4-chlorobenzyl methacrylate | 84072-97-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-chlorobenzyl methacrylate
• 英文别名: (4-Chlorophenyl)methyl 2-methylprop-2-enoate
• CAS: 84072-97-9
• 化学式: C₁₁H₁₁ClO₂
• 分子量: 210.66
• InChiKey: PKXZMCUFRWLMBT-UHFFFAOYSA-N

物化性质

• 沸点：
  279.5±15.0 °C(Predicted)
• 密度：
  1.156±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-chlorobenzyl methacrylate 、 苯甲酰甲酸 在 2,4,5,6-四(9H-咔唑-9-基)异酞腈 、 potassium tert-butylate 作用下， 以 乙腈 为溶剂， 以65%的产率得到C₁₈H₁₇ClO₃
  参考文献：
  名称：

  α-酮酸选择性光氧化还原脱羧为烯丙基酮和1,4-二羰基化合物，取决于钴肟的催化作用。

  摘要：

  描述了光氧化还原/钴肟共催化的α-酮酸和甲基丙烯酸酯的偶联反应，以获得烯丙基酮。如果没有钴肟肟催化剂，则会生成1,4-二羰基化合物。该钴肟肟催化剂能够脱氢以生成新的烯烃。通用性，良好的底物范围和温和的条件是光氧化还原/钴氧肟催化方案的良好特征，该方法将为更多烯烃的功能化提供新的机会。

  DOI：

  10.1039/d0cc05580h
• 作为产物：
  描述：

  巴豆酰氯 、 4-氯苯甲醇 在 三乙胺 作用下， 生成 4-chlorobenzyl methacrylate
  参考文献：
  名称：

  α-酮酸选择性光氧化还原脱羧为烯丙基酮和1,4-二羰基化合物，取决于钴肟的催化作用。

  摘要：

  描述了光氧化还原/钴肟共催化的α-酮酸和甲基丙烯酸酯的偶联反应，以获得烯丙基酮。如果没有钴肟肟催化剂，则会生成1,4-二羰基化合物。该钴肟肟催化剂能够脱氢以生成新的烯烃。通用性，良好的底物范围和温和的条件是光氧化还原/钴氧肟催化方案的良好特征，该方法将为更多烯烃的功能化提供新的机会。

  DOI：

  10.1039/d0cc05580h

文献信息

• Process for the manufacture of benzyl methacrylate and its derivatives
  申请人：Elf Atochem S.A.

  公开号：US05169980A1

  公开（公告）日：1992-12-08

  This process for the manufacture of benzyl methacrylate and of its halogenated or alkylated derviatives by the reaction of benzyl chloride or of one of its halogenated or alkylated derivatives with an alkali metal methacrylate is characterized in that the reaction is carried out in the presence of not more than 3 mol %, based on the benzyl chloride or a derivative, of a tertiary amine. The alkali metal is chosen especially from lithium, potassium and sodium. The tertiary amine is preferably a tertiary diamine of general formula: ##STR1## in which n is an integer ranging from 1 to 10 and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which are identical or different, are alkyl, cycloalkyl or aryl radicals containing from 1 to 12 carbon atoms, functionalized if appropriate and, if appropriate, such that they form a heterocyclic ring with the nitrogen atom(s) carrying them.

  这种用苄基氯或其卤代或烷基衍生物与碱金属甲基丙烯酸酯反应制备苄基丙烯酸苄酯及其卤代或烷基化衍生物的工艺过程的特点在于，在存在不超过苄基氯或其衍生物的3摩尔％的情况下，使用三级胺进行反应。碱金属特别选择自锂、钾和钠。三级胺最好是一般式为的三级二胺：##STR1##其中n是1到10的整数，R.sub.1、R.sub.2、R.sub.3和R.sub.4是相同或不同的烷基、环烷基或含有1到12个碳原子的芳基，如有必要经功能化处理，如有必要，它们与氮原子形成杂环。
• Fine polymer particles having heterogeneous phase structure, silver halide photographic light- sensitive material containing the fine polymer particles and image-forming method
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0716338A2

  公开（公告）日：1996-06-12

  Latex polymer of fine particles having a heterogeneous phase structure which comprises a core of a polymer having repeating units derived from a conjugated diene monomer and a shell of a polymer having repeating units derived from at least one ethylenically unsaturated monomer carrying an active methylene group; a silver halide photographic light-sensitive material comprises a core/shell latex polymer whose shell consists of a polymer having repeating units of an ethylenically unsaturated monomer represented by the formula: CH₂=C(R¹)-L-X (wherein R¹ represents H, alkyl or halogen, L represents a single bond or a bivalent coupling group, X represents an active methylene group, provided that L is bonded to X in the form of alkylene; and a method for forming images on a silver halide light-sensitive material which comprises exposing the material which comprises at least one light-sensitive silver halide emulsion layer and at least one hydrophilic colloidal layer either of which comprises a latex polymer having active methylene groups and developing the exposed material with a developer which comprises a dihydroxybenzene developing agent and an auxiliary developing agent showing superadditivity, the pH increase observed when adding 0.1mole/ℓ developer of NaOH to the developer ≦ 0.25; 9.5 ≦ initial pH of the developer ≦ 11.0; the amount of the developer supplemented≦ 225 ml/m².

  具有异相结构的细颗粒乳胶聚合物，其核由具有来自共轭二烯单体的重复单元的聚合物组成，壳由具有来自至少一种带有活性亚甲基的乙烯不饱和单体的重复单元的聚合物组成；卤化银感光材料由核/壳乳胶聚合物组成，其壳由具有由式表示的乙烯不饱和单体的重复单元的聚合物组成：CH₂=C(R¹)-L-X(其中R¹代表H、烷基或卤素，L代表单键或二价偶联基团，X代表活性亚甲基，条件是L以亚烷基的形式与X键合)；以及一种在卤化银感光材料上形成图像的方法，该方法包括曝光该材料，该材料包括至少一个感光卤化银乳剂层和至少一个亲水胶体层，其中任一亲水胶体层包括具有活性亚甲基的乳胶聚合物，并用显影剂显影曝光的材料，该显影剂包括二羟基苯显影剂和显示超加成性的辅助显影剂，当加入 0.1mole/ℓ 显影剂的 NaOH 时观察到的 pH 值增加 ≦ 0.25；9.5 ≦ 显影剂的初始 pH ≦ 11.0；补充的显影剂量 ≦ 225 ml/m²。
• FOUR COMPONENT COPOLYMER AND THE OCULAR LENS MADE THEREOF
  申请人：SANTEN PHARMACEUTICAL CO., LTD

  公开号：EP1026182A1

  公开（公告）日：2000-08-09

  This invention relates to a hydrophilic copolymer, which is suitable for the production of ocular lens such as intraocular lens or contact lens, particularly suitable for foldable intraocular lens, and also to the intraocular lens made thereof.

  本发明涉及一种亲水共聚物，它适用于生产眼内透镜或隐形眼镜等眼科晶状体，尤其适用于可折叠眼内透镜，还涉及用它制成的眼内透镜。
• Water-based coating composition, infrared absorbing film, and photothermographic material by use thereof
  申请人：——

  公开号：US20030186180A1

  公开（公告）日：2003-10-02

  A water-based coating composition is disclosed, comprising a latex comprising a polymer impregnated with an infared absorbing compound and a water-soluble polyester or latex comprising polyer containing an active methylene group. An infrared absorbing film and a photothermographic material by use thereof are also disclosed.

  本发明公开了一种水基涂料组合物，它包括一种由浸渍有红外吸收化合物的聚合物组成的胶乳和一种由含有活性亚甲基的聚合物组成的水溶性聚酯或胶乳。此外，还公开了一种红外线吸收薄膜和使用该薄膜的光热成像材料。
• Radiographic intensifying screen
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US20030226979A1

  公开（公告）日：2003-12-11

  A radiographic intensifying screen is composed of a support and a phosphor layer. The phosphor layer contains a terbium activated gadolinium oxysulfide phosphor. The screen contains a fluorescent dye or pigment which absorbs a portion of luminescence emitted by the oxysulfide phosphor and then emits a light having an emission peak in the wavelength resion of 490 to 600 nm.

  射线增强屏由支架和荧光粉层组成。荧光层含有铽活化钆氧化硫荧光粉。荧光屏中含有一种荧光染料或颜料，它能吸收一部分由氧化硫荧光粉发出的荧光，然后发出具有 490 至 600 纳米波长共振发射峰的光。