1-(2-hydroxybenzylideneamino)benzimidazoline-2-thion | 871917-73-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1-(2-hydroxybenzylideneamino)benzimidazoline-2-thion
• CAS: 871917-73-6
• 化学式: C₁₄H₁₁N₃OS
• 分子量: 269.327
• InChiKey: AGLJZQCDLUERPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.29
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.31
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1-(2-hydroxybenzylideneamino)benzimidazoline-2-thion 、 nickel(II) acetate tetrahydrate 以 正丁醇 为溶剂， 以63.5%的产率得到bis[1-(2-hydroxybenzylideneamino)benzimidazoline-2-thionato]nickel(II)
  参考文献：
  名称：

  1-amino-2-thiobenzimidazoleimines as novel ambidentate ligand systems

  摘要：

  Azomethine derivatives of 1-amino-2-thiobenzimidazole (H2L) were synthesized and studied by IR and H-1 NMR spectroscopy. Thiobenzimidazoline tautomeric form of these compounds was found to predominate in a solid state and DMSO solution. Novel mono- and binuclear metal chelates M(HL)(2) and M2L2 (M = Ni(II), Cu(II), Co(II), Zn(II), Cd(II)) were synthesized on the basis of H2L derivatives and their composition and structures were established from IR, H-1 NMR, EXAFS, and magnetochemical data. The composition of coordination sphere was shown to produce no effect on ferromagnetic exchange in binuclear Cu(II) complexes.

  DOI：

  10.1134/s1070328407030049