5,14-Dihydro-7,16-diethyldibenzo<1,4,8,11>tetraazacyclotetradecine | 55424-76-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 5,14-Dihydro-7,16-diethyldibenzo<1,4,8,11>tetraazacyclotetradecine
• 英文别名: 5,14-dihydro-7,16-diethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine；5,16-dihydro-3,14-diethyldibenzo{b,i}{1,4,8,11}tetraazacyclotetradecine；7,16-diethyl-5,14-dihydro-5,9,14,18-tetraaza-dibenzo[a,h]cyclotetradecene
• CAS: 55424-76-5
• 化学式: C₂₂H₂₄N₄
• 分子量: 344.459
• InChiKey: RFANXBRQOINCEZ-FRKMIVHASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.22
• 重原子数：
  26.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  48.78
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  5,14-Dihydro-7,16-diethyldibenzo<1,4,8,11>tetraazacyclotetradecine 在 palladium(II) sodium chloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以41%的产率得到(7,16-diethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II)
  参考文献：
  名称：

  Preparation and characterization of zinc(II) and palladium(II) complexes with 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo[b,i][1,4,8,11]-tetraazacyclotetradecine

  摘要：

  The zinc(II) and palladium(II) complexes of 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo [b,i][1,4,8,11] tetraazacyclotetradecine (HL(1)) and 5,14-dihydro-7,16-diethyldibenzo[b,i] [1,4,8,11]tetraazacyclotetradecine (H(2)L(2)) have been synthesized and their spectroscopic data determined. The absorption bands of ML(1)X (M = Zn,Pd; X = Cl, NCS, ClO4) observed in the 20,400-23,900 cm(-1) region were attributable to pi-pi* and charge transfer transitions. Those bands for the three palladium(II) complexes (PdL(1)X) are similar to each other in various solvents, but the bands of ZnL(1)X are slightly different from one another. The C-13 NMR signals for NiL(1)(ClO4) and PdL(1)(ClO4) are similar to each other, but the C(15) and C(17) carbon signals for ZnL(1)(ClO4) exhibit downfield shifts upon metal coordination. Judging from the molar conductances for the complexes, ZnL(1)(ClO4) and PdL(1)X (X = Cl, NCS, ClO4) are 1:1 electrolytes in acetonitrile and nitromethane, but ZnL(1)Cl and ZnL(1) (NCS) are non-electrolytes. The treatment of PdL(1)X (X=Cl, NCS, ClO4) in methanol solution with an excess of base in air gave (7-ethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) (PdL(3)). Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00342-7
• 作为产物：
  描述：

  (2E)-2-(trimethylsilyloxymethylidene)butanal 、 邻苯二胺 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以19%的产率得到5,14-Dihydro-7,16-diethyldibenzo<1,4,8,11>tetraazacyclotetradecine
  参考文献：
  名称：

  由3-三甲基甲硅烷氧基丙烯醛合成二苯并四氮杂[14]环戊烯

  摘要：

  DOI：

  10.1007/bf00529587

文献信息

• Preparation and characterization of a cyanocobalt(III) complex with tetraaza[14]annulene
  作者：Kazunori Sakata、Takamichi Annoura、Mamoru Hashimoto

  DOI：10.1016/s0020-1693(00)90586-3

  日期：1988.11

  Caracterisation de complexes macrocycliques du cobalt (III) au moyen de la spectrometrie RMN, IR et UV-visible. Effets de solvant sur la liaison Co−CN

  钴（III）分光光度法大分子络合物RMN，红外光谱和紫外可见光谱。索菲河联络处
• Condensation of o-phenylene diamine and substituted acroleins to form macroheterocycles
  作者：Yu. G. Yatluk、A. L. Suvorov

  DOI：10.1007/bf00761992

  日期：1987.3
• Hashimoto, Mamoru; Tagami, Hidetoshi; Sakata, Kazunori, Journal of Heterocyclic Chemistry, 1990, vol. 27, # 5, p. 1265 - 1271
  作者：Hashimoto, Mamoru、Tagami, Hidetoshi、Sakata, Kazunori

  DOI：——

  日期：——
• Preparation and spectral properties of nickel(II) and chloroiron(III) complexes with a macrocyclic N4-ligand: 5,14-dihydro-7,16-diethyldibenzo [b,i] [1,4,8,11]tetraazacyclotetradecine
  作者：Kazunori Sakata、Mamoru Hashimoto、Tsutomu Naganawa

  DOI：10.1016/s0020-1693(00)90739-4

  日期：1985.3
• YATLUK YU. G.; SUVOROV A. L., XIMIYA GETEROTSIKL. SOED.,(1987) N 3, 376-381
  作者：YATLUK YU. G.、 SUVOROV A. L.

  DOI：——

  日期：——