2,6-bis(methoxymethyl)phenol | 75508-71-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-bis(methoxymethyl)phenol
• CAS: 75508-71-3
• 化学式: C₁₀H₁₄O₃
• 分子量: 182.219
• InChiKey: DWKBMLWYFNGDCN-UHFFFAOYSA-N

物化性质

• 沸点：
  249.9±30.0 °C(Predicted)
• 密度：
  1.096±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,6-bis(methoxymethyl)phenol 、 4-硝基苯胺 在 盐酸 、 sodium hydroxide 、 sodium nitrite 作用下， 生成 2,6-Bis-methoxymethyl-4-(4-nitro-phenylazo)-phenol
  参考文献：
  名称：

  Phenylazophenol-quinone phenylhydrazone tautomerism in chromogenic cryptands and corands with inward-facing phenolic units and their acyclic analogs

  摘要：

  A series of 4-(4'-nitrophenol)azophenol compounds is prepared in which ether oxygen-containing substituents are attached at the 2- and 6-positions or connect the 2- and 6-positions to incorporate the chromophoric unit into corand or cryptand structures with inward-facing phenolic groups. The phenylazophenol-quinone phenylhydrazone tautomerism of these compounds, as probed by ultraviolet-visible spectroscopy, reveals a pronounced effect of the structure of the ether oxygen-containing substituents or bridging unit upon the tautomeric equilibrium. Chromogenic responses of five cryptands with inward-facing phenolic groups to sodium and potassium ions are determined and compared.

  DOI：

  10.1021/jo00007a057
• 作为产物：
  描述：

  2,6-二甲基苯酚 在 N-溴代丁二酰亚胺(NBS) 、 N,N-二异丙基乙胺 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 乙二醇二甲醚 为溶剂， 反应 3.0h， 生成 2,6-bis(methoxymethyl)phenol
  参考文献：
  名称：

  CN115959977

  摘要：

  公开号：

文献信息

• NOVEL TETRACARBOXYLIC DIANHYDRIDE, POLYIMIDE RESIN AND METHOD FOR PRODUCING THE SAME, PHOTOSENSITIVE RESIN COMPOSITIONS, PATTERNING PROCESS, METHOD FOR FORMING CURED FILM, INTERLAYER INSULATING FILM, SURFACE PROTECTIVE FILM, AND ELECTRONIC PARTS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20190169211A1

  公开（公告）日：2019-06-06

  The present invention has been made in view of the circumstances herein. An object of the present invention is to provide: a tetracarboxylic dianhydride which can lead to a polyimide usable as a base resin of a photosensitive resin composition capable of forming a fine pattern and obtaining high resolution without impairing excellent characteristics such as mechanical strength and adhesiveness; a polyimide resin obtained by using the tetracarboxylic dianhydride; and a method for producing the polyimide resin. The tetracarboxylic dianhydride is shown by the following general formula (1).

  本发明是基于本文中的情况而作出的。本发明的目的是提供：一种四羧酸二酐，可导致聚酰亚胺，作为感光树脂组合物的基树脂，能够形成细微图案并获得高分辨率，同时不损害优异的特性，如机械强度和粘附性；通过使用该四羧酸二酐获得的聚酰亚胺树脂；以及生产该聚酰亚胺树脂的方法。该四羧酸二酐由以下通用式（1）所示。
• Reactions of lithium aluminium hydride in hydrocarbon solvents. Selective demethylation of some substituted methyl phenyl ethers
  作者：John F. Carroll、Sunanta Kulkowit、M. Anthony McKervey

  DOI：10.1039/c39800000507

  日期：——

  Lithium aluminium hydride in benzene or heptane is an effective reagent for selective demethylation of methyl phenyl ethers having additional ether functions in the immediate vicinity of the reaction site.

  苯或庚烷中的氢化铝锂是一种有效的试剂，用于在反应位点附近使具有附加醚功能的甲基苯基醚选择性脱甲基。
• CONTINUOUS PROCESS FOR CONVERSION OF LIGNIN TO USEFUL COMPOUNDS
  申请人：Chemtex Italia, S.p.A.

  公开号：US20130224816A1

  公开（公告）日：2013-08-29

  This specification discloses an operational continuous process to convert lignin as found in ligno-cellulosic biomass before or after converting at least some of the carbohydrates. The continuous process has been demonstrated to create a slurry comprised of lignin, raise the slurry comprised of lignin to ultra-high pressure, deoxygenate the lignin in a lignin conversion reactor over a catalyst which is not a fixed bed without producing char. The conversion products of the carbohydrates or lignin can be further processed into polyester intermediates for use in polyester preforms and bottles.

  该规格说明披露了一种操作连续过程，用于将木质纤维生物质中的木质素转化为至少一些碳水化合物转化之前或之后。连续过程已经被证明可以创建由木质素组成的混合物，将由木质素组成的混合物提升至超高压，通过一个非固定床催化剂在木质素转化反应器中脱氧木质素，而不产生焦炭。碳水化合物或木质素的转化产品可以进一步加工成聚酯中间体，用于制造聚酯预制体和瓶子。
• Cured film-forming composition
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US10669376B2

  公开（公告）日：2020-06-02

  Provided are: a cured film-forming composition whereby a underlayer film for image formation formed from the composition exhibits high liquid repellency (lyophobicity) and lyophilic/liquid-repellent properties of the underlayer film can be easily changed even when exposed to a low amount of ultraviolet radiation; and a cured film obtained using the composition. The cured film-forming resin composition is characterized by containing: a polymer comprising a structural unit derived from a first monomer having the structure of formula (1) as component (A); a polymer other than component (A), which is a polymer in which the content of fluorine relative to the overall weight of the polymer is lower than in component (A), as component (B); a photoacid generator as component (C); and a solvent. (In the formula, R1 denotes hydrogen or a methyl group, and R2 denotes a fluorine-containing group able to be detached together with the oxygen atom bonded to R2.)

  提供的是一种治愈的成膜组合物，由该组合物形成的图像形成底层膜表现出高液体排斥性（亲疏性），即使暴露于低量紫外辐射下，底层膜的亲疏性和液体排斥性也可以轻松改变；以及使用该组合物获得的治愈膜。该治愈成膜树脂组合物的特点是包含：作为组分（A）的具有来自第一单体的结构单元的聚合物，该单体的结构式为（1）；除组分（A）外的另一种聚合物，其相对于聚合物总重量的含氟量低于组分（A），作为组分（B）；作为组分（C）的光酸发生剂；和溶剂。（在公式中，R1表示氢或甲基基团，R2表示能够与R2键合的氧原子一起脱落的含氟基团。）
• Tetracarboxylic dianhydride, polyimide resin and method for producing the same, photosensitive resin compositions, patterning process, method for forming cured film, interlayer insulating film, surface protective film, and electronic parts
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10919918B2

  公开（公告）日：2021-02-16

  An object of the present invention is to provide: a tetracarboxylic dianhydride which can lead to a polyimide usable as a base resin of a photosensitive resin composition capable of forming a fine pattern and obtaining high resolution without impairing excellent characteristics such as mechanical strength and adhesiveness; a polyimide resin obtained by using the tetracarboxylic dianhydride; and a method for producing the polyimide resin. The tetracarboxylic dianhydride is shown by the following general formula (1).

  本发明的目的是提供：一种四羧酸二酐，它可以产生一种聚酰亚胺，用作感光树脂组合物的基体树脂，能够形成精细图案并获得高分辨率，同时不影响机械强度和粘合性等优异特性；一种通过使用该四羧酸二酐获得的聚酰亚胺树脂；以及一种生产该聚酰亚胺树脂的方法。四羧酸二酐如下通式(1)所示。