11-(4'-methoxybiphenyl-4-oxy)undecanol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 11-(4'-methoxybiphenyl-4-oxy)undecanol
• 英文别名: 11-(4'-Methoxy-4-biphenyloxy)undecanol；11-[4-(4-methoxyphenyl)phenoxy]undecan-1-ol
• 化学式: C₂₄H₃₄O₃
• 分子量: 370.532
• InChiKey: MCODHZBFCBMDHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  27
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  11-(4'-methoxybiphenyl-4-oxy)undecanol 在 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 反应 21.5h， 生成 1-(5-(4'-cyanobiphenyl-4-oxy)pentylaminocarbonyl)-11-(4'-methoxybiphenyl-4-oxy)undecyl 11-(4'-((S)-2-methylbutoxy)biphenyl-4-oxy)undecanoate
  参考文献：
  名称：

  Efficient Syntheses of Star-Branched, Multifunctional Mesogens

  摘要：

  Star-branched molecular architectures lend themselves to convergent synthesis strategies for creating materials that combine three or mare functional modalities, but these approaches require a core moiety with several reactive groups that are orthogonal to one another. The direct synthesis of three-arm, star-branched mesogens has been Investigated via the Passerini three-component reaction to demonstrate how multicomponent reactions circumvent the need to identify and synthesize specialized branched core molecules.

  DOI：

  10.1021/acs.orglett.5b01388
• 作为产物：
  描述：

  4,4'-二羟基联苯 在 potassium carbonate 、 sodium hydroxide 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 21.0h， 生成 11-(4'-methoxybiphenyl-4-oxy)undecanol
  参考文献：
  名称：

  Efficient Syntheses of Star-Branched, Multifunctional Mesogens

  摘要：

  Star-branched molecular architectures lend themselves to convergent synthesis strategies for creating materials that combine three or mare functional modalities, but these approaches require a core moiety with several reactive groups that are orthogonal to one another. The direct synthesis of three-arm, star-branched mesogens has been Investigated via the Passerini three-component reaction to demonstrate how multicomponent reactions circumvent the need to identify and synthesize specialized branched core molecules.

  DOI：

  10.1021/acs.orglett.5b01388