Zn(II)(TPP)(N-methylimidazole) | 67820-10-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Zn(II)(TPP)(N-methylimidazole)
• 英文别名: (1-methyl-1H-imidazole)zinc(II) tetraphenylporphyrin
• CAS: 67820-10-4
• 化学式: C₄₈H₃₄N₆Zn
• 分子量: 760.228
• InChiKey: CBFZIOVDAPRKIU-YKKPBKTHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 zinc tetraphenylporphyrin 以 邻二氯苯 为溶剂， 生成 Zn(II)(TPP)(N-methylimidazole)
  参考文献：
  名称：

  氟化铝 (III) 卟啉：合成、光谱学、电化学和光化学

  摘要：

  一系列氟化游离碱卟啉（H 2 TPPFn,n= 0, 8, 12, 20, 24) 和相应的铝 (III) 卟啉 (AlTPPFn-Ph，n= 0, 8, 12, 20, 24) 已合成衍生物，并研究了它们的光谱、氧化还原和光学性质。吸收研究表明，所研究的卟啉的光谱形状对氟化程度很敏感。中观-苯基单元。类似地，荧光量子产率和单重态寿命取决于氟原子的数量，并随着氟原子数量的增加而降低。H 2 TPPFn和AlTPPFn-Ph (n= 8, 12, 20, 24) 衍生物分别与 H 2 TPP 和 AlTPP相比表现出较低的荧光强度。然而，AlTPPFn-Ph (n= 0, 8, 12, 20, 24) 衍生物与众所周知的 ZnTPP 相比产生相对强的荧光。正如预测的那样，通过增加氟原子，氧化还原电位向更正的一侧移动。AlTPPF 的路易斯酸度n-Ph通过使用路易斯碱的吸收和荧光滴定来量化ñ-

  DOI：

  10.1142/s1088424621500267

文献信息

• Recognition of Imidazoles by Strapped Zinc(II) Porphyrin Receptors:  Insight into the Induced-Fit Mechanism
  作者：Jeremy Brandel、Ali Trabolsi、Frédéric Melin、Mourad Elhabiri、Jean Weiss、Anne-Marie Albrecht-Gary

  DOI：10.1021/ic701590x

  日期：2007.11.1

  Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.
• Molecular Tools for the Self-Assembly of Bisporphyrin Photodyads: A Comprehensive Physicochemical and Photophysical Study
  作者：Jérémy Brandel、Ali Trabolsi、Hassan Traboulsi、Frédéric Melin、Matthieu Koepf、Jennifer A. Wytko、Mourad Elhabiri、Jean Weiss、Anne-Marie Albrecht-Gary

  DOI：10.1021/ic802407x

  日期：2009.4.20

  Accessible and hindered phenanthroline-strapped Zn(II) porphyrin receptors exhibited suitable topography tailored to strongly and selectively bind N-1-unsubstituted imidazoles and imidazoles appended to free-base porphyrins. Distal binding was clearly driven by the formation of strong bifurcated hydrogen bonds with the phenanthroline unit of the receptors. An extensive physicochemical study emphasized the influence of bulkiness of the substrate and of the porphyrin receptor on the binding and self-assembly mechanism. Knowledge of the corresponding spectroscopic, thermodynamic, and kinetic data were of fundamental importance to elucidate and to model the photoinduced properties which occur within the self-assembled porphyrin dyads.
• Storm, Carlyle B.; Turner, Anne H.; Swann, Madeline B., Inorganic Chemistry, 1984, vol. 23, # 18, p. 2743 - 2746
  作者：Storm, Carlyle B.、Turner, Anne H.、Swann, Madeline B.

  DOI：——

  日期：——
• Kadish; Shiue; Rhodes, Inorganic Chemistry, 1981, vol. 20, # 4, p. 1274 - 1277
  作者：Kadish、Shiue、Rhodes、Bottomley

  DOI：——

  日期：——
• Kugimiya, Shin-Ichi; Sasaki, Tomikazu; Tabushi, Iwao, Nippon Kagaku Kaishi/Journal of the Chemical Society of Japan
  作者：Kugimiya, Shin-Ichi、Sasaki, Tomikazu、Tabushi, Iwao

  DOI：——

  日期：——