2-chloro-3-[4-(5-dimethylaminonapthalene-1-sulfonyl)-piperazine]-1,4-napthoquinone | 871250-19-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-chloro-3-[4-(5-dimethylaminonapthalene-1-sulfonyl)-piperazine]-1,4-napthoquinone
• 英文别名: 2-Chloro-3-[4-[5-(dimethylamino)naphthalen-1-yl]sulfonylpiperazin-1-yl]naphthalene-1,4-dione；2-chloro-3-[4-[5-(dimethylamino)naphthalen-1-yl]sulfonylpiperazin-1-yl]naphthalene-1,4-dione
• CAS: 871250-19-0
• 化学式: C₂₆H₂₄ClN₃O₄S
• 分子量: 510.013
• InChiKey: ZWABUFZUKAUXKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  86.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2-chloro-3-[4-(5-dimethylaminonapthalene-1-sulfonyl)-piperazine]-1,4-napthoquinone 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 生成 2-Chloro-3-[4-(5-dimethylamino-naphthalene-1-sulfonyl)-piperazin-1-yl]-naphthalene-1,4-diol
  参考文献：
  名称：

  A novel all-organic chemical and electrochemical fluorescent switch

  摘要：

  A three-component molecular system capable of switching fluorescence ON and OFF was designed and synthesized. The new redox-activator optical signal generator is an 'all-organic' system composed of 2-chloronaphthoquinone connected to 5-dimethylaminonaphthalene via a non-conjugating piperazine spacer. Both chemo- and electrophotoswitching capabilities were demonstrated. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.09.127
• 作为产物：
  描述：

  2-Chloro-3-[4-(5-dimethylamino-naphthalene-1-sulfonyl)-piperazin-1-yl]-naphthalene-1,4-diol 在 双氧水 作用下， 生成 2-chloro-3-[4-(5-dimethylaminonapthalene-1-sulfonyl)-piperazine]-1,4-napthoquinone
  参考文献：
  名称：

  A novel all-organic chemical and electrochemical fluorescent switch

  摘要：

  A three-component molecular system capable of switching fluorescence ON and OFF was designed and synthesized. The new redox-activator optical signal generator is an 'all-organic' system composed of 2-chloronaphthoquinone connected to 5-dimethylaminonaphthalene via a non-conjugating piperazine spacer. Both chemo- and electrophotoswitching capabilities were demonstrated. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.09.127

文献信息

• A novel all-organic chemical and electrochemical fluorescent switch
  作者：R.A. Illos、E. Harlev、S. Bittner

  DOI：10.1016/j.tetlet.2005.09.127

  日期：2005.11

  A three-component molecular system capable of switching fluorescence ON and OFF was designed and synthesized. The new redox-activator optical signal generator is an 'all-organic' system composed of 2-chloronaphthoquinone connected to 5-dimethylaminonaphthalene via a non-conjugating piperazine spacer. Both chemo- and electrophotoswitching capabilities were demonstrated. (c) 2005 Elsevier Ltd. All rights reserved.