4-芘-1-基苯胺 | 87393-65-5

• 物质功能分类: 材料化学 - 配体
• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 中文名称: 4-芘-1-基苯胺
• 英文名称: 1-(p-aminophenyl)pyrene
• 英文别名: 4-(Pyren-1-YL)aniline；4-pyren-1-ylaniline
• CAS: 87393-65-5
• 化学式: C₂₂H₁₅N
• 分子量: 293.368
• InChiKey: USYIOAHBHWKOFH-UHFFFAOYSA-N

物化性质

• 沸点：
  501.2±19.0 °C(Predicted)
• 密度：
  1.278±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-芘-1-基苯胺 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 生成 1-(对氨基苯基)芘盐酸盐
  参考文献：
  名称：

  Photophysical studies on 1-(p-aminophenyl)pyrene. Characterization of an intramolecular charge-transfer state with application to proton-transfer dynamics

  摘要：

  DOI：

  10.1021/ja00293a012
• 作为产物：
  描述：

  芘 在 盐酸 、 sodium hydroxide 、 tin 、 sodium acetate 、 sodium nitrite 作用下， 以 乙醇 、 二氯甲烷 、 水 为溶剂， 反应 1.25h， 生成 4-芘-1-基苯胺
  参考文献：
  名称：

  Photophysical studies on 1-(p-aminophenyl)pyrene. Characterization of an intramolecular charge-transfer state with application to proton-transfer dynamics

  摘要：

  DOI：

  10.1021/ja00293a012

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE AND MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：INOUE Tetsuya

  公开号：US20080071122A1

  公开（公告）日：2008-03-20

  It is an object of the present invention to provide a novel compound useful as a constituent of an organic EL element and the use of the compound permits the realization of a highly practical organic EL element whose driving voltage is substantially low and which has a low leakage current. Accordingly, the present invention herein provides a fluoranthene compound represented by the following general formula (1): A-L-B  (1) wherein A and B each represent a monovalent group having a fluoranthene structure represented by the following general formula (2), provided that A is linked to the group L present in the general formula (1), at the carbon atom selected from those specified by the numerical values of 7 to 10 appearing in Formula (2) and that B is linked to the group L present in Formula (1), at the carbon atom selected from those specified by the numerical values of 1 to 6 appearing in Formula (2): wherein L is a member selected from the group consisting of a single bond, substituted or unsubstituted arylene groups each having 6 to 40 carbon atoms, divalent groups derived from substituted or unsubstituted arylamines each having 6 to 40 carbon atoms, divalent groups derived from substituted or unsubstituted heterocyclic rings each having 3 to 40 carbon atoms and substituted or unsubstituted ethenylene groups.

  本发明的目的是提供一种作为有机EL元件组分有用的新型化合物，该化合物的使用使得可以实现驱动电压实质上较低且具有低泄漏电流的高度实用的有机EL元件。因此，本发明在此提供一种由下述通用式（1）表示的芴烯化合物： A-L-B  (1) 其中A和B分别表示具有由下述通用式（2）表示的芴烯结构的一价基团，前提是A与通用式（1）中存在的L基团连接，在通用式（2）中出现的数值为7至10的碳原子中选择的碳原子上，并且B与通用式（1）中存在的L基团连接，在通用式（2）中出现的数值为1至6的碳原子中选择的碳原子上： 其中L是从以下组成的群体中选择的成员：单键，具有6至40个碳原子的取代或未取代芳基基团，由具有6至40个碳原子的取代或未取代芳胺衍生的二价基团，由具有3至40个碳原子的取代或未取代杂环戒指衍生的二价基团，以及取代或未取代乙烯基团。
• AMINODIBENZOFLUORENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：TAKASHIMA Yoriyuki

  公开号：US20090267491A1

  公开（公告）日：2009-10-29

  A novel compound which is useful as a constitutional component for an organic EL device is provided by an aminodibenzofluorene derivative comprising (A) at least one dibenzofluorene structure and (B) at least one amino group in a molecule, a material for an organic electroluminescence (EL) device comprising the same, a light emitting material for an organic EL device, a light emitting organic solution, an organic EL device in which an organic compound layer comprising a single layer or plural layers including at least a light emitting layer is interposed between a pair of electrodes, wherein at leas one layer in the organic compound layer described above contains at least one kind of the aminodibenzofluorene derivative described above and an equipment comprising the same. A practical organic EL device which has a low operating voltage, a long lifetime and a high current efficiency and which provides blue light emission having an excellent color purity is materialized by using the above compound.

  提供了一种新型化合物，可作为有机EL器件的构成组分，该化合物由包含（A）至少一个二苯并芴结构和（B）至少一个氨基团的氨基二苯并芴衍生物组成，一种用于有机电致发光（EL）器件的材料，一种用于有机EL器件的发光材料，一种发光有机溶液，一种有机EL器件，其中在一对电极之间夹设了包括至少一个发光层的单层或多层的有机化合物层，上述有机化合物层中的至少一层含有上述氨基二苯并芴衍生物中的至少一种，以及包括该化合物的设备。通过使用上述化合物，可以实现具有低工作电压、长寿命和高电流效率的实用有机EL器件，并提供具有优异色纯度的蓝光发射。
• Electronically Coupled 2D Polymer/MoS₂ Heterostructures
  作者：Halleh B. Balch、Austin M. Evans、Raghunath R. Dasari、Hong Li、Ruofan Li、Simil Thomas、Danqing Wang、Ryan P. Bisbey、Kaitlin Slicker、Ioannina Castano、Sangni Xun、Lili Jiang、Chenhui Zhu、Nathan Gianneschi、Daniel C. Ralph、Jean-Luc Brédas、Seth R. Marder、William R. Dichtel、Feng Wang

  DOI：10.1021/jacs.0c10151

  日期：2020.12.16

  2DP layers reveals enhancement of the 2DP photoluminescence by two orders of magnitude in ultrathin sheets and an unexpected thickness-dependent modulation of the ultrafast excited state dynamics in the 2DP/MoS2 heterostructure. These results provide fundamental insight into the electronic structure of 2DPs and present a route to tune emergent quantum phenomena in 2DP hybrid van der Waals heterostructures

  电子耦合二维异质结构中出现的量子现象是下一代光学、电子和量子信息应用的核心。定制耦合异质结构中的电子带隙将允许控制这种现象，并且是重要的研究兴趣的主题。二维聚合物 (2DP) 提供了一条通过选择分子成分来定制能带结构的令人信服的途径。然而，尽管具有合成灵活性和电子设计的前景，但形成电子耦合二维异质结构的 2DP 的制造仍然是一个突出的挑战。在这里，我们报告了电子耦合半导体 2DP/2D 过渡金属二硫化物范德瓦尔斯异质结构的合理设计和优化合成，展示了高度结晶和取向的 2DP 薄膜的直接剥离到几纳米，并提出了 2DP/MoS2 异质结构的第一个厚度依赖性研究。对 2DP 层的控制揭示了超薄片中 2DP 光致发光增强了两个数量级，以及 2DP/MoS2 异质结构中超快激发态动力学的意外厚度依赖调制。这些结果提供了对 2DP 电子结构的基本见解，并提出了调整 2DP 混合范德瓦尔斯异质结构中出现的量子现象的途径。对
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：HOSOKAWA Chishio

  公开号：US20080004445A1

  公开（公告）日：2008-01-03

  To attain an organic electroluminescence device having a long lifetime and high luminous efficiency, and is capable of emitting blue light having a high color purity, and an aromatic amine derivative for realizing the device, the present invention provides an aromatic amine derivative having a specific structure, and an organic electroluminescence device including an organic thin film layer composed of one or more layers including at least a light emitting layer and interposed between a cathode and an anode, in which at least one layer of the organic thin film layer contains the aromatic amine derivative alone or as a component of a mixture.

  为了获得具有长寿命和高发光效率的有机电致发光器件，并且能够发射具有高色纯度的蓝光，并且为了实现该器件，本发明提供了一种具有特定结构的芳香胺衍生物，以及包括至少一个发光层的有机薄膜层的有机电致发光器件，该有机薄膜层由一个或多个层组成，介于阴极和阳极之间，其中有机薄膜层的至少一层仅含有芳香胺衍生物或作为混合物成分。
• FLUORANTHENE COMPOUND, ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME, AND SOLUTION CONTAINING ORGANIC ELECTROLUMINESCENCE MATERIAL
  申请人：Takashima Yoriyuki

  公开号：US20090015144A1

  公开（公告）日：2009-01-15

  A fluoranthene compound with a specified asymmetric structure; an organic EL device which is composed of one or more organic compound layers including at least one emitting layer sandwiched between a pair of electrodes, wherein at least one of the organic compound layers contains at least one kind of the fluoranthene compound; and a solution containing a material for the organic EL which is composed of the fluoranthene compound as the material for the organic EL and a solvent. An organic electroluminescence (EL) device having a superior luminance of light emission, an enhanced efficiency of light emission, and a prolonged lifetime and a compound realizing the device are provided.

  提供一种具有特定不对称结构的芴类化合物；一种有机EL器件，其由至少一个发射层夹在一对电极之间的一个或多个有机化合物层组成，其中至少一个有机化合物层包含至少一种芴类化合物；以及含有作为有机EL材料的芴类化合物和溶剂的溶液。提供一种具有优异发光亮度、增强发光效率和延长寿命的有机电致发光（EL）器件及实现该器件的化合物。