N,N′-bis(4-pyridinecarboxamide)-1,3-propane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N,N′-bis(4-pyridinecarboxamide)-1,3-propane
• 英文别名: N,N′-(propane-1,3-diyl)diisonicotinamide；N,N'-propyleneenediaminebis(isonicotinamide)；N,N'-(propane-1,3-diyl)diisonicotinamide；1,3-propanediaminebis(isonicotinamide)；bis(4-pyridylcarboxamido)propane；N-[3-(isonicotinoylamino)propyl]isonicotinamide；N-[3-(pyridine-4-carbonylamino)propyl]pyridine-4-carboxamide
• 化学式: C₁₅H₁₆N₄O₂
• 分子量: 284.318
• InChiKey: WORZREXWFOMREX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 N,N′-bis(4-pyridinecarboxamide)-1,3-propane 以 甲醇 、 二氯甲烷 、 乙腈 为溶剂， 反应 96.0h， 以65%的产率得到[(Cu2I2)(bis(4-pyridylcarboxamido)propane)2]n
  参考文献：
  名称：

  包含奇数为-（CH 2）–的双（吡啶基甲酰胺基）烷烃的M 2 L 2和M 4 L 4金属laclaclaces的配位聚合物：客体包含和通过α片的网络识别

  摘要：

  双（pyridylcarboxamido）丙烷的（反应大号1，4-吡啶基和大号2，3-吡啶基）（和双（pyridylcarboxamido）戊烷大号3，4-吡啶基和大号4，3-吡啶基）与铜（I / II），Co（II）和Cd（II）盐在各种阴离子的存在下产生包含M 2 L 2和M 4 L 4金属环的一维（1D）和二维（2D）配位聚合物。的反应大号1和大号2与得到的CuI两种不同的SBU的形成以Cu 2我2和Cu4 I 4，两个络合物都形成一维链，这些链通过α片氢键进一步组装。M（II）盐在没有客体分子的情况下的反应导致形成包含M 2 L 2型金属环的一维链。发现这些一维链有两种类型：在一种类型中，相邻的金属环彼此在同一平面上，而在第二种类型中，它们彼此不平行。在客体分子（例如苄腈或硝基苯）存在下，Cu（II）与L 1的反应导致形成包含M 4 L 4的波纹二维层金属自行车。这些2D层同时显示

  DOI：

  10.1021/cg400918d
• 作为产物：
  描述：

  氯化异氰盐酸盐 、 1,3-丙二胺 在 吡啶 作用下， 生成 N,N′-bis(4-pyridinecarboxamide)-1,3-propane
  参考文献：
  名称：

  具有构象柔性双吡啶基酰胺配体的二苯酸锌和镉配位聚合物

  摘要：

  锌和二苯甲酸镉（dip，联苯-2,2'-二羧酸盐）配位聚合物含有构象灵活的二吡啶基酰胺配体，通过单晶 X 射线衍射确定显示出不同的链和层拓扑结构。[Cd(dipH)2(bdin)]n (1) [bdin = N,N'-(butane-1,3-diyl)diisoticotinamide] 显示了一个简单的一维锯齿形链结构。{[Cd(dip)(pdin)(H2O)]·1.25H2O}n (2) [pdin = N,N'-(propane-1,3-diyl)diisoticotinamide] 显示由 (4, 4）矩形网格层。{[Zn2(dip)2(3-pna)2]·3H2O}n (3) (3-pna = 3-pyridylnicotinamide) 表现出罕见的 4 连接一维带状拓扑结构。{[Cd(dip)(4-ppbp)]·2H2O}n (4) [4-ppbp = propane-1,3-

  DOI：

  10.1002/zaac.201700183

文献信息

• Auxiliary dipyridylamide ligand control of dimensionality in copper 5-sulfoisophthalate coordination polymers
  作者：Abigail E. Meyers、Robert L. LaDuca

  DOI：10.1016/j.ica.2017.11.062

  日期：2018.2

  Abstract Hydrothermal reaction of copper nitrate, sodium 5-sulfoisophthalate (sip), and a long-spanning hydrogen-bonding capable dipyridylamide ligand afforded four coordination polymers whose dimensionality depends critically on the dipyridylamide tether length. The four new phases were structurally characterized via single-crystal X-ray diffraction. [Cu 8 (sip) 4 (pbn) 3 (nic)(μ 3 -OH) 2 (μ 2 -OH)(μ

  摘要硝酸铜，5-磺基间苯二甲酸钠（sip）和具有跨度大的氢键能力的二吡啶酰胺配体的水热反应提供了四种配位聚合物，其尺寸关键取决于二吡啶酰胺的束缚长度。通过单晶X射线衍射在结构上表征了四个新相。[Cu 8（sip）4（pbn）3（nic）（μ3 -OH）2（μ2 -OH）（μ2 -H 2 O）（H 2 O）4]·5H 2 O} n（如图1所示，pbn ＝ 1，3-丙二胺双（烟酰胺），nic ＝烟酸酯）显示出有趣的2D平板结构，其特征在于包含桥连的氢氧离子和水分子的三聚体铜簇以及显着的晶体学无序。[Cu 3（sip）2（pbin）4（H 2 O）4]·14H 2 O} n（2，pbin = 1,3-丙二胺双（异烟酰胺））显示具有卷曲构型二吡啶酰胺配体的一维链基序。[Cu 4（μ3 -OH）2（sip）2（hbin）]·2H 2 O} n（3，hbin = 1,6-己二胺双（异烟酰胺））特征[Cu
• Novel Anderson-type [TeMo₆O₂₄]⁶⁻-based metal–organic complexes tuned by different species and their coordination modes: assembly, various architectures and properties
  作者：Xiuli Wang、Junjun Sun、Hongyan Lin、Zhihan Chang、Aixiang Tian、Guocheng Liu、Xiang Wang

  DOI：10.1039/c5dt04074d

  日期：——

  supramolecular networks through the hydrogen bonding interactions. In complex 3, the TeMo6 anions link the metal–organic units [Cu2(4-Hdpyp)2]6+ to construct a 2D layer, which is further extended to a 3D supramolecular framework by the hydrogen bonding interactions. In complex 4, the TeMo6 polyoxoanions bridge the CuII ions to generate a 2D Cu-TeMo6 inorganic layer, which is further linked by the μ2-bridging

  四种新型的安德森型多金属氧酸盐（POM）[TeMO 6 O 24 ] 6−（TeMO 6）-基金属-有机配合物（MOC），即H 2 [Zn 4（3-Hdpyp）2（TeMO 6 O 24）2（H 2 O）16 ]·6H 2 O（1），[Zn 3（3-dpyb）2（TeMO 6 O 24）（H 2 O）12 ]·8H 2 O（2），[Cu 2（ 4-Hdpyp）2（TeMO6 O 24）（H 2 O） 6 ]·4H 2 O（ 3）和[Cu 3（3-dpyp） 2（TeMO 6 O 24）（H 2 O） 8 ]·4H 2 O（ 4）（ 3-dpyp = N， N'-双（3-吡啶甲酰胺）-1,3-丙烷，3-dpyb = N， N'-双（3-吡啶甲酰胺）-1,4-丁烷，4-dpyp = N， ñ水热合成了'-双（4-吡啶甲酰胺）-1,3-丙烷，并通过单晶X射线衍射，IR光谱，粉末X射线衍射（PXR
• Nitrobenzene-detection cadmium thiophenedicarboxylate coordination polymers with flexible dipyridylamide ligands and diverse topologies
  作者：Jack J. Przybyla、Robert L. LaDuca

  DOI：10.1016/j.ica.2018.10.039

  日期：2019.2

  Hydrothermal reaction of cadmium nitrate, 2,5-thiophenedicarboxylic acid (H(2)tdc) and one of the conformationally flexible dipyridylamide ligands N,N'-(heptane-1,7-diyl)dinicotinamide (hedn), N,N'-(hexane-1,6-diyl)diisonicotinamide (hdin), N,N'-(hexane-1,6-diyl)dinicotinamide (hdn), N,N'-(propane-1,3-diyl)dinicotinamide (pdn), N,N'-(propane-1,3-diyl)diisonicotinamide (pdin) produced five new coordination polymers which were structurally characterized by single-crystal X-ray diffraction. [Cd(tdc)(hedn)(H2O)]center dot 3H(2)O}(n) (1) manifests looped (4,4) grid motifs with two-fold parallel interpenetration. [Cd(tdc)(hdin)(H2O)]center dot H2O}(n) (2) shows stacked (4,4) grid motifs. [Cd-2(tdc)(2)(hdn)(H2O)(4)]center dot H2O}(n) (3) exhibits herringbone (6,3) grid motifs. In contrast to the 2D topologies seen in 1-3, [Cd-2(tdc)(2)(pdn)(H2O)(2)]center dot 4H(2)O}(n) (4) displays a 3D self-penetrated net with 6(4)8(2) nbo topology and [Cd(tdc)(pdin)](n) (5) shows a 1D ribbon structure constructed from staple-conformation pdin ligands and Cd2O2} dimer-containing [Cd(tdc)](n) chains. Thermal decomposition and nitrobenzene detection properties of these five new materials are discussed.
• Nickel adamantanedicarboxylate and adamantanediacetate 2D and 3D coordination polymers with hydrogen-bonding capable dipyridyl ligands
  作者：Jamelah Z. Travis、Sean R. Pumford、Brianna L. Martinez、Robert L. LaDuca

  DOI：10.1016/j.poly.2017.12.008

  日期：2018.3

  Hydrothermal reaction of nickel nitrate, an adamantane-based dicarboxylic acid, and a hydrogen-bonding capable dipyridyl ligand generated six coordination polymers that were isolated and subsequently structurally characterized by single-crystal X-ray diffraction. [Ni(adc)(ebin)(H2O)]center dot 2H(2)O}(n) (1, adc = 1,3-adamantanedicarboxylate, ebin = N,N'-ethylenediaminebis(isonicotinamide)) shows ABAB stacked (4,4) coordination polymer grids. In contrast, [Ni(ada)(ebin)](n) (2, ada = 1,3-adamantanediacetate) manifests a very rare self-penetrated layer with a 3,5-connected (4(2)6)(4(2)6(7)8) topology. [Ni(adc)(pbin)]center dot 2H(2)O}(n) (3, pbin = N,N'-propyleneenediaminebis(isonicotinamide)) shows a dimer-based 4(12)6(3) pcu network, while [Ni-5(ada)(5)(pbin)(5)(H2O)(5)]center dot 8H(2)O}(n) (4) manifests looped layers with (4)(4.8(5)) topology. [Ni-2(adc)(adcH)(2)(dpa)(2)]center dot H2O}(n) (5, dpa =4,4'-dipyridylamine) possesses [Ni-2(adc)(adcH)(2)] linear fragments connected into an uncommon 3-connected 10(3) srs network. Concomitantly formed along with 5, ([Ni(adc)(dpa)]center dot 6.5H(2)O}(n) (6) is a stacked (4,4) grid phase but with a direct AAA stacking pattern. Embedded Ni-2(OCO)(2)} dimeric units in 2 and 3 exhibit antiferromagnetic coupling J = -10.5(1) cm(-1) (2), J = -2.38(7) cm(-1) (3)). Thermal decomposition behavior of 1-6 was also investigated. (C) 2017 Elsevier Ltd. All rights reserved.