5-[[5-[(1,3-Dimethyl-4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ylidene)methyl]thieno[3,2-b]thiophen-2-yl]methylidene]-1,3-dimethyl-2-sulfanylidene-1,3-diazinane-4,6-dione | 1566578-97-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 5-[[5-[(1,3-Dimethyl-4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ylidene)methyl]thieno[3,2-b]thiophen-2-yl]methylidene]-1,3-dimethyl-2-sulfanylidene-1,3-diazinane-4,6-dione
• 英文别名: 5-[[5-[(1,3-dimethyl-4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ylidene)methyl]thieno[3,2-b]thiophen-2-yl]methylidene]-1,3-dimethyl-2-sulfanylidene-1,3-diazinane-4,6-dione
• CAS: 1566578-97-9
• 化学式: C₂₀H₁₆N₄O₄S₄
• 分子量: 504.635
• InChiKey: DVPADSMILOVJRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  噻吩并[3,2-b]噻吩-2,5-二羧醛 、 1,3-二甲基-2-硫代巴比妥酸 在 哌啶 作用下， 以 叔丁醇 为溶剂， 生成 5-[[5-[(1,3-Dimethyl-4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ylidene)methyl]thieno[3,2-b]thiophen-2-yl]methylidene]-1,3-dimethyl-2-sulfanylidene-1,3-diazinane-4,6-dione
  参考文献：
  名称：

  N-Alkyl functionalized barbituric and thiobarbituric acid bithiophene derivatives for vacuum deposited n-channel OFETs

  摘要：

  对巴比妥酸受体基团的修改导致了结构和光电变化，从而提供了接近0.3 cm² V⁻¹ s⁻¹的电子迁移率。

  DOI：

  10.1039/c4tc00002a

文献信息

• [EN] PHOTOACTIVE OPTOELECTRONIC AND TRANSISTOR DEVICES<br/>[FR] DISPOSITIFS OPTOÉLECTRONIQUES PHOTOACTIFS ET À TRANSISTORS
  申请人：COMMW SCIENT IND RES ORG

  公开号：WO2014026244A1

  公开（公告）日：2014-02-20

  The present invention relates to photoactive optoelectronic devices, such as organic photovoltaic devices, and transistor devices, and to organic compounds for use in the optoelectronic and transistor devices. The present invention also relates to processes for preparing photoactive optoelectronic and transistor devices. The photoactive optoelectronic devices comprise a first and second electrode, and at least one organic light-absorbing electroactive layer in electrical connection with the first and second electrodes that generates an electrical current in response to electromagnetic radiation. The light-absorbing electroactive layer comprises an electron donor material and an electron acceptor material, the electron acceptor material comprising a compound as described herein.
• <i>N</i>-Alkyl functionalized barbituric and thiobarbituric acid bithiophene derivatives for vacuum deposited n-channel OFETs
  作者：Ying Shu、Annabel Mikosch、Kevin N. Winzenberg、Peter Kemppinen、Christopher D. Easton、Ante Bilic、Craig M. Forsyth、Christopher J. Dunn、Th. Birendra Singh、Gavin E. Collis

  DOI：10.1039/c4tc00002a

  日期：——

  Modification of the barbituric acid acceptor group results in structural and optoelectronic changes that provide electron mobilities nearing 0.3 cm² V⁻¹ s⁻¹.

  对巴比妥酸受体基团的修改导致了结构和光电变化，从而提供了接近0.3 cm² V⁻¹ s⁻¹的电子迁移率。