3-dimethylamino-2-ethoxy-N,N-dimethyl-prop-2-eneiminium perchlorate | 42784-01-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: 3-dimethylamino-2-ethoxy-N,N-dimethyl-prop-2-eneiminium perchlorate
• 英文别名: 1,3-Bis-(dimethylamino)-2-ethoxytrimethinium perchlorate；N-(3-(dimethylamino)-2-ethoxy-2-propenylidene)-N-methylmethanaminium perchlorate；[3-(Dimethylamino)-2-ethoxyprop-2-enylidene]-dimethylazanium;perchlorate；[3-(dimethylamino)-2-ethoxyprop-2-enylidene]-dimethylazanium;perchlorate
• CAS: 42784-01-0
• 化学式: C₉H₁₉N₂O*ClO₄
• 分子量: 270.713
• InChiKey: PXZUMGOPFIEHOG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.99
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  89.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-dimethylamino-2-ethoxy-N,N-dimethyl-prop-2-eneiminium perchlorate 生成 N-(3-(dimethylamino)-2-ethoxy-2-propenylidene)-N-methylmethanaminium nitrate
  参考文献：
  名称：

  WAGNER, EUGENE R.;MATTHEWS, DONALD P.;BARNEY, CHARLOTTE L.

  摘要：

  DOI：
• 作为产物：
  描述：

  二甲氨基乙醛缩二乙醇 生成 3-dimethylamino-2-ethoxy-N,N-dimethyl-prop-2-eneiminium perchlorate
  参考文献：
  名称：

  WAGNER, EUGENE R.;MATTHEWS, DONALD P.;BARNEY, CHARLOTTE L.

  摘要：

  DOI：

文献信息

• Hypoglycemic
  申请人：Merrell Dow Pharmaceuticals Inc.

  公开号：US04533677A1

  公开（公告）日：1985-08-06

  N-(3-Dialkylamino-2-propenylidene)-N-alkylalkanaminium salts substituted in the 2-position with an ether or thioether and having the formula ##STR1## are active as hypoglycemic agents.

  N-(3-二烷氨基-2-丙烯基亚甲基)-N-烷基烷基胺盐在2位被醚或硫醚取代，并具有以下结构式的化学式##STR1##，作为降血糖药物具有活性。
• Reinvestigation of the jutz synthesis of benzo [e] pyrene and benzo [a] pyrene derivatives from benzanthrene
  作者：Hongmee Lee、Ronald G. Harvey

  DOI：10.1016/s0040-4039(01)82848-3

  日期：1981.1

  Base-catalyzed reactions of benzanthrene with “vinamidinium salts” (2a-c ) followed by thermal electrocyclic ring closure are regiospecific affording only benzo [e] pyrene derivatives, contrary to previous claims.

  与先前的权利要求相反，苯并蒽与“乙烯基ami盐”（2a-c）的碱催化反应，随后进行热电环闭合是区域特异性的，仅提供苯并[e] pyr衍生物。
• 5 Pyrimidinol phosphorus esters, and methods for their manufacture, compositions containing those esters and their use as pesticides
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0023841A2

  公开（公告）日：1981-02-11

  Compounds of the formulas: and wherein R is alkylcycloalkyl or cycloalkylalkyl having 4 to 6 carbon atoms; R' is hydrogen, alkyl or alkylthio of 1 to 3 carbons; R" is alkyl having 1 to 4 carbon atoms; X is oxygen or sulfur; and R"' is alkyl of 1 to 2 carbons, alkoxy, alkylthio or monoalkylamino, each with 1 to 4 carbon atoms, or phenyl. The novel 2-cycloalkylalkyl or alkylcycloalkyl pyrimidinols are used in preparing the phosphate compounds which are highly useful insecticides and are particularly valuable when applied to the soil, but are also useful applied to foliage of crops or trees. Especially good control is obtained of corn rootworm, black cutworm, European corn borer, and nematodes. The compounds are conveniently applied in the form of a composition containing a pesticidal carrier such as an inert solvent or a finely divided inert solid in which case the composition is preferably granulated. An effective application rate is in the range of 0.1 to 5 pounds per acre (0.112 to 5.6 kg/hectare) when soil incorporated, and 0.5 to 2000 ppm for foliar applications.

  的化合物： 和 其中 R 是具有 4 至 6 个碳原子的烷基环烷基或环烷基烷基；R'是氢、1 至 3 个碳原子的烷基或烷基硫基；R "是具有 1 至 4 个碳原子的烷基；X 是氧或硫；R"'是具有 1 至 2 个碳原子的烷基、烷氧基、烷基硫基或单烷基氨基（各具有 1 至 4 个碳原子）或苯基。新型 2-环烷基烷基或烷基环烷基嘧啶醇可用于制备磷酸盐化合物，这些化合物是非常有用的杀虫剂，尤其适用于土壤，但也适用于作物或树木的叶片。对玉米根虫、黑切虫、欧洲玉米螟和线虫的防治效果尤为显著。这些化合物可以方便地以含有杀虫剂载体（如惰性溶剂或细小的惰性固体）的组合物的形式施用，在这种情况下，组合物最好是颗粒状的。土壤施用的有效施用量为每英亩 0.1 至 5 磅（每公顷 0.112 至 5.6 千克），叶面施用的有效施用量为 0.5 至 2000 ppm。
• Synthesis of aminals and aminalacetals of ?-substituted ?-dimethylaminoacrolein
  作者：Zh. A. Krasnaya、T. S. Stytsenko、V. S. Bogdanov

  DOI：10.1007/bf00962665

  日期：1988.1
• Synthesis, Transition Temperatures and Some Physical Properties of Some Low-Melting Smectic C Materials
  作者：Stephen Kelly、Jürg Fünfschilling

  DOI：10.1080/10587259508038688

  日期：1995.2

  As part of a systematic study of the factors affecting the smectic C phase, a dipole (ie, an oxygen atom) was introduced into the middle of one of the (non-polarisable) alkyl chains of a model phenylpyrimidine. A carbon-carbon double bond has also been introduced and the position and nature (E/Z) of the double bond was varied systematically and the resultant effect on the transition temperatures and several other physical properties of relevance to ferroelectric liquid crystal displays (FLCDs) studied. The new phenylpyrimidines exhibit nematic, smectic C and sometimes highly ordered smectic phases for long chain lengths. The effect of the oxygen atom in a central position in the chain is often to reduce the melting point (T-m) more than all the other transition temperatures (eg, below room temperature). This often results in a widening of the smectic C temperature range compared to the corresponding compounds without an oxygen atom in the middle of the chain. Of the alkenyl substituted compounds the ethers with a trans double bond in the 2-position [(E)-2-] exhibit the highest T-Sc values and lowest smectic A transition temperatures. The ethers with a double bond in a terminal position of the alkenyloxy chain exhibit the widest smectic C mesophase ranges (up to 60 degrees C). Of the esters only the (E)-alk-2-enoates exhibit mesomorphic properties.