2-(2,6-bis((E)-4-diethylaminostyryl)-4H-pyran-4-ylidene)-1,3-indanedione | 1165800-69-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 2-(2,6-bis((E)-4-diethylaminostyryl)-4H-pyran-4-ylidene)-1,3-indanedione
• 英文别名: 2-[2,6-bis[(E)-2-[4-(diethylamino)phenyl]ethenyl]pyran-4-ylidene]indene-1,3-dione
• CAS: 1165800-69-0
• 化学式: C₃₈H₃₈N₂O₃
• 分子量: 570.731
• InChiKey: AVIPWTTZZFDHDY-GJHDBBOXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  43
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  49.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-(2,6-dimethyl-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione 、 N,N-二乙基-4-氨基苯甲醛 在 哌啶 作用下， 以 乙腈 为溶剂， 以50%的产率得到2-(2,6-bis((E)-4-diethylaminostyryl)-4H-pyran-4-ylidene)-1,3-indanedione
  参考文献：
  名称：

  New one- and two-dimensional 4H-pyranylidene NLO-phores

  摘要：

  Dipolar, V-shaped compounds derived from 4H-pyranylidene-linked acceptors have been synthesized, and their linear and nonlinear optical properties (displaying mu beta values up to 3000 x 10(-48) esu) have been compared to those of analogous one-dimensional derivatives. The pyranylidene ring behaves strictly as a spacer, and not as a donor group. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.03.197

文献信息

• New one- and two-dimensional 4H-pyranylidene NLO-phores
  作者：Raquel Andreu、Laura Carrasquer、Javier Garín、María Jesús Modrego、Jesús Orduna、Raquel Alicante、Belén Villacampa、Magali Allain

  DOI：10.1016/j.tetlet.2009.03.197

  日期：2009.6

  Dipolar, V-shaped compounds derived from 4H-pyranylidene-linked acceptors have been synthesized, and their linear and nonlinear optical properties (displaying mu beta values up to 3000 x 10(-48) esu) have been compared to those of analogous one-dimensional derivatives. The pyranylidene ring behaves strictly as a spacer, and not as a donor group. (C) 2009 Elsevier Ltd. All rights reserved.