potassium;chloroplatinum(1+);2,6-di(phenyl)pyridine;platinum(2+) | 224195-08-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: potassium;chloroplatinum(1+);2,6-di(phenyl)pyridine;platinum(2+)
• CAS: 224195-08-8
• 化学式: C₃₄H₂₂ClN₂Pt₂*K
• 分子量: 923.273
• InChiKey: MVLLPJAUNYQPNR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.72
• 重原子数：
  40
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  potassium;chloroplatinum(1+);2,6-di(phenyl)pyridine;platinum(2+) 以 氯仿 、 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  High-Yield Synthesis of a C∧N∧C Tridentate Platinum Complex

  摘要：

  2,6-Diphenylpyridine is metalated twice by potassium tetrachloroplatinate in acetic acid to give in high yield a complex with a tridentate ligand bound to the metal via a C boolean AND N boolean AND C donor set. This complex and three derivatives have been characterized, including the single-crystal X-ray analysis of one derivative.

  DOI：

  10.1021/om981006o
• 作为产物：
  描述：

  2,6-二苯基吡啶 、 以 溶剂黄146 为溶剂， 以98%的产率得到potassium;chloroplatinum(1+);2,6-di(phenyl)pyridine;platinum(2+)
  参考文献：
  名称：

  High-Yield Synthesis of a C∧N∧C Tridentate Platinum Complex

  摘要：

  2,6-Diphenylpyridine is metalated twice by potassium tetrachloroplatinate in acetic acid to give in high yield a complex with a tridentate ligand bound to the metal via a C boolean AND N boolean AND C donor set. This complex and three derivatives have been characterized, including the single-crystal X-ray analysis of one derivative.

  DOI：

  10.1021/om981006o

文献信息

• High-Yield Synthesis of a C∧N∧C Tridentate Platinum Complex
  作者：Gareth W. V. Cave、Nathaniel W. Alcock、Jonathan P. Rourke

  DOI：10.1021/om981006o

  日期：1999.4.1

  2,6-Diphenylpyridine is metalated twice by potassium tetrachloroplatinate in acetic acid to give in high yield a complex with a tridentate ligand bound to the metal via a C boolean AND N boolean AND C donor set. This complex and three derivatives have been characterized, including the single-crystal X-ray analysis of one derivative.