Cu2(μ-tBuCO2)4(NEt3)2 | 220168-83-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cu2(μ-tBuCO2)4(NEt3)2
• 英文别名: Cu2(μ-trimetylacetato)4(NEt3)2；[Cu2(μ-OOCBu-t)4(NEt2)2]；Cu2(μ-pivalate)4(NEt3)2
• CAS: 220168-83-2
• 化学式: C₃₂H₆₆Cu₂N₂O₈
• 分子量: 733.977
• InChiKey: CYYFXVWJOXMPPX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cu2(μ-tBuCO2)4(NEt3)2 以 二氯甲烷 为溶剂， 生成 [Cu2(trimetylacetate)2(μ-3,5-dimethylpyrazole(-1H))2(3,5-dimethylpyrazole)2]
  参考文献：
  名称：

  Copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole

  摘要：

  Specific features of the chemical behavior and structure of copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole have been considered based on X-ray crystallographic data.

  DOI：

  10.1134/s0036023606070084
• 作为产物：
  描述：

  copper(II) dipivaloate 、 三乙胺 以 正己烷 为溶剂， 生成 Cu2(μ-tBuCO2)4(NEt3)2
  参考文献：
  名称：

  Copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole

  摘要：

  Specific features of the chemical behavior and structure of copper(II) trimethylacetate complexes with 3,5-dimethylpyrazole have been considered based on X-ray crystallographic data.

  DOI：

  10.1134/s0036023606070084

文献信息

• Binuclear complexes with the “Chinese Lantern” geometry as intermediates in the liquid-phase oxidation of dibenzyl ether with atmospheric oxygen in the presence of copper(II) carboxylates
  作者：S. E. Nefedov、E. V. Kushan、M. A. Yakovleva、D. G. Chikhichin、V. A. Kotseruba、O. A. Levchenko、G. L. Kamalov

  DOI：10.1134/s1070328412030086

  日期：2012.3

  carboxylates with dibenzyl ether (DBE) gave binuclear complexes of the formula Cu2(μ-OOCR)4(DBE)2 (R = But, Ph, and CF3). The complexes were characterized by X-ray diffraction. The axial positions in the lantern-type dimer are occupied by the coordinated DBE molecules. The complexes seem to be analogs of intermediate catalysts for the oxidation of DBE with atmospheric oxygen in the presence of transition

  羧酸铜（II）与二苄基醚（DBE）的反应得到式Cu 2（μ-OOCR）4（DBE）2（R = Bu t，Ph和CF 3）的双核配合物。通过X射线衍射表征复合物。灯笼型二聚体中的轴向位置被配位的DBE分子占据。该络合物似乎是过渡金属络合物存在下用空气中的氧气氧化DBE的中间催化剂的类似物。当存储在空气中时，复杂的Cu 2（μ-OOCPh）4（DBE）2氧化成Cu 2（μ-OOCPh）4（HOOCPh）2，其特征在于X射线衍射。它的框架的几何形状是相似的。轴向取向的苯甲酸分子与相邻的桥接苯甲酸酯阴离子之间的分子内氢键使结构稳定。
• Binuclear transition-metal trimethylacetato complexes containing coordinated 3,5-dimethylpyrazole as structural analogues of the active site of natural metalloenzymes
  作者：S. E. Nefedov

  DOI：10.1134/s0036023606130031

  日期：2006.1

  Synthetic approaches are discussed to prepare binuclear trimethylacetato complexes of zinc, copper, cobalt, and nickel containing an M-2(mu-OOCR)(2)L-4 binuclear fragment, which is found in the active site of natural metalloenzymes.
• Synthetic modeling of the active site of native metalloenzymes by trimethylacetatozinc complexes
  作者：E. V. Amel’chenkova、T. O. Denisova、S. E. Nefedov

  DOI：10.1134/s0036023606080110

  日期：2006.8

  Synthetic approaches are discussed to a preparation of binuclear trimethylacetatozinc complexes containing an M-2(mu-OOCR)(2)L-4 binuclear fragment, which is found in the active site of native metalloenzymes.