2-N,3-N-bis(2,6-dimethylphenyl)-1,1,1,4,4,4-hexafluorobutane-2,3-diimine | 625385-96-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-N,3-N-bis(2,6-dimethylphenyl)-1,1,1,4,4,4-hexafluorobutane-2,3-diimine
• CAS: 625385-96-8
• 化学式: C₂₀H₁₈F₆N₂
• 分子量: 400.367
• InChiKey: KEQCWZMLGHGZCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  bis(benzonitrile)dichloroplatinum(II) 、 2-N,3-N-bis(2,6-dimethylphenyl)-1,1,1,4,4,4-hexafluorobutane-2,3-diimine 以 氯苯 为溶剂， 生成 [((C(CF₃)NC₆H₃(CH₃)2)2)PtCl₂]
  参考文献：
  名称：

  Synthesis and Structural Characterization of a Fluorinated α-Diimine Platinum(II) Complex

  摘要：

  The preparation of an electron-deficient (N-N)PtCl2 complex in which the diimine C is substituted by CF3 is described. Thus, reactions between the diimine ligand 1 (R = CF3, R' = 2,6-dimethylphenyl) and PtCl2 (thermal reaction) or KPtCl3(C2H4) (photochemically activated) furnishes the corresponding (N-N)PtCl2 complex 2. The ligand 1 and its Pt complexes 2, as well as related (N-N)PtCl2 complexes 3 (R = CO2CD3, R' = 2,6-dimethylphenyl; a methanolysis product) and 4 (R = H, R' = 2,6-dimethylphenyl) have been characterized by X-ray crystallography.

  DOI：

  10.1021/om060897u
• 作为产物：
  描述：

  N-(2,6-Dimethylphenyl)-2,2,2-trifluoroacetimidoyl iodide 在 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 一氧化碳 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 70.0 ℃ 、101.32 kPa 条件下， 以82%的产率得到2-N,3-N-bis(2,6-dimethylphenyl)-1,1,1,4,4,4-hexafluorobutane-2,3-diimine
  参考文献：
  名称：

  一种制备氟化二亚胺的新途径：在钯催化剂存在下，一氧化碳促进氟化亚胺酰碘的还原均聚

  摘要：

  提出了一种新的氟化二亚胺催化途径，该途径涉及钯（0）催化的亚氨基碘化物的还原二聚。

  DOI：

  10.1039/b303040g

文献信息

• A novel route to the fluorinated diimines: carbon monoxide-promoted reductive homocoupling of fluorinated imidoyl iodides in the presence of a palladium catalyst
  作者：Hideki Amii、Mitsuhiro Kohda、Motoharu Seo、Kenji Uneyama

  DOI：10.1039/b303040g

  日期：——

  A new catalytic access to the fluorinated diimines which involves palladium(0)-catalyzed reductive dimerization of the imidoyl iodides is presented.

  提出了一种新的氟化二亚胺催化途径，该途径涉及钯（0）催化的亚氨基碘化物的还原二聚。
• Synthesis and Structural Characterization of a Fluorinated α-Diimine Platinum(II) Complex
  作者：Martin Lersch、Alexander Krivokapic、Mats Tilset

  DOI：10.1021/om060897u

  日期：2007.3.1

  The preparation of an electron-deficient (N-N)PtCl2 complex in which the diimine C is substituted by CF3 is described. Thus, reactions between the diimine ligand 1 (R = CF3, R' = 2,6-dimethylphenyl) and PtCl2 (thermal reaction) or KPtCl3(C2H4) (photochemically activated) furnishes the corresponding (N-N)PtCl2 complex 2. The ligand 1 and its Pt complexes 2, as well as related (N-N)PtCl2 complexes 3 (R = CO2CD3, R' = 2,6-dimethylphenyl; a methanolysis product) and 4 (R = H, R' = 2,6-dimethylphenyl) have been characterized by X-ray crystallography.