Tris(4-nonylphenyl)phosphane | 76287-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Tris(4-nonylphenyl)phosphane
• CAS: 76287-48-4
• 化学式: C₄₅H₆₉P
• 分子量: 641.017
• InChiKey: JNJGSDYMEKOBPD-UHFFFAOYSA-N

物化性质

• 沸点：
  677.1±54.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  18.4
• 重原子数：
  46
• 可旋转键数：
  27
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Tris(4-nonylphenyl)phosphane 在 双氧水 作用下， 生成 tris-nonylphenylphosphine oxide
  参考文献：
  名称：

  Franks, Stephen; Hartley, Frank R., Journal of the Chemical Society. Perkin transactions I, 1980, p. 2233 - 2237

  摘要：

  DOI：
• 作为产物：
  描述：

  正辛基镁溴盐 在 platinum(IV) oxide potassium hydrogensulfate 、 氢气 、 三氯化磷 作用下， 以 四氢呋喃 、 乙醚 、 乙醇 为溶剂， 反应 2.0h， 生成 Tris(4-nonylphenyl)phosphane
  参考文献：
  名称：

  Franks, Stephen; Hartley, Frank R., Journal of the Chemical Society. Perkin transactions I, 1980, p. 2233 - 2237

  摘要：

  DOI：

文献信息

• Complexes of long alkyl chain tertiary phosphines. Part I. The preparation and characterization of platinum metal complexes of long-chain tertiary phosphine ligands
  作者：S. Franks、F.R. Hartley

  DOI：10.1016/s0020-1693(00)89336-6

  日期：1981.1

  Abstract The long chain tertiary phosphine ligands (P(CnH2n+1)3 and P CmH2m·1)3 have been used to prepare the following series of platinum, palladium and rhodium complexes: cis-[PtL2Cl2], trans-[PdL2Cl2], trans-[PtL2HCl] (L = trialkylphosphine only), [PtL4] and trans-[RhL2Cl(CO)]. The complexes are very soluble in chlorinated solvents and both aliphatic and aromatic hydrocarbons as well as tetrahydrofuran

  摘要长链叔膦配体（P（CnH2n + 1）3和P CmH2m·1）3已用于制备以下系列的铂，钯和铑配合物：顺式[PtL2Cl2]，反式[PdL2Cl2]，反式-[PtL2HCl]（仅L =三烷基膦），[PtL4]和反式-[RhL2Cl（CO）]。该络合物在氯化溶剂，脂族和芳族烃以及四氢呋喃中都非常易溶，但不溶于或仅微溶于极性溶剂（如醇，丙酮和二乙醚）中。许多配合物是结晶固体，其纯化仅需小心。但是，必须格外小心地选择许多蜡或油，以及所用的制备路线和后处理程序。
• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Epoxy resin composition
  申请人：——

  公开号：US20020022681A1

  公开（公告）日：2002-02-21

  An epoxy resin composition comprising (A) an epoxy resin, (B) a curing agent, and (C) a silicone stress-reducing agent further includes (D) a foam-suppressing composition comprising (D-i) an oil compound consisting of a hydrophobic organopolysiloxane and finely divided silica, (D-ii) a hydrophilic polyoxyalkylene-modified silicone oil, and optionally, (D-iii) a polyoxyalkylene polymer. The epoxy resin composition has the advantages of improved infiltration to semiconductor device-substrate gaps and minimized formation of internal and surface voids.

  一种环氧树脂组合物，包括（A）环氧树脂，（B）固化剂和（C）硅应力减少剂，还包括（D）一种抑制泡沫形成的组合物，包括（D-i）由疏水有机聚硅氧烷和细分硅组成的油类化合物，（D-ii）亲水性聚氧烷改性硅油，以及可选的（D-iii）聚氧烷聚合物。该环氧树脂组合物具有改善对半导体器件基板间隙的渗透和最小化内部和表面空洞形成的优点。
• LIGHT DIFFUSIVE POLYCARBONATE RESIN COMPOSITION AND LIGHT DIFFUSIVE PLATE USING SAID RESIN COMPOSITION
  申请人：Kogure Masami

  公开号：US20090080079A1

  公开（公告）日：2009-03-26

  The present invention provides a light-diffusive polycarbonate-based resin composition which includes (A) 100 parts by mass of an aromatic polycarbonate resin, (B) 0.01 to parts by mass of a light-diffusing agent, and (C) 0.1 to parts by mass of a styrene-(meth)acrylic ester copolymer, and a light-diffusing plate formed from the composition. The light-diffusive polycarbonate-based resin composition can be injection-molded to form a light-diffusing plate having satisfactory precision in thickness for use in comparatively large liquid crystal displays having a size larger than 20 inches.

  本发明提供了一种光扩散的基于聚碳酸酯的树脂组合物，包括（A）100份质量部的芳香族聚碳酸酯树脂，（B）0.01至份质量部的光扩散剂，以及（C）0.1至份质量部的苯乙烯-（甲基）丙烯酸酯共聚物，以及由该组合物形成的光扩散板。该光扩散的基于聚碳酸酯的树脂组合物可以注塑成形，形成具有满意的厚度精度的光扩散板，用于比20英寸更大的液晶显示器。
• ACRYLIC ESTER COMPOUND AND MANUFACTURING INTERMEDIATE THEREOF, METHOD FOR MANUFACTURING ACRYLIC ESTER COMPOUND, AND LATENT ELECTROSTATIC IMAGE BEARING MEMBER, IMAGE FORMING METHOD, IMAGE FORMING APPARATUS AND PROCESS CARTRIDGE
  申请人：HORIUCHI Tamotsu

  公开号：US20110287353A1

  公开（公告）日：2011-11-24

  To provide: a latent electrostatic image bearing member including one of a cured material obtained through radical polymerization of a radically polymerizable compound of component (A1), and a cured material obtained through radical polymerization of a radically polymerizable compound of component (A2) in the outermost layer, wherein the component (A1) includes two radically polymerizable groups and a substituted amino group which does not include a radically polymerizable group in a molecule, and the radically polymerizable group and the nearest substituted amino group which does not include an unsaturated bond in between are connected with two or more aromatic hydrocarbon compounds, and, the radically polymerizable compound of component (A2) includes a condensed polycyclic aromatic hydrocarbon formed by bonding a radically polymerizable group and a non-radically polymerizable substituted amine group through a condensed polycyclic aromatic hydrocarbon group; and an image forming apparatus, image forming method and process cartridge which uses thereof.

  提供一种潜在的静电图像承载成员，包括通过组分（A1）的自由基聚合获得的固化材料之一，以及在最外层通过组分（A2）的自由基聚合获得的固化材料，其中组分（A1）包括两个自由基聚合基团和一个分子中不包含自由基聚合基团的取代氨基团，并且最近的不包含不饱和键的取代氨基团与自由基聚合基团之间连接有两个或更多芳香族碳氢化合物，而组分（A2）的自由基聚合化合物包括通过连接一个自由基聚合基团和一个非自由基聚合取代胺基团的环状多环芳香族碳氢化合物形成的缩聚多环芳香族碳氢化合物；以及使用该承载成员的图像形成设备、图像形成方法和处理盒。