{6-acetyl-13-(4-acetoxybenzoyl)-7,12,14-trimethyl-1,4,8,11-tetraazacyclodeca-4,6,11,13-tetraenato(2-)}nickel(II) | 141053-94-3

• 分子结构分类: 有机化合物
• 英文名称: {6-acetyl-13-(4-acetoxybenzoyl)-7,12,14-trimethyl-1,4,8,11-tetraazacyclodeca-4,6,11,13-tetraenato(2-)}nickel(II)
• CAS: 141053-94-3
• 化学式: C₂₄H₂₈N₄NiO₄
• 分子量: 495.201
• InChiKey: VLHBTBPRCJNVRI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {6-acetyl-13-(4-acetoxybenzoyl)-7,12,14-trimethyl-1,4,8,11-tetraazacyclodeca-4,6,11,13-tetraenato(2-)}nickel(II) 在 potassium tert-butylate 作用下， 以 甲醇 为溶剂， 以55%的产率得到{6-acetyl-13-(p-hydroxybenzoyl)-7,12,14-trimethyl-1,4,8,11-tetraazacyclodeca-4,6,11,13-tetraenato(2-)}nickel(II)
  参考文献：
  名称：

  Non-symmetrical tetraaza macrocyclic complexes of nickel(II) and their binding to synthetic polymer supports

  摘要：

  The synthesis and characterisation of a family of new tetraaza macrocyclic complexes of nickel(II) have been performed, via reaction of a nucleophilic macrocycle with various acid chlorides, or via peripheral functionalisation of suitable macrocycles. The new complexes have an asymmetric distribution of the peripheral groups on the macrocyclic rings and this is reflected in the appearance of their NMR spectra. Some of the new complexes have been incorporated into the structure of synthetic polymers, either via copolymerisation with a chosen comonomer, in this case styrene, or via reaction with a suitably functionalised, preformed polymer.

  DOI：

  10.1039/dt9920000597
• 作为产物：
  描述：

  4-acetoxybenzoyl chloride 、 {6-acetyl-7,12,14-trimethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenato(2-)}nickel(II) 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以53%的产率得到{6-acetyl-13-(4-acetoxybenzoyl)-7,12,14-trimethyl-1,4,8,11-tetraazacyclodeca-4,6,11,13-tetraenato(2-)}nickel(II)
  参考文献：
  名称：

  Non-symmetrical tetraaza macrocyclic complexes of nickel(II) and their binding to synthetic polymer supports

  摘要：

  The synthesis and characterisation of a family of new tetraaza macrocyclic complexes of nickel(II) have been performed, via reaction of a nucleophilic macrocycle with various acid chlorides, or via peripheral functionalisation of suitable macrocycles. The new complexes have an asymmetric distribution of the peripheral groups on the macrocyclic rings and this is reflected in the appearance of their NMR spectra. Some of the new complexes have been incorporated into the structure of synthetic polymers, either via copolymerisation with a chosen comonomer, in this case styrene, or via reaction with a suitably functionalised, preformed polymer.

  DOI：

  10.1039/dt9920000597