2-hexyl-adipic acid | 37507-02-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-hexyl-adipic acid
• 英文别名: 2-Hexyl-adipinsaeure；2-Hexyladipinsaeure；n-Hexyladipic acid；2-hexylhexanedioic acid
• CAS: 37507-02-1
• 化学式: C₁₂H₂₂O₄
• 分子量: 230.304
• InChiKey: CQLCSKMKNLINGZ-UHFFFAOYSA-N

物化性质

• 熔点：
  65.4 °C
• 沸点：
  175 °C(Press: 0.2 Torr)
• 密度：
  1.064±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-hexyl-adipic acid 在 氢氧化钾 、 氯化亚砜 作用下， 生成 5-hexyl-adipamic acid
  参考文献：
  名称：

  �ber eine neue Synthese von ?-Alkyladipins�uren

  摘要：

  DOI：

  10.1007/bf01518477
• 作为产物：
  描述：

  1,4-dibromo-decane 在 氢氧化钾 、 乙醇 作用下， 生成 2-hexyl-adipic acid
  参考文献：
  名称：

  Franke; Kroupa, Monatshefte fur Chemie, 1930, vol. 56, p. 349

  摘要：

  DOI：

文献信息

• Ester Compounds, Lubricating Oil Compositions Containing Same and Processes for Making Same
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20190100710A1

  公开（公告）日：2019-04-04

  This disclosure relates to ester compounds derived from neo-alcohol, lubricating oil base stocks comprising such ester compounds, lubricating oil compositions comprising such ester compounds, and method for making such compounds and/or base stocks. The lubricating oil base stocks comprising the ester compounds exhibit desirable lubricating properties such as polarity and oxidation stability.

  本公开涉及从新醇衍生的酯化合物、包含这种酯化合物的润滑油基础油、包含这种酯化合物的润滑油组合物，以及制备这种化合物和/或基础油的方法。包含这种酯化合物的润滑油基础油具有理想的润滑性能，如极性和氧化稳定性。
• PROCESSES FOR PREPARING VINYLIDENE DIMER DERIVATIVES
  申请人：ExxonMobil Research and Engineering Company

  公开号：US20180086682A1

  公开（公告）日：2018-03-29

  This disclosure provides a process for producing vinylidene dimer derivatives by subjecting one or more vinylidene dimers and one or more carbonyl-containing compounds to a carbonyl-ene reaction, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure also provides a process for producing vinylidene dimer derivatives by reacting one or more vinylidene dimers with one or more carbonyl-containing compounds, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure further provides vinylidene dimer derivatives (e.g., vinylidene dimer derived alcohols and esters) produced by these processes. This disclosure still further provides for hydrogenating/reacting the vinylidene dimer derived alcohols with acids or anhydrides to produce vinylidene dimer derived esters. This disclosure yet further relates to lubricating ester oil base stocks, and lubricating oils containing the lubricating ester oil base stocks.

  本公开提供了一种通过将一个或多个乙烯二聚体和一个或多个含羰基化合物置于羰基-烯反应中，可选地在催化剂的存在下，生产一个或多个乙烯二聚体衍生醇的过程。本公开还提供了一种通过将一个或多个乙烯二聚体与一个或多个含羰基化合物反应，可选地在催化剂的存在下，生产一个或多个乙烯二聚体衍生醇的过程。本公开进一步提供了通过这些过程生产的乙烯二聚体衍生物（例如，乙烯二聚体衍生醇和酯）。本公开还提供了将乙烯二聚体衍生醇与酸或酐氧化/反应以生产乙烯二聚体衍生酯的方法。本公开还涉及润滑酯油基础油和含有润滑酯油基础油的润滑油。
• Photosensitive polyurethanes and plates
  申请人：WITCO CHEMICAL CORPORATION

  公开号：EP0186959A1

  公开（公告）日：1986-07-09

  Photopolymeric polyurethanes are provided which have a polymeric backbone including recurring urethane or urea groups or both and which have unsaturated hydrocarbon groups attached to this backbone. These photopolymers are combined with a solvent and have a selected and controlled molecular weight and viscosity. The photopolymeric polyurethane solutions are especially useful in providing plates that have a layer including a photopolymer, particularly plates for printing or photoresists that have a photopolymeric layer over a layer of light sensitive diazonium composition.

  所提供的光聚合物聚氨酯具有聚合物骨架，其中包括重复出现的氨基甲酸乙酯基团或脲基团，或两者兼而有之，并且骨架上连接有不饱和烃基团。这些光聚合物与溶剂结合在一起，具有经过选择和控制的分子量和粘度。光聚合物聚氨酯溶液特别适用于提供具有包括光聚合物层的板材，尤其是在光敏重氮组合物层上具有光聚合物层的印刷板材或光刻胶板材。
• Printed thermoplastic resin products and method for printing such products
  申请人：HAYAKAWA RUBBER COMPANY LIMITED

  公开号：EP0588533A2

  公开（公告）日：1994-03-23

  An easily regeneratable printed thermoplastic resin product is provided by printing it with a specific radiation-curing ink composition and curing the printed ink with radiation to form a cured ink film thereon. The ink composition comprises a vehicle mixture containing : (A) an ingredient selected from the group consisting of a skeletal linear polyester oligomer having 1 to 10 double bonds in a molecule and a polymer of the oligomer, (B) an ingredient selected from the group consisting of a double bond-containing carboxylic acid wherein the acid has at least one acidic group which is capable of forming a water-soluble alkali metal salt in a molecule, a carboxylic ester of the acid and a carboxylic amide of the acid, (C) a double bond-containing polycarboxylic ester, having 2 to 10 acidic groups which are capable of forming an alkali metal salt which will swell with water absorption, (D) an ingredient selected from the group consisting of a fluorinated double bond-containing carboxylic ester wherein the fluorine component is oriented on the surface of a coplymer or polymer to give water-repellency, a block copolymer which comprises a surface-oriented and water-repellent fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and a block copolymer which comprises a surface-oriented and water-repellent siloxane group-containing polymer segment and a (meth)acrylic polymer segment, (E) a double bond-containing polycarboxylic ester, and (F) an ingredient selected from the group consisting of a double bond-containing monocarboxylic ester and its amide, wherein the acid value of the vehicle mixture is from 5 to 100. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.

  通过用特定的辐射固化油墨组合物印刷热塑性树脂产品，并用辐射固化印刷油墨，在其上形成固化油墨膜，提供了一种易于再生的印刷热塑性树脂产品。 油墨组合物包括一种载体混合物，其中含有......： (A) 从以下组别中选出的成分：分子中含有 1 至 10 个双键的骨架线性聚酯低聚物和该低聚物的聚合物； (B) 从以下组别中选出的成分：含双键的羧酸，其中该酸至少有一个酸性基团，能在分子中形成水溶性碱金属盐、(C) 含雙鍵的聚羧酸酯，其中有 2 至 10 個酸性基團，可形成吸水後 會膨脹的鹼金屬鹽、 (D) 从以下组别中选出的一种成分：含氟双键羧酸酯，其中的氟成分在共聚物或聚合物的表面定向，以产生憎水性、(E) 含双键的聚羧酸酯，及 (F) 从含双键单羧酸酯及其酰胺组成的组中选出的成分，其中载体混合物的酸值为 5 至 100。 这种油墨可用于在特定的热塑性产品上显示和装饰商品名称、图案、说明、条形码等，固化后的油墨膜很容易用碱水溶液剥离。
• Radiation curing ink
  申请人：HAYAKAWA RUBBER COMPANY LIMITED

  公开号：EP0588534A2

  公开（公告）日：1994-03-23

  A radiation-curing ink composition contains a vehicle mixture comprising : (A) an ingredient selected from the group consisting of a skeletal linear polyester oligomer having 1 to 10 double bonds in a molecule and a polymer of the oligomer, (B) an ingredient selected from the group consisting of a double bond-containing carboxylic acid wherein the acid has at least one acidic group which is capable of forming a water-soluble alkali metal salt in a molecule, a carboxylic ester of the acid and a carboxylic amide of the acid, (C) a double bond-containing carboxylic ester, having 2 to 10 acidic groups which are capable of forming an alkali metal salt capable of swelling with water absorption, (D) an ingredient selected from the group consisting of a fluorinated double bond-containing carboxylic ester wherein the fluorine component is oriented on the surface of a copolymer or polymer to give water-repellency, a block copolymer which comprises a surface-oriented and water-repellent fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and a block copolymer which comprises a surface-oriented and water-repellent siloxane group-containing polymer segment and a (meth)acrylic polymer segment, (E) a double bond-containing polycarboxylic ester, and (F) an ingredient selected from the group consisting of a double bond-containing carboxylic monoester and its amide, wherein the acid value of the vehicle mixture is from 5 to 100, is provided. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.

  一种辐射固化油墨组合物含有一种载体混合物，该载体混合物包括 ..：(A) 从以下组中选出的成分：分子中含有 1 至 10 个双键的骨架线性聚酯低聚物和该低聚物的聚合物； (B) 从以下组中选出的成分：含双键的羧酸，其中该酸具有至少一个酸性基团，能在分子中形成水溶性碱金属盐、(C) 含雙鍵的羧酸酯，其中有 2 至 10 個酸性基團，能形成能吸水膨脹 的鹼金屬鹽、(D) 从以下组别中选出的成分：含氟双键羧酸酯，其中的氟成分在共聚物或聚合物表面定向，以产生憎水性；嵌段共聚物，包括表面定向和憎水的含氟烷基聚合物段和（甲基）丙烯酸聚合物段；以及嵌段共聚物，包括表面定向和憎水的含氟烷基聚合物段和（甲基）丙烯酸聚合物段、(E) 含双键的聚羧酸酯，和 (F) 从含双键的羧酸单酯及其酰胺组成的组中选出的成分，其中载体混合物的酸值为 5 至 100。 这种油墨可用于在特定的热塑性产品上显示和装饰商品名称、图案、说明、条形码等，而且固化后的油墨膜很容易用碱水溶液剥离。