2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone
• 英文别名: 2,6-di(p-Azidobenzal)-4-methylcyclohexanone；(2Z,6E)-2,6-bis[(4-azidophenyl)methylidene]-4-methylcyclohexan-1-one
• 化学式: C₂₁H₁₈N₆O
• 分子量: 370.414
• InChiKey: MLIWQXBKMZNZNF-BQWARBPISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  syn-4-硝基苯甲醛肟 在 盐酸 、 苯酐 、 sodium azide 、 sodium 、 sodium nitrite 作用下， 以 甲醇 、 乙醇 、 水 为溶剂， 反应 5.0h， 生成 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone
  参考文献：
  名称：

  Sauer, Erika; Schopf, Gudrun; Czarnetzki, Kerstin, Zeitschrift fur Chemie, 1987, vol. 27, # 9, p. 335 - 336

  摘要：

  DOI：

文献信息

• INFRARED-SENSITIVE COLOR DEVELOPING COMPOSITION, LITHOGRAPHIC PRINTING PLATE PRECURSOR, PLATE MAKING METHOD FOR LITHOGRAPHIC PRINTING PLATE, AND INFRARED-SENSITIVE COLOR DEVELOPER
  申请人：FUJIFILM Corporation

  公开号：US20160326372A1

  公开（公告）日：2016-11-10

  Objects are to provide an infrared-sensitive color developing composition which develops colors in a high density by means of infrared exposure and does not significantly discolor when aged, to provide a lithographic printing plate precursor which has extremely excellent plate-inspecting properties and favorable storage stability and is capable of maintaining favorable color-developing properties and a plate making method for a lithographic printing plate in which the lithographic printing plate precursor is used, and to provide a new compound that can be preferably used as an infrared-sensitive color developer. An infrared-sensitive color developing composition of the present invention includes a compound represented by Formula (1) (Component A). In addition, the compound in the present invention is represented by Formula (1).

  本发明旨在提供一种红外敏感的彩色显影组成物，通过红外曝光高密度地显色而在老化时不会显著变色，提供一种具有极好的版检查性能和良好的储存稳定性的平版印刷版前体，能够保持良好的显色性能和一种平版印刷版制版方法，其中使用了该平版印刷版前体，并提供一种新的化合物，可作为红外敏感的彩色显影剂优选使用。 本发明的红外敏感的彩色显影组成物包括由式（1）表示的化合物（组分A）。此外，本发明中的化合物由式（1）表示。
• NITROXIDE CONTAINING ELECTRODE MATERIALS FOR SECONDARY BATTERIES
  申请人：Nesvadba Peter

  公开号：US20100181527A1

  公开（公告）日：2010-07-22

  This invention relates to a stable secondary battery utilizing as active principle the oxidation and reduction cycle of a sterically hindered nitroxide radical, a sterically hindered oxoammonium cation, a sterically hindered hydroxylamine or a sterically hindered aminoxide anion containing a piperazin-2,6-dione, a piperazin-2-one or morpholin-2-one structural unit. Further aspects of the invention are a method for providing such a secondary battery, the use of the respective compounds as active elements in secondary batteries and selected novel compounds.

  本发明涉及一种稳定的二次电池，利用空间位阻的亚硝基自由基、空间位阻的氧代铵阳离子、空间位阻的羟胺或空间位阻的氨氧阴离子，其中包含哌嗪-2,6-二酮、哌嗪-2-酮或吗啉-2-酮结构单元的氧化还原循环作为活性原理。发明的其他方面包括提供这种二次电池的方法，使用相应化合物作为二次电池中的活性元素以及选择的新化合物。
• DIVERSITY-ORIENTED POLYMERS OF INTRINSIC MICROPOROSITY AND USES THEREOF
  申请人：The Regents of the University of California

  公开号：US20210309802A1

  公开（公告）日：2021-10-07

  The present disclosure is directed to raicroporous ladder polymers containing amine-functionalized monomer segments, amidoxime-functionalized monomer segments, or a combination thereof. Monomer compounds for preparation of the polymers are also described, as well as membranes and electrochemical cells containing the polymers.

  本公开涉及含有胺基化单体段、酰胺肟化单体段或两者组合的多孔梯形聚合物。还描述了用于制备聚合物的单体化合物，以及包含聚合物的膜和电化学电池。
• CROSSLINKABLE COMPOSITIONS BASED ON VINYLIDENE FLUORIDE-TRIFLUOROETHYLENE POLYMERS
  申请人：SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

  公开号：US20140378621A1

  公开（公告）日：2014-12-25

  The present invention relates to crosslinkable compositions comprising vinylidene fluoride (VDF)/trifluoroethylene (TrFE) polymers and a fluorine-containing crosslinking agent of formula (A) [agent (Cz)]: N 3 [S(O) g1 ] s1 } na —(R H ) nh —R f —(R′ H ) nh′ —[S(O) g2 ], s2 N 3 } na′ , formula (A) wherein each of g1 and g2, equal to or different from each other, is 1 or 2, each of s1 and s2, equal to or different from each other, is 0 or 1, each of na and na′ is independently zero or an integer of 1 to 3, provided that the sum na+na′ is at least 2, each of R H and R′ H , equal to or different from each other, is a C 1 -C 12 hydrocarbon group free of fluorine atoms, nh and nh′, equal or different from each other are independently 0 or 1, and R f is selected from the group consisting of i) a C 3 -C 20 fluorocarbon group, possibly comprising one or more ethereal oxygen atoms, ii) an oligomer comprising copolymerized units of vinylidene fluoride and trifluoroethylene, to a process for the manufacture of said compositions, to a method for curing the same, and to the use of said copolymers in electrical and electronic devices.

  本发明涉及交联性组合物，其包括乙烯基氟化物（VDF）/三氟乙烯（TrFE）聚合物和含氟交联剂的化学式（A）[剂（Cz）]：N3 [S（O）g1]s1} na—（RH）nh—Rf—（R′H）nh′—[S（O）g2]，s2N3} na′，其中g1和g2分别为1或2，s1和s2分别为0或1，na和na'分别独立地为0或1至3的整数，前提是na + na'至少为2，RHand R′H分别相同或不同，是不含氟原子的C1-C12碳氢基团，nh和nh'相等或不等，独立地为0或1，而Rf选自以下组：i）C3-C20氟碳基团，可能包括一个或多个乙氧基氧原子，ii）包括共聚乙烯基氟化物和三氟乙烯单元的寡聚物。本发明还涉及制造该组合物的方法、固化该组合物的方法以及在电子设备中使用该共聚物的方法。
• Methods for Producing Water-Absorbent Foamed Polymer Particles
  申请人：Lopez Villanueva Francisco Javier

  公开号：US20120232177A1

  公开（公告）日：2012-09-13

  A process for preparing water-absorbing polymer particles, comprising polymerization of a foamed monomer solution or suspension, drying, grinding and classification.

  一种制备吸水性高分子颗粒的方法，包括聚合泡沫单体溶液或悬浮液，干燥，研磨和分类。