| 651329-73-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 651329-73-6
• 化学式: C₈H₁₆N*C₃₆H₂₉BP
• 分子量: 629.633
• InChiKey: IZFINKPTCGUUGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.21
• 重原子数：
  47.0
• 可旋转键数：
  7.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  (1,5-cyclooctadiene)dimethylplatinum(II) 、 以 not given 为溶剂， 生成 (5-azonia-spiro[4.4]nonane)2((Ph3BP(m-Ph2))2PtMe2)
  参考文献：
  名称：

  Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis

  摘要：

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.

  DOI：

  10.1021/ic0350234
• 作为产物：
  描述：

  四氢呋喃 、 三苯基硼烷 、 (3-bromophenyl)diphenylphosphine 、 叔丁基锂 、 5-氮鎓螺[4.4]壬烷溴化物 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis

  摘要：

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.

  DOI：

  10.1021/ic0350234