4-[2-[4-(4-methoxyanilino)phenyl]-1,3-dioxolan-2-yl]-N-(4-methoxyphenyl)aniline | 872447-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[2-[4-(4-methoxyanilino)phenyl]-1,3-dioxolan-2-yl]-N-(4-methoxyphenyl)aniline
• CAS: 872447-03-5
• 化学式: C₂₉H₂₈N₂O₄
• 分子量: 468.552
• InChiKey: BYXNXNNBQVNEII-UHFFFAOYSA-N

物化性质

• 沸点：
  636.2±55.0 °C(Predicted)
• 密度：
  1.240±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  61
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-[2-[4-(4-methoxyanilino)phenyl]-1,3-dioxolan-2-yl]-N-(4-methoxyphenyl)aniline 在 硫酸 作用下， 以 丙酮 为溶剂， 反应 2.0h， 以87%的产率得到di[4-(4-methoxyanilino)phenyl]methanone
  参考文献：
  名称：

  New tetrakis(4-aminophenyl)ethenes: synthesis and electrochemical investigations

  摘要：

  Four novel functional conjugated tetraarylamines containing a tetraphenylenecore were synthesized via Ni-catalyzed aryl amination followed by McMurry olefination. Their electrochemical properties were studied by cyclic voltammetry, coulometry, and electrolysis monitored by UV-vis spectroscopy, and discussed with regard to those of the known tetrakis(dimethylaminophenyl)ethane. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.10.071
• 作为产物：
  描述：

  4,4'-二氯二苯甲酮 在 bis(acetylacetonate)nickel(II) sodium hydride 、 APTS 、 1,3-双-(2,6-二异丙基苯基)咪唑鎓氯化物 、 叔丁醇 作用下， 以 四氢呋喃 、 xylene 为溶剂， 反应 7.0h， 生成 4-[2-[4-(4-methoxyanilino)phenyl]-1,3-dioxolan-2-yl]-N-(4-methoxyphenyl)aniline
  参考文献：
  名称：

  New tetrakis(4-aminophenyl)ethenes: synthesis and electrochemical investigations

  摘要：

  Four novel functional conjugated tetraarylamines containing a tetraphenylenecore were synthesized via Ni-catalyzed aryl amination followed by McMurry olefination. Their electrochemical properties were studied by cyclic voltammetry, coulometry, and electrolysis monitored by UV-vis spectroscopy, and discussed with regard to those of the known tetrakis(dimethylaminophenyl)ethane. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.10.071

文献信息

• New tetrakis(4-aminophenyl)ethenes: synthesis and electrochemical investigations
  作者：Jean-François Kuntz、Raphaël Schneider、Alain Walcarius、Yves Fort

  DOI：10.1016/j.tetlet.2005.10.071

  日期：2005.12

  Four novel functional conjugated tetraarylamines containing a tetraphenylenecore were synthesized via Ni-catalyzed aryl amination followed by McMurry olefination. Their electrochemical properties were studied by cyclic voltammetry, coulometry, and electrolysis monitored by UV-vis spectroscopy, and discussed with regard to those of the known tetrakis(dimethylaminophenyl)ethane. (c) 2005 Elsevier Ltd. All rights reserved.