propionic acid cyclohex-1-enyl ester | 59557-03-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: propionic acid cyclohex-1-enyl ester
• 英文别名: Propionsaeure-cyclohex-1-enylester；Cyclohexenyl propionate；cyclohexen-1-yl propanoate
• CAS: 59557-03-8
• 化学式: C₉H₁₄O₂
• 分子量: 154.209
• InChiKey: SQZNAONOTRQTIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  propionic acid cyclohex-1-enyl ester 在 五氯化磷 、 二氧化硫 作用下， 生成 2-chlorocyclohexenyl propionate
  参考文献：
  名称：

  Krolevets, A. A., Journal of general chemistry of the USSR, 1987, vol. 57, # 3, p. 484 - 485

  摘要：

  DOI：
• 作为产物：
  描述：

  1-环己烯氧基三甲基硅烷 、 丙酰氯 在 copper(l) chloride 作用下， 以 various solvent(s) 为溶剂， 反应 20.0h， 以74%的产率得到propionic acid cyclohex-1-enyl ester
  参考文献：
  名称：

  铜（I）盐介导的甲硅烷基烯醇醚与酰卤的选择性O酰化

  摘要：

  描述了在CuCl存在下由甲硅烷基烯醇醚和酰氯选择性合成烯醇酯（O-酰化产物）的新方法。该反应在DMI（1,3-二甲基-2-咪唑啉酮）中平稳进行，但在极性较小的溶剂中则无法进行。如先前报道的氢硅烷和炔基硅烷的情况那样，提出了用于该转化的硅-铜交换反应路径。

  DOI：

  10.1016/s0040-4039(98)01334-3

文献信息

• TRANSESTERIFICATION PROCESS USING MIXED SALT ACETYLACETONATES CATALYSTS
  申请人：Goossens Thomas Peter Anne

  公开号：US20130090492A1

  公开（公告）日：2013-04-11

  This invention is directed to a general catalyst of high activity and selectivity for the production of a variety of esters, particularly acrylate and methacrylate-based esters, by a transesterification reaction. This objective is achieved by reaction of an ester of a carboxylic or a carbonic acid, in particular of a saturated or unsaturated, typically, a 3 to 4 carbon atom carboxylic acid; with an alcohol in the presence of a catalyst comprising the combination of a metal 1,3-dicarbonyl complex (pref. Zn or Fe acetylacetonate) and a salt, in particular an inorganic salt, pref. ZnCl2, LiCI, NaCI, NH4CI or Lil. These catalysts are prepared from readily available starting materials within the reaction medium without the need for isolation (in-situ preparation).

  这项发明针对一种高活性和选择性的通用催化剂，用于通过酯交换反应生产各种酯类，特别是丙烯酸酯和甲基丙烯酸酯。该目标通过在存在催化剂的情况下，将羧酸酯或碳酸酯的酯，特别是饱和或不饱和的、通常为3到4个碳原子的羧酸酯；与醇反应来实现。催化剂包括金属1,3-二羰基配合物（首选Zn或Fe乙酰丙酮酸盐）和盐的组合，特别是无机盐，首选ZnCl2，LiCl，NaCl，NH4Cl或I2。这些催化剂是在反应介质中从易得的起始物质制备而成，无需分离（原位制备）。
• Method for Allylating and Vinylating Aryl, Heteroaryl, Alkyl, and Alkene Halogenides Using Transition Metal Catalysis
  申请人：Gotta Matthias

  公开号：US20130184485A1

  公开（公告）日：2013-07-18

  What is described is a process for preparing organic compounds of the general formula (I) R—R′  (I) by converting a corresponding compound of the general formula (II) R—X   (II) in which X is fluorine, chlorine, bromine or iodine to an organomagnesium compound of the general formula (III) [M + ] n [R m MgX k Y 1 ]  (III) wherein compounds of the formula (III) are reacted with a compound of the general formula (IV) characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic amounts of an iron compound, based on the compound of the general formula (II), and optionally in the presence of b) a nitrogen-, oxygen- and/or phosphorus-containing additive in a catalytic or stoichiometric amount, based on the compound of the general formula (II).

  描述的是一种制备通式（I）R—R′的有机化合物的过程  (I)，通过将通式（II）R—X的相应化合物转化为通式（III）[M+]n[RmMgXkY1]的有机镁化合物  (III)，其中X为氟、氯、溴或碘，其中化合物的通式（III）与通式（IV）的化合物发生反应，其特点在于（III）与（IV）的反应在以下条件下进行：a）基于通式（II）的化合物的铁化合物的催化量，可选地在b）氮、氧和/或磷含量添加剂的存在下以催化量或化学计量量进行。
• ACYLOXYLATION CATALYST AND PROCESS FOR ITS PRODUCTION
  申请人：Yamamoto Yoshimi

  公开号：US20100076217A1

  公开（公告）日：2010-03-25

  An acyloxylation catalyst is obtained by loading (a) a first component containing at least one element of Groups 8, 9, 10 and 11 of the Periodic Table, (b) a second component containing an element which is at least one element of Groups 8, 9, 10 and 11 of the Periodic Table and which is different from the element of the first component, and (c) a third component containing an element which is a component that produces a precipitation-starting pH below the precipitation-starting pH of the first component and second component and which is different from the elements of the first component and second component, onto (d) a support. A catalyst is obtained that can be used to efficiently carry out acyloxylation for economical production of acyloxylated compounds.

  通过将(a)至少包含周期表第8、9、10和11组元素的第一组分、(b)含有周期表第8、9、10和11组中至少一种元素且与第一组分元素不同的第二组分、以及(c)含有一个产生沉淀起始pH低于第一组分和第二组分的沉淀起始pH的组分且与第一组分和第二组分元素不同的第三组分，负载到(d)载体上，可以获得酰氧化催化剂。获得的催化剂可用于高效地进行酰氧化反应，从而经济地生产酰氧基化合物。
• Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom
  申请人：——

  公开号：US20030149219A1

  公开（公告）日：2003-08-07

  A process for manufacturing an &agr;-halohydrin intermediate and an epoxy resin prepared therefrom including epoxidizing an &agr;-halohydrin intermediate produced from an in situ halide substitution-deesterification of an &agr;-hydroxy ester derivative which has been obtained by the coupling reaction of a phenol or a mixture of phenols and a glycidyl ester optionally in the presence of a catalyst.

  一种制造&agr;-卤代醇中间体和由此制备的环氧树脂的工艺，包括环氧化由&agr;-羟基酯衍生物的原位卤化物取代-酯化反应生成的&agr;-卤代醇中间体，该&agr;-羟基酯衍生物是由苯酚或苯酚混合物与缩水甘油酯偶联反应生成的，可选择在催化剂存在下进行。
• Duhamel, Pierre; Cahard, Dominique; Poirier, Jean-Marie, Journal of the Chemical Society. Perkin transactions I, 1993, # 21, p. 2509 - 2512
  作者：Duhamel, Pierre、Cahard, Dominique、Poirier, Jean-Marie

  DOI：——

  日期：——