N-(N-phenylacetyl-glycyl)-DL-penicillamine | 879553-97-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(N-phenylacetyl-glycyl)-DL-penicillamine
• 英文别名: N-(N-phenylacetyl-glycyl)-penicillamine；N-(N-Phenylacetyl-glycyl)-penicillamin；N-(N-Phenylacetyl-glycyl)-DL-penicillamin
• CAS: 879553-97-6
• 化学式: C₁₅H₂₀N₂O₄S
• 分子量: 324.401
• InChiKey: DEDRCZRTRSEXSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.62
• 重原子数：
  22.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  95.5
• 氢给体数：
  4.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  N-(N-phenylacetyl-glycyl)-DL-penicillamine 在 盐酸 作用下， 生成 5,5-dimethyl-2-[(2-phenyl-acetylamino)-methyl]-4,5-dihydro-thiazole-4-carboxylic acid ; hydrochloride
  参考文献：
  名称：

  Bachmann; Cronyn, Chemistry of Penicillin

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氨 、 sodium 作用下， 生成 N-(N-phenylacetyl-glycyl)-DL-penicillamine
  参考文献：
  名称：

  Coesite inclusions in zircon from gneisses identified by laser Raman microspectrometer in ultrahigh pressure zone of Dabie Mountains, China

  摘要：

  The mineral inclusions in zircon from gneisses in ultra-high pressure (UHP) zone of the Dable Mountains were identified by using a laser Raman microspectrometer. Coesite occurs as inclusions in zircons from all types of gneiss. Other important minerals, such as jadeite, omphacite, aragonite, barite, and anhydrite were also found as inclusion minerals. These discoveries indicate that (i) gneissic country rocks had metamorphosed at the same time as the enclosed eclogites; and (ii) SO4-2-bearing fluids were present in the UHP metamorphic process, which is manifested by occurrence of barite and anhydrite coexisting with coesite.

  DOI：

  10.1007/bf02901171

文献信息

• Effect of Mn cluster on the formation of Superoxide radicals in photoinhibition of photosystem II
  作者：Suping Zhang、Tiecheng Tu、Jun Weng、Jingxi Pan、Chunhe Xu、Side Yao

  DOI：10.1007/bf02901162

  日期：2001.11

  To further realize the action of superoxide radicals (O-2(-.)) in photoinhibition of photosystem II (PS II), we employed 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap, associated with EPR spectroscopy, to study the effect of illumination time on O-2(-.) formation during high light photoinhibition in PS II membranes and Mn-depleted PS II membranes. Results indicated that the removal of Mn cluster from PS II membranes has a strong influence on the dynamics of superoxide formation. The relative mechanism was also discussed. These novel findings may further promote the studies of the structure and function of PS II and the mechanism of photoinhibition.
• Knunjanz; Schokina, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955, p. 462,467; engl. Ausg. S. 409, 413
  作者：Knunjanz、Schokina

  DOI：——

  日期：——
• Knunjanz et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959, p. 1777,1781
  作者：Knunjanz et al.

  DOI：——

  日期：——
• Sues, Justus Liebigs Annalen der Chemie, 1949, vol. 564, p. 54,62
  作者：Sues

  DOI：——

  日期：——