Benzoylthiocholin | 13365-71-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzoylthiocholin
• 英文别名: 2-(Benzoylsulfanyl)-N,N,N-trimethylethan-1-aminium；2-benzoylsulfanylethyl(trimethyl)azanium
• CAS: 13365-71-4
• 化学式: C₁₂H₁₈NOS
• 分子量: 224.347
• InChiKey: WHFRQMFIMVEPIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  S-乙酰基硫代胆碱 、 钠硫代苯甲酰基乙烷磺酸酯 在 sodium hydroxide 、 重水 、 氘代磷酸 、 acetylcholinesterase 作用下， 生成 Benzoylthiocholin 、
  参考文献：
  名称：

  Tandem driven dynamic self-inhibition of acetylcholinesterase

  摘要：

  通过使用可逆转硫醇酯化技术的乙酰胆碱酯酶（AChE）动态抑制剂，证明了串联驱动动态自我抑制的概念。

  DOI：

  10.1039/c0cc02479a

文献信息

• DYE-SENSITIZED SOLAR CELL
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP2928009A1

  公开（公告）日：2015-10-07

  The purpose of the present invention is to provide a dye-sensitized solar cell which has excellent photoelectric conversion efficiency and excellent durability. Disclosed is a dye-sensitized solar cell which comprises: a first conductive supporting body which has a semiconductor-containing layer that is sensitized by a dye; a second conductive supporting body which has a counter electrode and is disposed at a position where the semiconductor-containing layer and the counter electrode face each other at a predetermined distance; a charge transfer layer which is sandwiched between the first and second conductive supporting bodies; and a sealing agent which is provided in the peripheral portions of the first and second conductive supporting bodies for the purpose of sealing the charge transfer layer. The dye is an organic non-ruthenium dye; the counter electrode contains platinum; and the charge transfer layer is composed of an electrolyte solution that contains iodine, iodine ions and a compound which has both a thioester bond and a positively charged nitrogen atom in each molecule.

  本发明的目的是提供一种染料敏化太阳能电池，它具有优异的光电转换效率和出色的耐用性。本发明公开了一种染料敏化太阳能电池，该电池包括：第一导电支撑体，该支撑体具有被染料敏化的含半导体层；第二导电支撑体，该支撑体具有对电极，并设置在含半导体层和对电极以预定距离面对面的位置；电荷转移层，该电荷转移层夹在第一和第二导电支撑体之间；以及密封剂，该密封剂设置在第一和第二导电支撑体的外围部分，用于密封电荷转移层。染料是一种有机非钌染料；对电极含有铂；电荷转移层由电解质溶液组成，电解质溶液含有碘、碘离子和一种在每个分子中都有硫酯键和带正电的氮原子的化合物。
• BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, METHOD FOR MANUFACTURING BIO-ELECTRODE, AND REACTION COMPOSITE
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP4006921A2

  公开（公告）日：2022-06-01

  A bio-electrode composition contains (A) a reaction composite of a monomer having an ionic functional group and a carbon particle. The component (A) contains the carbon particle bonded to the monomer having a structure selected from the group consisting of salts of ammonium, lithium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which prevents significant reduction in the electric conductivity even when wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.

  一种生物电极组合物包含(A)具有离子官能团的单体和碳颗粒的反应复合材料。组分（A）包含与单体结合的碳颗粒，单体的结构选自与氟磺酸、氟磺酰亚胺和 N-羰基-氟磺酰胺中的任一种形成的铵、锂、钠、钾和银的盐组成的组。因此，本发明提供了：一种能够为生物电极形成活体接触层的生物电极组合物，其导电性和生物相容性极佳，重量轻，可低成本制造，即使被水浸湿或干燥，也不会显著降低导电性；一种生物电极，包括由该生物电极组合物形成的活体接触层；以及一种制造该生物电极的方法。
• Adhesive composition, bio-electrode, method for manufacturing a bio-electrode, and salt
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10808148B2

  公开（公告）日：2020-10-20

  An adhesive composition including a resin and electro-conductive material, wherein the electro-conductive material is an ammonium salt of fluorosulfonic acid having 5 or more carbon atoms shown by the general formula (1): (R1—X—Z—SO3−)n Mn+ (1), wherein, R1 represents a monovalent hydrocarbon group having 1 to 40 carbon atoms and optionally substituted by a heteroatom or optionally interposed by heteroatom; X represents any of a single bond, ether group, ester group, and amide group; Z represents an alkylene group having 2 to 4 carbon atoms, containing 1 to 6 fluorine atoms, and optionally containing a carbonyl group; Mn+ represents a cation having one or two ammonium cation structures. This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility, and light weight, which manufactures at low cost and does not cause large lowering of the electric conductivity even when it is wetted with water or dried.

  一种粘合剂组合物，包括树脂和导电材料，其中导电材料是具有 5 个或更多碳原子的氟磺酸铵盐，如通式(1)所示：(R1-X-Z-SO3-)n Mn+ (1)，其中，R1 代表具有 1 至 40 个碳原子的单价烃基，可选被杂原子取代或可选被杂原子夹杂；X 代表单键、醚基、酯基和酰胺基中的任何一种；Z 代表具有 2 至 4 个碳原子的亚烷基，含有 1 至 6 个氟原子，可选含有一个羰基；Mn+ 代表具有一个或两个铵阳离子结构的阳离子。这样就可以形成生物电极的活体接触层，该层具有优异的导电性、生物相容性和轻质，制造成本低，即使被水浸湿或干燥也不会导致导电性大幅降低。
• Bio-electrode composition, bio-electrode, and method for manufacturing bio-electrode
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10864366B2

  公开（公告）日：2020-12-15

  The present invention provides a bio-electrode composition including: a resin containing a urethane bond in a main chain and a silsesquioxane in a side chain; and an electro-conductive material, wherein the electro-conductive material is a polymer compound having one or more repeating units selected from fluorosulfonic acid salts shown by the following general formulae (1)-1 and (1)-2, sulfonimide salts shown by the following general formula (1)-3, and sulfonamide salts shown by the following general formula (1)-4. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light in weight, manufacturable at low cost, and free from large lowering of the electric conductivity even when it is wetted with water or dried. The present invention also provides a bio-electrode in which the living body contact layer is formed from the bio-electrode composition, and a method for manufacturing the bio-electrode.

  本发明提供了一种生物电极组合物，包括：主链中含有聚氨酯键、侧链中含有硅倍半氧烷的树脂；以及导电材料，其中导电材料是具有一个或多个重复单元的聚合物化合物，这些重复单元选自以下通式(1)-1和(1)-2所示的氟磺酸盐、以下通式(1)-3所示的磺酰亚胺盐以及以下通式(1)-4所示的磺酰胺盐。这样就可以形成生物电极的活体接触层，该层具有优异的导电性和生物相容性，重量轻，制造成本低，即使被水浸湿或干燥，导电性也不会大幅降低。本发明还提供了一种由生物电极组合物形成活体接触层的生物电极，以及制造该生物电极的方法。
• Dye-Sensitized Solar Cell
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：US20150294798A1

  公开（公告）日：2015-10-15

  The purpose of the present invention is to provide a dye-sensitized solar cell which has excellent photoelectric conversion efficiency and excellent durability. Disclosed is a dye-sensitized solar cell which comprises: a first conductive supporting body which has a semiconductor-containing layer that is sensitized by a dye; a second conductive supporting body which has a counter electrode and is disposed at a position where the semiconductor-containing layer and the counter electrode face each other at a predetermined distance; a charge transfer layer which is sandwiched between the first and second conductive supporting bodies; and a sealing agent which is provided in the peripheral portions of the first and second conductive supporting bodies for the purpose of sealing the charge transfer layer. The dye is an organic non-ruthenium dye; the counter electrode contains platinum; and the charge transfer layer is composed of an electrolyte solution that contains iodine, iodine ions and a compound which has both a thioester bond and a positively charged nitrogen atom in each molecule.