1,1,2,3,3,4,4,5,5,6,6,7,7,8,8-十五氟-1-辛烯 | 336-01-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 中文名称: 1,1,2,3,3,4,4,5,5,6,6,7,7,8,8-十五氟-1-辛烯
• 英文名称: 8-hydropentadecafluoro-1-octene
• 英文别名: 8H-pentadecafluoro-oct-1-ene；1,1,2,3,3,4,4,5,5,6,6,7,7,8,8-Pentadecafluor-octen-(1)；ω-Hydro-perfluor-octen-(1)；8-H-Perfluor-octen-(1)；8-Hydroperfluorocten-1；8-H-Perfluorokten-1；8H-Perfluorooct-1-ene；1,1,2,3,3,4,4,5,5,6,6,7,7,8,8-pentadecafluorooct-1-ene
• CAS: 336-01-6
• 化学式: C₈HF₁₅
• 分子量: 382.072
• InChiKey: PAAIHHFXTDHQHM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  1,1,2,3,3,4,4,5,5,6,6,7,7,8,8-十五氟-1-辛烯 在 sodium hypochlorite 、 五氟化锑 、 cesium fluoride 作用下， 以 乙腈 为溶剂， 反应 24.0h， 生成 8-hydropentadecafluoro-2-octanone
  参考文献：
  名称：

  Saloutina, L. V.; Kodess, M. I.; Zapevalov, A. Ya., Russian Journal of Organic Chemistry, 1993, vol. 29, # 7.1, p. 1097 - 1107

  摘要：

  DOI：
• 作为产物：
  描述：

  9H-十六氟壬酸 生成 1,1,2,3,3,4,4,5,5,6,6,7,7,8,8-十五氟-1-辛烯
  参考文献：
  名称：

  Reactions of Fluoroölefins with Sulfur Trioxide

  摘要：

  DOI：

  10.1021/ja01508a051

文献信息

• [EN] TETRAZOLINONE COMPOUNDS AND ITS USE<br/>[FR] COMPOSÉS DE TÉTRAZOLINONE ET LEUR UTILISATION
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2013162077A1

  公开（公告）日：2013-10-31

  The present invention provides a compound having an excellent efficacy for controlling pests. A tetrazolinone compound of a formula (1): [wherein, R1 represents an C6-C16 aryl group, an C1-C12 alkyl group, a C3-C12 cycloalkyl group or an adamantyl group, etc., which each optionally be substituted; R2 represents a hydrogen atom, an C1-C12 alkyl group, or a halogen atom, etc.; R4 and R5 represent independently of each other a hydrogen atom or an C1-C3 alkyl group, etc.; R6, R7, R8 and R9 represent independently of each other a hydrogen atom, a halogen atom, an C1-C12 alkyl group, a C1-C12 haloalkyl group, an C2-C12 alkenyl group, a C3-C12 cycloalkyl group, an C1-C12 alkoxy group or a C1-C12 haloalkoxy group, etc.; X and Y represent independently of each other a sulfur atom or an oxygen atom; Q represents an oxygen atom or a sulfur atom; and R10 represents an C1-C6 alkyl group, etc.] shows an excellent controlling efficacy on pests.

  本发明提供了一种具有优异杀虫效果的化合物。式（1）中的四氮杂酮化合物：[其中，R1代表一个C6-C16芳基，一个C1-C12烷基，一个C3-C12环烷基或一个金刚烷基等，每个都可以选择性地被取代；R2代表一个氢原子，一个C1-C12烷基或一个卤素原子等；R4和R5分别独立地代表一个氢原子或一个C1-C3烷基等；R6、R7、R8和R9分别独立地代表一个氢原子，一个卤素原子，一个C1-C12烷基，一个C1-C12卤代烷基，一个C2-C12烯基，一个C3-C12环烷基，一个C1-C12烷氧基或一个C1-C12卤代烷氧基等；X和Y分别独立地代表一个硫原子或一个氧原子；Q代表一个氧原子或一个硫原子；R10代表一个C1-C6烷基等]对害虫有极佳的控制效果。
• Isomerization of monohydroperfluoroalkenes
  作者：T. I. Filyakova、A. Ya. Zapevalov、M. I. Kodess、M. A. Kurykin、L. S. German

  DOI：10.1007/bf00697141

  日期：1994.9

  Isomerization of monohydroperfluoro-1-alkenes HC(CF2)nCF=CF2 (n = 2 to 8) catalyzed by Lewis bases or acids (CsF, KHF2, and SbF5) under conditions of thermodynamic control affords equilibrium mixtures of all of the possible isomers resulting from migration of the double bond along the carbon chain. Under conditions of kinetic control, isomerization through the action of SbF5 gives ω-H-perfluoro-2-alkenes. The

  在热力学控制条件下，由路易斯碱或酸（CsF、KHF2 和 SbF5）催化的单氢全氟-1-烯烃 HC(CF2)nCF=CF2（n = 2 至 8）的异构化提供了所有可能的异构体的平衡混合物，由此产生来自双键沿碳链的迁移。在动力学控制条件下，通过 SbF5 的作用异构化得到 ω-H-全氟-2-烯烃。所得单氢全氟烯烃中顺式异构体的比例明显高于其全氟化类似物，这归因于分子内氢键的影响。
• Processes for production and purification of hydrofluoroolefins
  申请人：Miller Newton Ralph

  公开号：US20060106263A1

  公开（公告）日：2006-05-18

  Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文公开了通过脱氟制备氢氟烯的工艺。本文还公开了从氢氟碳和氟化氢中分离氢氟烯的工艺。
• PROCESSES FOR PRODUCTION AND PURIFICATION OF HYDROFLUOROOLEFINS
  申请人：MILLER RALPH NEWTON

  公开号：US20110118512A1

  公开（公告）日：2011-05-19

  Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文揭示了通过脱氟制备氢氟烯的过程。同时，还揭示了从氢氟碳化物和氢氟酸中分离氢氟烯的过程。
• TETRAZOLINONE COMPOUNDS AND ITS USE
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20150031733A1

  公开（公告）日：2015-01-29

  The present invention provides a compound having an excellent efficacy for controlling pests. A tetrazolinone compound of a formula (1): [wherein, R1 represents an C6-C16 aryl group, an C1-C12 alkyl group, a C3-C12 cycloalkyl group or an adamantyl group, etc., which each optionally be substituted; R2 represents a hydrogen atom, an C1-C12 alkyl group, or a halogen atom, etc.; R4 and R5 represent independently of each other a hydrogen atom or an C1-C3 alkyl group, etc.; R6, R7, R8 and R9 represent independently of each other a hydrogen atom, a halogen atom, an C1-C12 alkyl group, a C1-C12 haloalkyl group, an C2-C12 alkenyl group, a C3-C12 cycloalkyl group, an C1-C12 alkoxy group or a C1-C12 haloalkoxy group, etc.; X and Y represent independently of each other a sulfur atom or an oxygen atom; Q represents an oxygen atom or a sulfur atom; and R10 represents an C1-C6 alkyl group, etc.] shows an excellent controlling efficacy on pests.

  本发明提供了一种具有优异的杀虫功效的化合物。公式（1）的四唑酮化合物：[其中，R1代表C6-C16芳基，C1-C12烷基，C3-C12环烷基或金刚烷基等，每个都可以选择性地被取代；R2代表氢原子，C1-C12烷基或卤素原子等；R4和R5分别独立地代表氢原子或C1-C3烷基等；R6、R7、R8和R9分别独立地代表氢原子、卤素原子、C1-C12烷基、C1-C12卤代烷基、C2-C12烯基、C3-C12环烷基、C1-C12烷氧基或C1-C12卤代烷氧基等；X和Y分别独立地代表硫原子或氧原子；Q代表氧原子或硫原子；R10代表C1-C6烷基等]在控制害虫方面表现出优异的效果。