4-(dimethoxymethylsilyl)styrene | 17998-86-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(dimethoxymethylsilyl)styrene
• 英文别名: dimethoxy-methyl-(4-vinyl-phenyl)-silane；Dimethoxy-methyl-(4-vinyl-phenyl)-silan；4-(methyldimethoxysilyl)styrene；(4-ethenylphenyl)-dimethoxy-methylsilane
• CAS: 17998-86-6
• 化学式: C₁₁H₁₆O₂Si
• 分子量: 208.332
• InChiKey: PXDIIXCXCVILQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(dimethoxymethylsilyl)styrene 在 硫酸 作用下， 生成 1,1,3,3-tetramethyl-1,3-bis(p-vinylphenyl)disiloxane
  参考文献：
  名称：

  Preparation and Properties of Styrenyl-Substituted Organosilicon Compounds

  摘要：

  DOI：

  10.1021/jo01106a018
• 作为产物：
  描述：

  三氯(4-乙烯基苯基)硅烷 生成 4-(dimethoxymethylsilyl)styrene
  参考文献：
  名称：

  Preparation and Properties of Styrenyl-Substituted Organosilicon Compounds

  摘要：

  DOI：

  10.1021/jo01106a018

文献信息

• Curable silicone resin composition and reactive silicon compounds
  申请人：——

  公开号：US20030130389A1

  公开（公告）日：2003-07-10

  A curable silicone resin composition comprises (A) an uncured silicone resin having units of the formula (R*) a (R) b SiO (4−a−b)/2 , where each R* is a functional group capable of reacting with Si—OH and/or Si-alkoxy groups and each R is a nonfunctional monovalent hydrocarbon group, a+b is from 1.0 to 3.0 and each molecule of uncured silicone resin contains an average of at least two groups R*, and (B) a silanol or hydrolysable compound of the formula (I) where R′ represents a hydroxyl group or a hydrolysable group; each R″ represents hydrogen, a monovalent hydrocarbon which optionally is substituted, or a group within the above definition of R′; and Ar is a substantially nonflexible linkage including at least one para-arylene moiety, so that the groups (R′) 2 R″Si— are spatially separated.

  一种可治愈的硅树脂组合物包括(A)未固化的硅树脂，其具有式(R*)a(R)bSiO(4−a−b)/2的单元，其中每个R*是能够与Si—OH和/或Si-烷氧基反应的功能性基团，每个R是非功能性单价碳氢基团，a+b为1.0至3.0，每个未固化的硅树脂分子含有平均至少两个R*基团；以及(B)式(I)的硅醇或可水解化合物，其中R'代表羟基或可水解基团；每个R"代表氢、一价碳氢基团（可选地被取代）或上述R'定义内的基团；Ar是包括至少一个对位芳基单元的实质上非柔性连接，以使得(R')2R"Si—基团在空间上分离。
• Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis
  作者：Geneviève Cerveau、Sabrina Chappellet、Robert J.P. Corriu*、Bertrand Dabiens

  DOI：10.1016/s0022-328x(01)00668-4

  日期：2001.4

  The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.
• Preparation and Properties of Styrenyl-Substituted Organosilicon Compounds
  作者：DANIEL W. LEWIS

  DOI：10.1021/jo01106a018

  日期：1958.12
• Manami, Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1959, vol. 62, p. 529
  作者：Manami

  DOI：——

  日期：——