p-Vinyl-β-phenylethylamin | 38902-07-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-Vinyl-β-phenylethylamin
• 英文别名: p-(2-Aminoaethyl)styrol；poly[4-(2-aminoethyl)styrene]；4-(2-aminoethyl)styrene；2-(4-Ethenylphenyl)ethan-1-amine；2-(4-ethenylphenyl)ethanamine
• CAS: 38902-07-7
• 化学式: C₁₀H₁₃N
• mdl: MFCD19203874
• 分子量: 147.22
• InChiKey: FXWRUNXMOLCZEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  p-Vinyl-β-phenylethylamin 以 苯 为溶剂， 生成 (R)-2-(4-vinyl-phenyl)-[1,3,2]dioxaborolane-4-carboxylic acid 4-vinyl-phenethylamide
  参考文献：
  名称：

  Wulff,G. et al., Chemische Berichte, 1974, vol. 107, p. 3364 - 3376

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(2-溴乙基)苯乙酮 在 氨 、 氯化铵 作用下， 以 甲醇 为溶剂， 生成 p-Vinyl-β-phenylethylamin
  参考文献：
  名称：

  Wulff,G. et al., Chemische Berichte, 1974, vol. 107, p. 3364 - 3376

  摘要：

  DOI：

文献信息

• [EN] FORMAMIDE MONOMERS AND POLYMERS SYNTHESIZED THEREFROM<br/>[FR] MONOMÈRES DE FORMAMIDE ET POLYMÈRES SYNTHÉTISÉS À PARTIR DE CEUX-CI
  申请人：WISCONSIN ALUMNI RES FOUND

  公开号：WO2020185872A1

  公开（公告）日：2020-09-17

  Formamide group-containing monomers and polymers made by polymerizing the monomers are provided. Also provided are methods of polymerizing the monomers and methods of synthesizing functionalized polymers by pre- and/or post-polymerization functionalization. The monomers are non-toxic and can generate highly reactive isocyanate and isonitrile precursors in a one-pot synthesisthat enables the incorporation of complex functionalities into the side-chain of the polymers that are synthesized from the monomers.

  提供了通过聚合含有甲酰胺基团的单体制备的单体和聚合物。还提供了聚合这些单体的方法以及通过聚合前和/或聚合后功能化合成功能化聚合物的方法。这些单体是无毒的，可以在一个锅合成过程中产生高度活性的异氰酸酯和异腈前体，从而使从这些单体合成的聚合物的侧链中能够加入复杂的功能基团。
• Functionalized rubbery polymers
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP1792892A2

  公开（公告）日：2007-06-06

  This invention discloses a functional monomer, its use in a polymer, a rubbery composition, a tire, and a process to make such a rubbery composition. The functional monomer has a structural formula selected from the group consisting of: wherein the R1 groups can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to 8 carbon atoms, wherein R2 represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms, wherein R3 represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms, wherein R4 represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms, with the proviso that if R3 represents an alkyl group then R4 represents a hydrogen atom, and with the proviso that R4 represents an alkyl group then R3 represents a hydrogen atom, and wherein the R5 groups can be the same or different and represent alkyl groups containing from 1 to 8 carbon atoms.

  本发明揭示了一种功能单体，其在聚合物中的使用，橡胶组合物，轮胎以及制造这种橡胶组合物的过程。该功能单体具有以下结构式中所选的结构式：其中R1基团可以相同或不同，并表示氢原子或含有1至8个碳原子的烷基基团，其中R2表示氢原子或含有1至8个碳原子的烷基基团，其中R3表示氢原子或含有1至8个碳原子的烷基基团，其中R4表示氢原子或含有1至8个碳原子的烷基基团，但如果R3表示烷基基团，则R4表示氢原子，如果R4表示烷基基团，则R3表示氢原子，其中R5基团可以相同或不同，并表示含有1至8个碳原子的烷基基团。
• Multi-branched polymer, process for producing the same, and applications thereof
  申请人：——

  公开号：US20040220346A1

  公开（公告）日：2004-11-04

  A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer, thus exhibiting useful performance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.

  通过使用含有功能性基团的聚烯烃作为宏启动剂、宏单体或反应性聚合物，聚合或反应各种极性单体及其聚合物即极性聚合物链，可以高效地生产出由多个聚烯烃链和极性聚合物链组成的聚合物群，其具有诸如块状结构、嫁接结构和星形结构等多分支结构。所得到的多分支聚合物具有特定形状，如块状结构、嫁接结构或星形结构，并具有聚烯烃和极性聚合物的性质，因此在薄膜和相容剂等各种用途中表现出有用的性能，是一种新型的基于聚烯烃的聚合物。
• Polyolefin macromonomer, graft polymer obtained from the polyolefin macromonomer, and use thereof
  申请人：——

  公开号：US20040242791A1

  公开（公告）日：2004-12-02

  A novel graft polymer useful in various uses that has a polyolefin backbone having polyolefin segments excellent in moldability can be obtained by homopolymerizing a novel polyolefin macromonomer or polymerizing the novel polyolefin macromonomer in the coexistence of other olefins depending on need, wherein the macromonomer has at the terminal of its polyolefin chain a vinyl group whose &agr;-position may be substituted, and the macromonomer can be efficiently obtained by a method, for example, successively carrying out i) a step of producing a polyolefin having a hydroxyl group at the terminal of the polyolefin chain and ii) a step of converting the terminal hydroxyl group of the polyolefin in chain into an acryloyl group, a methacryloyl group or a styryl group.

  一种新型的移植聚合物，可用于各种用途，具有聚烯烃骨架，其聚烯烃段具有优异的成型性能，可以通过聚合新型聚烯烃大分子单体或在需要时在其他烯烃的共存下聚合新型聚烯烃大分子单体来获得。其中，大分子单体在其聚烯烃链的末端具有一个乙烯基，其α-位可以被取代，通过一种方法可以高效地获得大分子单体，例如连续进行i）生成在聚烯烃链末端具有羟基的聚烯烃的步骤和ii）将聚烯烃的末端羟基转化为丙烯酰基、甲基丙烯酰基或苯乙烯基的步骤。
• Cationic electrocoating composition
  申请人：NIPPON PAINT CO., LTD.

  公开号：EP0431554A2

  公开（公告）日：1991-06-12

  The present invention provides a cationic electrocoating composition which cures at the preferred curing temperature range and provides superior curing properties and cured film properties. The cationic electrocoating composition of the present invention comprises a resinous component and an aqueous medium, wherein the resinous component is composed of one or more polymers and has as a whole an active hydrogen containing group, a cationic group and a substituted group and at least one of the polymers comprises a vinyl polymer which has 5 to 1,000 substituted acylamide groups.

  本发明提供了一种阳离子电涂层组合物，它能在优选的固化温度范围内固化，并具有优异的固化性能和固化膜性能。本发明的阳离子电涂组合物包括树脂成分和水介质，其中树脂成分由一种或多种聚合物组成，整体上具有活性含氢基团、阳离子基团和取代基团，至少一种聚合物包括乙烯基聚合物，该聚合物具有 5 至 1 000 个取代的酰酰胺基团。