N-(4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)phenyl)acrylamide | 1263304-43-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)phenyl)acrylamide
• 英文别名: N-[4-[4-[2-(2-Methyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentenyl]-5-methyl-2-thienyl]phenyl]acrylamide；N-[4-[4-[3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopenten-1-yl]-5-methylthiophen-2-yl]phenyl]prop-2-enamide
• CAS: 1263304-43-3
• 化学式: C₃₀H₂₁F₆NOS₂
• 分子量: 589.625
• InChiKey: RLFXDINPPOFAAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  85.6
• 氢给体数：
  1
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  1-[2-methyl-5-phenyl-3-thienyl]heptafluorocyclopentene 在 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 乙醚 、 乙醇 、 正己烷 、 水 、 甲苯 为溶剂， 反应 68.67h， 生成 N-(4-(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)phenyl)acrylamide
  参考文献：
  名称：

  Multifunctional photo- and thermo-responsive copolymer nanoparticles

  摘要：

  A novel amphiphilic photochromic copolymer P1-o consisting of a hydrophilic poly(N-isopropylacrylamide) backbone and thermally irreversible photochromic and hydrophobic 1,2-dithienylethene derivative pendants was designed, synthesized and used to fabricate self-assembled copolymer nanoparticles in an aqueous condition. The hydrodynamic diameters of the multifunctional copolymer P1-o nanoparticles reversibly switched between two stable states with two stimuli: light and temperature in an aqueous suspension.Graphical abstract:(C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.03.013

文献信息

• Multifunctional photo- and thermo-responsive copolymer nanoparticles
  作者：Seon-Jeong Lim、Carl-Johan Carling、C. Chad Warford、Dennis Hsiao、Byron D. Gates、Neil R. Branda

  DOI：10.1016/j.dyepig.2010.03.013

  日期：2011.6

  A novel amphiphilic photochromic copolymer P1-o consisting of a hydrophilic poly(N-isopropylacrylamide) backbone and thermally irreversible photochromic and hydrophobic 1,2-dithienylethene derivative pendants was designed, synthesized and used to fabricate self-assembled copolymer nanoparticles in an aqueous condition. The hydrodynamic diameters of the multifunctional copolymer P1-o nanoparticles reversibly switched between two stable states with two stimuli: light and temperature in an aqueous suspension.Graphical abstract:(C) 2010 Elsevier Ltd. All rights reserved.