N-Isopropylidene-benzenesulfenamide | 38206-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Isopropylidene-benzenesulfenamide
• 英文别名: n-(Phenylsulfanyl)propan-2-imine；N-phenylsulfanylpropan-2-imine
• CAS: 38206-14-3
• 化学式: C₉H₁₁NS
• 分子量: 165.259
• InChiKey: DZXGPEWLIHOSRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  37.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-Isopropylidene-benzenesulfenamide 在 碳酸氢钠 、 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Chemistry of the sulfur-nitrogen bond. VIII. N-Alkylidenesulfinamides

  摘要：

  DOI：

  10.1021/ja00822a055
• 作为产物：
  描述：

  丙酮 、 二苯二硫醚 在 氨 、 silver nitrate 作用下， 以 甲醇 为溶剂， 生成 N-Isopropylidene-benzenesulfenamide
  参考文献：
  名称：

  Chemistry of the sulfur-nitrogen bond. VI. Convenient one-step synthesis of sulfenimines (S-aryl thiooximes)

  摘要：

  DOI：

  10.1021/jo00956a016

文献信息

• Hydrogenated modified polymer, process for producing the same and composition containing the same
  申请人：JSR Corporation

  公开号：US20030100683A1

  公开（公告）日：2003-05-29

  An objective of the present invention is to provide a hydrogenated modified polymer which can afford a molded body excellent in improvement in the balance among the impact resistance, the strength, the adherability and as the appearance, and a process for producing the same as well as a composition containing the same. Another objective is to provide a composition which can afford a molded body excellent in the balance among the flame retardancy, the tensile strength, the tensile extension, the heat resistance, the characteristic at low temperature, the insulation property, the pliability and the like. The hydrogenated modified polymer of the invention is a hydrogenated polymer of a modified conjugated diene-based polymer obtained by reacting an alkoxysilane compound to a polymer which is polymerized a conjugated diene or a conjugated diene and another monomer using an organic alkali metal compound as a polymerization initiator in an inert organic solvent such as cyclohexane and the like. The hydrogenated modified polymer composition of the invention contains the above-mentioned hydrogenated modified polymer and at least one selected from the group consisting of nonpolar polymer, polar polymer and filler.

  本发明的目标是提供一种氢化改性聚合物，该聚合物能够提供在冲击抗性、强度、附着性和外观之间平衡改善的模塑体，以及生产该聚合物的方法和包含该聚合物的组合物。另一个目标是提供一种组合物，该组合物能够提供在阻燃性、拉伸强度、拉伸延伸、耐热性、低温特性、绝缘性、可塑性等方面平衡改善的模塑体。本发明的氢化改性聚合物是一种氢化的改性共轭二烯基聚合物，通过在惰性有机溶剂如环己烷等中使用有机金属碱作为聚合引发剂，将烯丙基二烯或烯丙基二烯和另一种单体聚合而成的聚合物中反应烷氧基硅烷化合物而得到。本发明的氢化改性聚合物组合物包含上述氢化改性聚合物和至少选自非极性聚合物、极性聚合物和填料的一种。
• TERMINAL-MODIFIED BLOCK COPOLYMER AND COMPOSITION CONTAINING SAID COPOLYMER
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0245505A1

  公开（公告）日：1987-11-19

  A terminal-modified block copolymer wherein an amino group- or amino group-containing, terminal-treating agent is bound to the terminals of the polymer. It is obtained by reacting the active terminals of a block copolymer of a conjugated diene with a vinylaromatic hydrocarbon comprising 5 to 95 % of a vinylaromatic hydrocarbon and having a number- average molecular weight of 5,000 to 1,000,000 (obtained by using at least one member selected from among alkali metals and organic alkali metal compounds as a polymerization initiator) with at least one terminal-treating agent selected from among imide compounds, cyanamide compounds, aziridinyl compounds, amide compounds, and other tertiary amino group-containing compounds. A pressure-sensitive adhesive composition excellent in adhesiveness and anti-creeping properties comprising said block copolymer and a tackifying resin, a water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplastic resin composition comprising said block copolymer and a thermoplastic resin, and a conductive composition comprising said block copolymer and a conductive material are also disclosed.

  一种末端改性嵌段共聚物，其中一种含氨基或氨基基团的末端处理剂与聚合物的末端结合。它是通过将共轭二烯与乙烯基芳烃的嵌段共聚物的活性末端与至少一种末端处理剂反应而得到的，该末端处理剂选自亚胺化合物、氰胺化合物、氮杂环丁基化合物、酰胺化合物和其他含三级氨基基团的化合物，乙烯基芳烃的含量为 5%至 95%，平均分子量为 5,000 至 1,000,000 （通过使用至少一种选自碱金属和有机碱金属化合物的成员作为聚合引发剂而得到）。此外，还公开了由所述嵌段共聚物和增粘树脂组成的粘合性和防蠕变性能优异的压敏胶组合物、由所述嵌段共聚物和高吸水性树脂组成的吸水组合物、由所述嵌段共聚物和热塑性树脂组成的热塑性树脂组合物以及由所述嵌段共聚物和导电材料组成的导电组合物。
• Compositions containing a terminal-modified block copolymer
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0473206A2

  公开（公告）日：1992-03-04

  An adhesive composition excellent in tackiness, adhesiveness, and creep resistance characteristic which comprises said block copolymer and a tackifier resin, a water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplastic resin composition comprising said block copolymer and a thermoplastic resin, and an electroconductive composition comprising said block copolymer and an electroconductive material, which consists of a terminal-modified block copolymer having the rest of the terminal-treating agent bonded to the polymer terminal which is obtained by treating the active terminal of a block copolymer comprising conjugated dienes and vinylaromatic hydrocarbon compounds which is obtained by using as the polymerization initiator at least one member selected from alkali metals or organoalkali metals and has a vinylaromatic hydrocarbon content of 5 to 95% by weight and a number average molecular weight of 5,000 to 1,000,000.

  一种粘合剂组合物，具有优异的粘性、粘附性和抗蠕变性，由所述嵌段共聚物和增粘树脂、由所述嵌段共聚物和高吸水性树脂组成的吸水组合物、由所述嵌段共聚物和热塑性树脂组成的热塑性树脂组合物以及由所述嵌段共聚物和导电材料组成的导电组合物构成、其中包括一种末端改性嵌段共聚物，其末端处理剂的其余部分与聚合物末端结合，该聚合物末端是通过处理由共轭二烯和乙烯基芳烃化合物组成的嵌段共聚物的活性末端而获得的，该嵌段共聚物是通过使用至少一种选自碱金属或有机碱金属的成员作为聚合引发剂而获得的，其乙烯基芳烃含量为 5%至 95%（按重量计），平均分子量为 5,000 至 1,000,000 。
• POLYVINYL ALCOHOL RESIN COMPOSITION AND MULTILAYER PACKAGES
  申请人：Kuraray Co., Ltd.

  公开号：EP1316582A1

  公开（公告）日：2003-06-04

  The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt% of a polyvinyl alcohol resin (A) and 0.1 to 30 wt% of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2 • day or more.

  本发明提供了一种具有氧清除功能的树脂组合物。该树脂组合物包括 70 至 99.9 wt%的聚乙烯醇树脂（A）和 0.1 至 30 wt%的除聚乙烯醇树脂（A）之外的热塑性树脂（B），其中热塑性树脂（B）具有碳碳双键和包括杂原子的官能团，该树脂组合物的吸氧率为 0.001 ml/m2 - 天或以上。
• Polyvinyl alcohol resin composition and multilayer packages
  申请人：——

  公开号：US20030022974A1

  公开（公告）日：2003-01-30

  The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 m//m 2 day or more.

  本发明提供了一种具有氧清除功能的树脂组合物。该树脂组合物包括 70 至 99.9 wt % 的聚乙烯醇树脂（A）和 0.1 至 30 wt % 的除聚乙烯醇树脂（A）之外的热塑性树脂（B），其中热塑性树脂（B）具有碳碳双键和包括杂原子的官能团，该树脂组合物的吸氧率为 0.001 m//m 2 天或以上。