3,3'-diallylbiphenyl-4,4'-diol diacetate | 178426-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-diallylbiphenyl-4,4'-diol diacetate
• 英文别名: 4,4'-Diacetoxy-3,3'-diallyl-biphenyl；3,3'-diallyl-4,4'-diacetoxy biphenyl；3,3'-diallyl-4,4'-diacetoxy-biphenyl；[4-(4-Acetyloxy-3-prop-2-enylphenyl)-2-prop-2-enylphenyl] acetate
• CAS: 178426-57-8
• 化学式: C₂₂H₂₂O₄
• 分子量: 350.414
• InChiKey: CLKXLPLPSOCDOJ-UHFFFAOYSA-N

物化性质

• 沸点：
  467.1±45.0 °C(Predicted)
• 密度：
  1.099±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,3'-diallylbiphenyl-4,4'-diol diacetate 在 乙醇 、 溴 、 sodium ethanolate 、 苯 作用下， 生成 2,2'-bis-piperidinomethyl-2,3,2',3'-tetrahydro-[5,5']bibenzofuranyl
  参考文献：
  名称：

  Funke; v. Daniken, Bulletin de la Societe Chimique de France, 1953, p. 457,459

  摘要：

  DOI：
• 作为产物：
  描述：

  4,4'-二羟基联苯 在 吡啶 、 potassium carbonate 、 N,N-二乙基苯胺 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 56.0h， 生成 3,3'-diallylbiphenyl-4,4'-diol diacetate
  参考文献：
  名称：

  Halogenated Analogs of the Antimalarial Bialamicol

  摘要：

  为了提高抗疟药比亚拉米醇的药理活性，人们成功地在烯丙基侧链的 2 位引入了取代基。2-Fluoroallyl bromide（2-氟烯丙基溴）是一种多用途的 C3F 构建模块，它是首次被描述。

  DOI：

  10.1055/s-1996-4262

文献信息

• COMPOUND HAVING ALKOXYSILYL GROUP AND ACTIVE ESTER GROUP, METHOD FOR PREPARING SAME, COMPOSITION COMPRISING SAME, AND USE
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20200165275A1

  公开（公告）日：2020-05-28

  The present invention relates to a novel compound having an alkoxysilyl group and an active ester group, a method for preparing the same, a composition comprising the same, and a use, wherein the novel compound exhibits improved low moisture absorption and/or low dielectric properties when cured as an epoxy composition, but is not accompanied by loss of thermal expansion characteristics. Disclosed are a novel compound of formulae AF to LF having an alkoxysilyl group and an active ester group, and a method for preparing the same, a composition comprising the same, and a use of same.

  本发明涉及一种具有烷氧基硅基团和活性酯基团的新化合物，以及其制备方法、包含该化合物的组合物和用途，其中该新化合物在作为环氧组合物固化时表现出改善的低吸湿性和/或低介电性能，但不伴随热膨胀特性的丧失。公开了具有烷氧基硅基团和活性酯基团的化合物AF至LF的新化合物，以及其制备方法、包含该化合物的组合物和用途。
• Novel compositions of monomers, oligomers and polymers and methods for making the same
  申请人：Panambur Gangadhar

  公开号：US20060089510A1

  公开（公告）日：2006-04-27

  A novel monomer composition is described. The novel monomer composition includes at least one property imparting unit. The property imparting unit has at least one member selected from the group consisting of conductivity imparting unit, stability imparting unit and any combinations thereof. The novel monomer may further include a delinking agent, which is attached to at least one of said property imparting unit. The delinking agent includes at least one member selected from the group consisting of C—C bond, CH 2 , CH 3 , CF 2 , CF 3 , Si, O, S, functional groups, aromatic residues and any combinations thereof.

  本文描述了一种新型单体组成物。该新型单体组成物包括至少一个赋予性能的单元。该赋予性能的单元具有来自以下组中至少一个成员的单元：导电赋予单元、稳定性赋予单元和任何组合。该新型单体还可以包括一个解离剂，该解离剂附着在至少一个赋予性能的单元上。该解离剂包括来自以下组中至少一个成员的单元：C-C键，CH2，CH3，CF2，CF3，Si，O，S，功能性基团，芳香残基和任何组合。
• METHODS OF MAKING STABLE AND THERMALLY POLYMERIZABLE VINYL, AMINO OR OLIGOMERIC PHENOXY BENZOCYCLOBUTENE MONOMERS WITH IMPROVED CURING KINETICS
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：US20190169327A1

  公开（公告）日：2019-06-06

  The present invention provides methods of making low energy polymerizable monomers and resins for use in making dielectric materials. The methods comprise deprotecting or deacylating an organic alkali cleavable protecting group containing addition polymerizable, amine containing aromatic monomer or oligoaromatic phenol resin containing an organic alkali cleavable protecting group, such as a C 2 to C 9 alkanoyl group, preferably, an acyl group, by hydrolyzing to remove the protecting group in organic alkali in a polar solvent containing an excess of alkali C 1 to C 7 alkoxide and form a hydroxyl functional monomer or resin, followed by; reacting via nucleophilic substitution the resulting hydroxyl functional monomer or resin with an alpha-halide (α-halide) or strong acid conjugate leaving group containing arylcyclobutene compound in a polar solvent, to yield a product an arylcyclobutene-containing addition polymerizable or amine containing aromatic monomer or oligoaromatic phenol resin having an ether linkage from the cyclobutene ring to an aromatic group of the addition polymerizable aromatic monomer, aromatic amine or oligoaromatic phenol.

  本发明提供了制备低能量聚合单体和树脂的方法，用于制造介电材料。该方法包括去保护有机碱可解除保护基，其中包含加成聚合、胺含量芳香单体或寡聚芳香酚树脂，该保护基是有机碱可解除的保护基，例如C2至C9烷酰基，优选为酰基，通过在含有过量碱C1至C7醇酸盐的极性溶剂中水解去除保护基，形成羟基官能单体或树脂，然后通过亲核取代反应，在极性溶剂中与含有芳基环丁烯化合物的α-卤代物或强酸共轭离去基反应，得到含有芳基环丁烯的加成聚合或胺含量芳香单体或寡聚芳香酚树脂产物，其环丁烯环上有一个醚键，连接到加成聚合芳香单体、芳香胺或寡聚芳香酚的芳香基上。
• METHODS OF MAKING STABLE AND THERMALLY POLYMERIZABLE VINYL, AMINO OR OLIGOMERIC PHENOXY BENZOCYCLOBUTENE MONOMERS WITH IMPROVED CURING KINETICS
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：EP3492444A1

  公开（公告）日：2019-06-05

  The present invention provides methods of making low energy polymerizable monomers and resins for use in making dielectric materials. The methods comprise deprotecting or deacylating an organic alkali cleavable protecting group containing addition polymerizable, amine containing aromatic monomer or oligoaromatic phenol resin containing an organic alkali cleavable protecting group, such as a C2 to C9 alkanoyl group, preferably, an acyl group, by hydrolyzing to remove the protecting group in organic alkali in a polar solvent containing an excess of alkali C1 to C7 alkoxide and form a hydroxyl functional monomer or resin, followed by; reacting via nucleophilic substitution the resulting hydroxyl functional monomer or resin with an alpha-halide (a-halide) or strong acid conjugate leaving group containing arylcyclobutene compound in a polar solvent, to yield a product an arylcyclobutene-containing addition polymerizable or amine containing aromatic monomer or oligoaromatic phenol resin having an ether linkage from the cyclobutene ring to an aromatic group of the addition polymerizable aromatic monomer, aromatic amine or oligoaromatic phenol.

  本发明提供了用于制造介电材料的低能可聚合单体和树脂的制造方法。这些方法包括通过在含有过量碱 C1 至 C7 烷氧基的极性溶剂中，在有机碱中水解去除保护基团，形成羟基官能团单体或树脂，从而对含有可加成聚合的、含胺的芳香族单体或低芳香族酚树脂进行脱保护或脱乙酰化；在极性溶剂中，通过亲核取代作用，使得到的羟基官能团单体或树脂与含有芳基环丁烯化合物的α-卤化物（a-卤化物）或强酸共轭离去基团反应，得到一种含有芳基环丁烯的可加成聚合或含胺的芳香族单体或低芳香族酚树脂，该产品具有从环丁烯环到可加成聚合芳香族单体、芳香族胺或低芳香族酚的芳香族基团的醚键。
• METHODS OF MAKING STABLE AND THERMALLY POLYMERIZABLE VINYL, AMINO OR OLIGOMERIC PHENOXY BENZOCYCLOBUTENE MONOMERS WITH IMPROVED CURING KINETICS
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：EP3708559A1

  公开（公告）日：2020-09-16

  The present invention provides methods of making low energy polymerizable monomers and resins for use in making dielectric materials. The methods comprise deprotecting or deacylating an organic alkali cleavable protecting group containing addition polymerizable, amine containing aromatic monomer or oligoaromatic phenol resin containing an organic alkali cleavable protecting group, such as a C2 to C9 alkanoyl group, preferably, an acyl group, by hydrolyzing to remove the protecting group in organic alkali in a polar solvent containing an excess of alkali C1 to C7 alkoxide and form a hydroxyl functional monomer or resin, followed by; reacting via nucleophilic substitution the resulting hydroxyl functional monomer or resin with an alpha-halide (a-halide) or strong acid conjugate leaving group containing arylcyclobutene compound in a polar solvent, to yield a product an arylcyclobutene-containing addition polymerizable or amine containing aromatic monomer or oligoaromatic phenol resin having an ether linkage from the cyclobutene ring to an aromatic group of the addition polymerizable aromatic monomer, aromatic amine or oligoaromatic phenol.

  本发明提供了用于制造介电材料的低能可聚合单体和树脂的制造方法。这些方法包括通过在含有过量碱 C1 至 C7 烷氧基的极性溶剂中，在有机碱中水解去除保护基团，形成羟基官能团单体或树脂，从而对含有可加成聚合的、含胺的芳香族单体或低芳香族酚树脂进行脱保护或脱乙酰化；在极性溶剂中，通过亲核取代作用，使得到的羟基官能团单体或树脂与含有芳基环丁烯化合物的α-卤化物（a-卤化物）或强酸共轭离去基团反应，得到一种含有芳基环丁烯的可加成聚合或含胺的芳香族单体或低芳香族酚树脂，该产品具有从环丁烯环到可加成聚合芳香族单体、芳香族胺或低芳香族酚的芳香族基团的醚键。