 87, p. 1115,1122
  作者：Angeletti et al.

  DOI：——

  日期：——
• Facile Preparation of Aryl Sulfides Catalyzed by PEG400 and Nickel without Solvent
  作者：Yu‐Qing Cao、Zhan Zhang、Yan‐Xin Guo、Guo‐Qiang Wu

  DOI：10.1080/00397910801914111

  日期：2008.4

  Abstract A variety of aryl sulfides were synthesized by aryl bromides with thiols, with PEG400 and nickel as catalysts under basic conditions in the absence of solvents. This article reported an easy and convenient method for formation of aryl‐sulfur bonds.

  摘要 以芳基溴化物与硫醇为原料，以PEG400和镍为催化剂，在碱性条件下，无溶剂合成了多种芳基硫化物。本文报道了一种简单方便的形成芳硫键的方法。