3,7-diacetyl-10-n-hexylphenothiazine | 863030-27-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 3,7-diacetyl-10-n-hexylphenothiazine
• 英文别名: 2,7-diacetyl-10-n-hexylphenothiazine；1-(7-Acetyl-10-hexylphenothiazin-3-yl)ethanone；1-(7-acetyl-10-hexylphenothiazin-3-yl)ethanone
• CAS: 863030-27-7
• 化学式: C₂₂H₂₅NO₂S
• 分子量: 367.512
• InChiKey: UWLDLRNFDBRKRX-UHFFFAOYSA-N

物化性质

• 沸点：
  555.7±50.0 °C(Predicted)
• 密度：
  1.136±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  62.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  吩噻嗪 在 氢氧化钾 、 三氯化铝 作用下， 以 二硫化碳 、 N,N-二甲基甲酰胺 为溶剂， 生成 3,7-diacetyl-10-n-hexylphenothiazine
  参考文献：
  名称：

  New Series of Light-Emitting Polyquinolines Containing 9,9‘-Spirobifluorene Units

  摘要：

  A new series of polyquinoline copolymers (P1-P5) containing 9,9'-spirobifluorene in the main chain were synthesized via Friedlander reactions. The emission colors of the polymers were readily tuned from blue to yellow by changing the conjugated counits. Excellent EL performances were obtained for P5, probably because the proper donor/acceptor pairs were rightly matched, and the charge transport was significantly balanced. The devices based on P5 showed a maximum external quantum efficiency of 0.63% and a maximum photometric efficiency of 1.85 cd/A (at a brightness of 140 cd/m(2)). Yellow-green EL with narrow full width at the half-maximum (fwhm < 70 nm) and the highest maximum luminance (1768 cd/m(2)) among the currently reported polyquinolines was obtained for P5.

  DOI：

  10.1021/ma050741q

文献信息

• New Series of Light-Emitting Polyquinolines Containing 9,9‘-Spirobifluorene Units
  作者：Bing Huang、Jun Li、Zuoquan Jiang、Jingui Qin、Gui Yu、Yunqi Liu

  DOI：10.1021/ma050741q

  日期：2005.8.1

  A new series of polyquinoline copolymers (P1-P5) containing 9,9'-spirobifluorene in the main chain were synthesized via Friedlander reactions. The emission colors of the polymers were readily tuned from blue to yellow by changing the conjugated counits. Excellent EL performances were obtained for P5, probably because the proper donor/acceptor pairs were rightly matched, and the charge transport was significantly balanced. The devices based on P5 showed a maximum external quantum efficiency of 0.63% and a maximum photometric efficiency of 1.85 cd/A (at a brightness of 140 cd/m(2)). Yellow-green EL with narrow full width at the half-maximum (fwhm < 70 nm) and the highest maximum luminance (1768 cd/m(2)) among the currently reported polyquinolines was obtained for P5.