1-[1'-(9"-fluorenyl)-2'-naphthyl]indan-1-ol | 719278-28-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1-[1'-(9"-fluorenyl)-2'-naphthyl]indan-1-ol
• 英文别名: 1-[1-(9H-fluoren-9-yl)naphthalen-2-yl]-2,3-dihydroinden-1-ol
• CAS: 719278-28-1
• 化学式: C₃₂H₂₄O
• 分子量: 424.542
• InChiKey: RZOCHGVHPAEBCV-UHFFFAOYSA-N

物化性质

• 沸点：
  627.1±24.0 °C(Predicted)
• 密度：
  1.266±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-[1'-(9"-fluorenyl)-2'-naphthyl]indan-1-ol 在 对甲苯磺酸 作用下， 以 苯 为溶剂， 反应 0.33h， 以72%的产率得到9-[2'-(3"-indenyl)-1'-naphthyl]fluorene
  参考文献：
  名称：

  Zirconocene dichloride complexes with a 1,2-naphthylidene bridge as catalysts for the polymerisation of ethylene and propylene

  摘要：

  Ansa-zirconocene dichloride complexes containing a 9-fluorenyl group at the 1-position of naphthalene and a 2-indenyl 12, 1-indenyl 13, or cyclopentadienyl 14 group at the 2-position of the naphthalene were synthesised and characterised. The molecular structures of the complexes have been determined by single crystal X-ray diffraction studies. After activation with excess methyl-alumoxane (MAO). the complexes were used as homogeneous catalysts for the homopolymerisation of ethylene and propylene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.021
• 作为产物：
  描述：

  isopropyl 1-bromonaphthalene-2-carboxylate 在 正丁基锂 、 ethylene diamine tetraacetic acid tetrasodium salt 、 sodium hydride 、 碳酸氢钠 、 magnesium 、 丙酮 作用下， 以 四氢呋喃 、 正己烷 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 45.83h， 生成 1-[1'-(9"-fluorenyl)-2'-naphthyl]indan-1-ol
  参考文献：
  名称：

  Zirconocene dichloride complexes with a 1,2-naphthylidene bridge as catalysts for the polymerisation of ethylene and propylene

  摘要：

  Ansa-zirconocene dichloride complexes containing a 9-fluorenyl group at the 1-position of naphthalene and a 2-indenyl 12, 1-indenyl 13, or cyclopentadienyl 14 group at the 2-position of the naphthalene were synthesised and characterised. The molecular structures of the complexes have been determined by single crystal X-ray diffraction studies. After activation with excess methyl-alumoxane (MAO). the complexes were used as homogeneous catalysts for the homopolymerisation of ethylene and propylene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.021

文献信息

• Zirconocene dichloride complexes with a 1,2-naphthylidene bridge as catalysts for the polymerisation of ethylene and propylene
  作者：Helmut G Alt、Robert W Baker、Mahmoud Dakkak、Michael A Foulkes、Marc O Schilling、Peter Turner

  DOI：10.1016/j.jorganchem.2004.03.021

  日期：2004.6

  Ansa-zirconocene dichloride complexes containing a 9-fluorenyl group at the 1-position of naphthalene and a 2-indenyl 12, 1-indenyl 13, or cyclopentadienyl 14 group at the 2-position of the naphthalene were synthesised and characterised. The molecular structures of the complexes have been determined by single crystal X-ray diffraction studies. After activation with excess methyl-alumoxane (MAO). the complexes were used as homogeneous catalysts for the homopolymerisation of ethylene and propylene. (C) 2004 Elsevier B.V. All rights reserved.