Tri-(5-methyl-3-thienyl)-phosphin | 30537-01-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: Tri-(5-methyl-3-thienyl)-phosphin
• 英文别名: Tri(5-methyl-3-thienyl)-phosphine；tris(5-methylthiophen-3-yl)phosphane
• CAS: 30537-01-0
• 化学式: C₁₅H₁₅PS₃
• 分子量: 322.456
• InChiKey: XJMRSMZLPBIJPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Tri-(5-methyl-3-thienyl)-phosphin 在 亚磷酸三苯酯 、 正丁基锂 、 双氧水 作用下， 以 丙酮 为溶剂， 生成 2,6,12-trimethyl-8,4-[2,3]thiopheno[1,4]diphosphinino[2,3-b:6,5-b']dithiophene 4-oxide
  参考文献：
  名称：

  4,8-Diphosphathiophenetriptycenes

  摘要：

  Unsubstituted and trimethyl-4,8-diphosphathiophenetriptycenes (4 and 3d) were synthesized by reduction of the corresponding phosphine oxides (8a and 8b) with trichlorosilane which were prepared by the reaction of trilithium salts, derived from tri-3-thienylphosphine oxides (7a and 7b), with P(OPh)(3). The reaction of 3d with W(CO)(5)(THF) gave a 1:2 complex 12 in high yield.

  DOI：

  10.1016/s0040-4039(00)61405-3
• 作为产物：
  描述：

  4-溴-2-甲基噻吩 在 亚磷酸三苯酯 、 仲丁基锂 作用下， 生成 Tri-(5-methyl-3-thienyl)-phosphin
  参考文献：
  名称：

  4,8-Diphosphathiophenetriptycenes

  摘要：

  Unsubstituted and trimethyl-4,8-diphosphathiophenetriptycenes (4 and 3d) were synthesized by reduction of the corresponding phosphine oxides (8a and 8b) with trichlorosilane which were prepared by the reaction of trilithium salts, derived from tri-3-thienylphosphine oxides (7a and 7b), with P(OPh)(3). The reaction of 3d with W(CO)(5)(THF) gave a 1:2 complex 12 in high yield.

  DOI：

  10.1016/s0040-4039(00)61405-3

文献信息

• 4,8-Diphosphathiophenetriptycenes
  作者：Akihiko Ishii、Rie Yoshioka、Juzo Nakayama、Masamatsu Hoshino

  DOI：10.1016/s0040-4039(00)61405-3

  日期：1993.12

  Unsubstituted and trimethyl-4,8-diphosphathiophenetriptycenes (4 and 3d) were synthesized by reduction of the corresponding phosphine oxides (8a and 8b) with trichlorosilane which were prepared by the reaction of trilithium salts, derived from tri-3-thienylphosphine oxides (7a and 7b), with P(OPh)(3). The reaction of 3d with W(CO)(5)(THF) gave a 1:2 complex 12 in high yield.

表征谱图