4,4'-dibutyl-benzophenone | 64357-54-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-dibutyl-benzophenone
• 英文别名: 4,4'-Dibutyl-benzophenon；Bis-(4-butyl-phenyl)-methanone；bis(4-butylphenyl)methanone
• CAS: 64357-54-6
• 化学式: C₂₁H₂₆O
• 分子量: 294.437
• InChiKey: OVFVXQIINPCEFU-UHFFFAOYSA-N

物化性质

• 沸点：
  258-262 °C(Press: 26 Torr)
• 密度：
  0.984±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4,4'-dibutyl-benzophenone 在 aluminum isopropoxide 、 异丙醇 作用下， 生成 <2-Dimethylaminoaethyl>-<4.4'-dibutyl-benzhydryl>-aether
  参考文献：
  名称：

  Muraoka,M. et al., Chemical and pharmaceutical bulletin, 1960, vol. 8, p. 860 - 866

  摘要：

  DOI：
• 作为产物：
  描述：

  草酰氯 、 丁苯 在 二硫化碳 、 三氯化铝 作用下， 生成 4,4'-dibutyl-benzophenone
  参考文献：
  名称：

  Fahim, Journal of the Chemical Society, 1949, p. 520

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING ALPHA-ACYLOXYCARBONYL COMPOUND AND NOVEL ALPHA-ACYLOXYCARBONYL COMPOUND
  申请人：Ishihara Kazuaki

  公开号：US20120323014A1

  公开（公告）日：2012-12-20

  A method for producing an α-acyloxycarbonyl compound of the present invention includes performing an intermolecular reaction between a carboxylic acid and a carbonyl compound selected from the group consisting of ketones, aldehydes, and esters, which have a hydrogen atom at the α-position, using a hydroperoxide as an oxidizer and an iodide salt as a catalyst precursor, thereby introducing an acyloxy group derived from the carboxylic acid into the α-position of the carbonyl compound.

  本发明提供了一种制备α-酰氧基碳酰化合物的方法，包括使用过氧化氢作为氧化剂和碘化物盐作为催化剂前体，通过在羧酸和酮、醛或酯的α位含有氢原子的羰基化合物之间进行分子间反应，从而将来自羧酸的酰氧基团引入到羰基化合物的α位。
• Organocatalytic Enantioselective Vinylogous Pinacol Rearrangement Enabled by Chiral Ion Pairing
  作者：Hua Wu、Qian Wang、Jieping Zhu

  DOI：10.1002/anie.201609911

  日期：2016.12.5

  An enantioselective pinacol rearrangement of functionalized (E)‐2‐butene‐1,4‐diols was developed. In the presence of a catalytic amount of a chiral BINOL‐derived N‐triflyl phosphoramide, these 1,4‐diols rearranged to β,γ‐unsaturated ketones in excellent yields and enantioselectivities. The formation of a chiral ion pair between the intermediary allylic cation and the chiral phosphoramide anion was

  开发了功能化（E）-2-丁烯-1,4-二醇的对映选择性频哪醇重排。在催化量的手性BINOL衍生的N - triflyl磷酰胺的存在下，这些1,4-二醇以优异的收率和对映选择性重排为β，γ-不饱和酮。假定在中间烯丙基阳离子和手性磷酰胺阴离子之间形成手性离子对是造成高效手性转移的原因。这些手性结构单元进一步转化为对映体富集的多取代的四氢呋喃和四氢萘衍生物。
• Synthesis of olefins from ketones using a bis(substituted alumino) substituted methane
  申请人：TEXAS ALKYLS, INC.

  公开号：EP0316979A1

  公开（公告）日：1989-05-24

  Ketones are alkylenated to form the corresponding olefin by reaction with a bis(substituted alumino)­substituted methane, e.g., in the form of its dietherate.

  酮通过与双（取代铝）取代甲烷（如二醚酸盐形式）反应进行烷基化，生成相应的烯烃。
• Inverse phase polymerization
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0336874A1

  公开（公告）日：1989-10-11

  It is sometimes advantageous to disperse crystalline polymers throughout rubbery elastomers. For instance, the cold flow characteristics and green strength of polydiene rubbers can be improved by dispersing syndiotactic-1,2-polybutadiene therein. This invention discloses a process for preparing a highly dispersed blend of a crystalline polymer in a rubbery elastomer which comprises (1) polymerizing at least one diene monomer in an organic solvent under solution polymerization conditions to form a polymer cement of the rubbery elastomer in the organic solvent, (2) polymerizing additional monomers in the polymer cement into the crystalline polymer to form a rubbery cement having the crystalline polymer dispersed therein, and (3) recovering the highly dispersed blend of the crystalline polymer in the rubbery elastomer from the organic solvent in the rubber cement.

  有时，将结晶聚合物分散到橡胶弹性体中会带来好处。例如，通过在聚二烯橡胶中分散辛二烯-1,2-聚丁二烯，可以改善聚二烯橡胶的冷流特性和生坯强度。本发明公开了一种在橡胶弹性体中制备高度分散的结晶聚合物混合物的工艺，该工艺包括 (1) 在溶液聚合条件下，在有机溶剂中聚合至少一种二烯烃单体，在有机溶剂中形成橡胶弹性体的聚合物胶结物、(2) 将聚合物胶结物中的其他单体聚合到结晶聚合物中，形成其中分散有结晶聚合物的橡胶胶结物，以及 (3) 从橡胶胶结物中的有机溶剂中回收橡胶弹性体中高度分散的结晶聚合物混合物。
• High modulus rubber composition
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0434596A2

  公开（公告）日：1991-06-26

  It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for preparing high modulus rubber compositions. By utilizing this technique, high modulus can be attained without sacrificing other properties, such as processability. The subject invention more specifically relates to a process for preparing a high modulus rubber composition which comprises: (1) polymerizing at least one diacid or diacid halide with at least one member selected from the group consisting of diols and diamines in a polymer cement of a rubbery elastomer under conditions which result in the formation of a rubber cement having a polyester or a polyamide dispersed therein; and (2) recovering the high modulus rubber composition from the rubber cement. It is highly desirable to make the high modulus rubber composition by interfacial polymerization.

  人们希望提高各种应用中的橡胶模量。本发明公开了一种制备高模量橡胶组合物的技术。利用该技术，可在不牺牲其他性能（如加工性能）的情况下获得高模量。本发明更具体地涉及一种制备高模量橡胶组合物的工艺，该工艺包括：(1) 在橡胶弹性体的聚合物胶结物中，将至少一种二元酸或二元酸卤化物与至少一种选自由二元醇和二元胺组成的组中的成员聚合，聚合条件是形成一种橡胶胶结物，其中分散有聚酯或聚酰胺；(2) 从橡胶胶结物中回收高模量橡胶组合物。通过界面聚合制造高模量橡胶组合物是非常理想的。