2t-(4-nitro-phenyl)-ethenesulfonic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2t-(4-nitro-phenyl)-ethenesulfonic acid
• 英文别名: 2t-(4-Nitro-phenyl)-aethensulfonsaeure；(E)-2-(4-nitrophenyl)ethenesulfonic acid
• 化学式: C₈H₇NO₅S
• 分子量: 229.213
• InChiKey: OWKZEBVXYLBHLZ-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  109
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2t-(4-nitro-phenyl)-ethenesulfonic acid 在 磺酰氯 、 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 反应 0.25h， 生成 反式-2-(对硝基苯基)乙烯磺酰氯
  参考文献：
  名称：

  Sulfonylated aminothiazoles as new small molecule inhibitors of protein phosphatases

  摘要：

  Based on a previously identified lead structure, SC-alpha alpha delta9, we have developed a versatile new chemical scaffold that can be readily modified to generate libraries of both Tyr and dual specificity phosphatase inhibitors with reduced molecular weight and lipophilicity. The most potent analogue identified to dare, aminothiazole 8z, inhibits the dual specificity phosphatase Cdc25B with a K-i of 4.6 +/- 0.4 muM and a Hill coefficient of 2. (C) 2001 Elsevier Science Ltd. Ail rights reserved.

  DOI：

  10.1016/s0960-894x(00)00658-2
• 作为产物：
  描述：

  4-硝基苯乙烯 在 dioxane-SO₃ 、 1,2-二氯乙烷 作用下， 生成 2t-(4-nitro-phenyl)-ethenesulfonic acid
  参考文献：
  名称：

  The Reaction of Certain Substituted Styrenes with Dioxane Sulfotrioxide¹

  摘要：

  DOI：

  10.1021/ja01162a014

文献信息

• Completely non-halogenated flame retardant polycarbonate compounds
  申请人：PolyOne Corporation

  公开号：US10100192B2

  公开（公告）日：2018-10-16

  A completely non-halogenated flame retardant polycarbonate compound includes polycarbonate, non-halogenated termini-functional chemical such as vinyl-terminated siloxane and non-halogenated hydride-functional polysiloxane as non-halogenated drip suppressant ingredients which react in the presence of heat to form a drip suppressant adduct, and potassium 3-(phenylsulfonyl)benzenesulfonate as a non-halogenated char former. The compound can achieve a UL 94 rating of V-0 at a thickness of at least 3.2 mm and otherwise achieves no dripping/igniting of the cotton indicator during that test.

  一种完全非卤化阻燃聚碳酸酯化合物包括聚碳酸酯、作为非卤化滴漏抑制剂成分的非卤化端基官能团化学品（如乙烯基端基硅氧烷和非卤化氢化物官能团聚硅氧烷）（它们在热的作用下反应形成滴漏抑制剂加合物）以及作为非卤化炭前剂的 3-(苯磺酰基)苯磺酸钾。该化合物在厚度至少为 3.2 毫米时可达到 UL 94 V-0 级，并且在该测试中棉花指示剂不会滴落或点燃。
• Unsaturated Sulfonic Acids. I. Diels—Alder Reactions¹
  作者：Christian S. Rondestvedt、James C. Wygant

  DOI：10.1021/ja01156a090

  日期：1951.12
• Unsaturated Sulfonic Acids. III. Bromination and Brominolysis of p-Substituted 2-Phenylethene-1-sulfonic Acid Derivatives¹
  作者：Christian S. Rondestvedt、James C. Wygant

  DOI：10.1021/ja01631a053

  日期：1954.1
• COMPLETELY NON-HALOGENATED FLAME RETARDANT POLYCARBONATE COMPOUNDS
  申请人：PolyOne Corporation

  公开号：EP3008128A1

  公开（公告）日：2016-04-20
• PHOSPHAZENE FLAME RETARDANT POLYCARBONATE COMPOUNDS
  申请人：POLYONE CORPORATION

  公开号：US20160272812A1

  公开（公告）日：2016-09-22

  A non-halogenated flame retardant polycarbonate compound is disclosed. The compound comprises a polycarbonate, a non-halogenated, non-migrating, non-plasticizing flame retardant adduct. The compound can achieve a UL 94 rating of V-0 at a thickness of at least 3.2 mm and otherwise achieves no dripping/igniting of the cotton indicator during that test. The adduct is formed from an allyl-functional phenoxyphosphazene and a hydride-functional polysiloxane.