4-methyl-4'-trimethylsilanyl-benzophenone | 18105-93-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-methyl-4'-trimethylsilanyl-benzophenone
• 英文别名: 4-Methyl-4'-trimethylsilyl-benzophenon；4-Methyl-4'-(trimethylsilyl)-benzophenon；(4-Methylphenyl)[4-(trimethylsilyl)phenyl]methanone；(4-methylphenyl)-(4-trimethylsilylphenyl)methanone
• CAS: 18105-93-6
• 化学式: C₁₇H₂₀OSi
• 分子量: 268.431
• InChiKey: FOEPZPFZHSWYGX-UHFFFAOYSA-N

物化性质

• 熔点：
  44-44.5 °C
• 沸点：
  159-162 °C(Press: 0.5 Torr)
• 密度：
  1.01±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.77
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  对甲苯腈 、 (4-(trimethylsilyl)phenyl)magnesium bromide 生成 4-methyl-4'-trimethylsilanyl-benzophenone
  参考文献：
  名称：

  Friedel-Crafts Acylations with Trimethylsilylbenzoyl Chlorides

  摘要：

  DOI：

  10.1021/ja01631a081

文献信息

• Process for the production of modified polysiloxane-coated sanitary
  申请人：Daikyo Gomu Seiko Ltd.

  公开号：US05110621A1

  公开（公告）日：1992-05-05

  A sanitary rubber article having an improved surface property to be useful as rubber parts of medical instruments or machines and as rubber articles for medicaments is provided. This sanitary rubber article is coated, through bridging and bonding, with a modified polysiloxane composition comprising a modified polysiloxane having at least one modifying group selected from the group consisting of alkenyl, acryloyl, vinyloxy, maleimide and phenylketone groups in the molecule.

  提供一种具有改善表面性能的卫生橡胶制品，可用作医疗仪器或机器的橡胶零件和药品橡胶制品。该卫生橡胶制品通过桥接和结合，涂覆有改性聚硅氧烷组成的复合物，该复合物包括至少一种改性基团，所述改性基团选自烯基，丙烯酰基，氧乙基乙烯基，马来酰亚胺和苯基酮基团。
• Modified polysiloxane-coated sanitary rubber article and a process for
  申请人：Daikyo Gomu Seiko Ltd.

  公开号：US05114794A1

  公开（公告）日：1992-05-19

  A sanitary rubber article having an improved surface property to be useful as rubber parts of medical instruments or machines and as rubber articles for medicaments is provided. This sanitary rubber article is coated, through bridging and bonding, with a modified polysiloxane composition comprising a modified polysiloxane having at least one modifying group selected from the group consisting of alkenyl, acryloyl, vinyloxy, maleimide and phenylketone groups in the molecule.

  提供一种具有改进表面性能的卫生橡胶制品，可用作医疗仪器或机器的橡胶零件和药品橡胶制品。该卫生橡胶制品经过桥接和结合，涂覆有一种改性聚硅氧烷组合物，该组合物包括具有至少一种修饰基团的改性聚硅氧烷，所述修饰基团选自烯基、丙烯酰基、氧乙烯基、马来酰亚胺和苯基酮基团。
• Dey,K. et al., Organometallics in Chemical Synthesis, 1970, vol. 1, p. 151 - 160
  作者：Dey,K. et al.

  DOI：——

  日期：——
• Friedel-Crafts Acylations with Trimethylsilylbenzoyl Chlorides
  作者：Robert A. Benkeser、Henry R. Krysiak

  DOI：10.1021/ja01631a081

  日期：1954.1