(S)-4-methyl-1-nonanol | 118665-25-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (S)-4-methyl-1-nonanol
• 英文别名: (4S)-4-methylnonan-1-ol
• CAS: 118665-25-1
• 化学式: C₁₀H₂₂O
• 分子量: 158.284
• InChiKey: HECVGHIJHFNAIL-JTQLQIEISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (S)-4-methyl-1-nonanol 生成 (S)-4-methylnonanoic acid
  参考文献：
  名称：

  TANAKA, YUICHI;HONDA, HIROSHI;OHSAWA, KANJU;YAMAMOTO, IZURU, NIXON NOYAKU GAKKAJSI, 14,(1989) N, S. 197-202

  摘要：

  DOI：
• 作为产物：
  描述：

  methyl 3-(R)-methyl-5-hydroxypentanoate 在 lithium aluminium tetrahydride 、 magnesium 、 lithium bromide 作用下， 以 吡啶 、 乙醚 、 丙酮 为溶剂， 反应 20.5h， 生成 (S)-4-methyl-1-nonanol
  参考文献：
  名称：

  Carpita, Adriano; Magistris, Elisabetta De; Rossi, Renzo, Gazzetta Chimica Italiana, 1989, vol. 119, # 2, p. 99 - 106

  摘要：

  DOI：

文献信息

• SN2′ Alkylation of Chiral Allylic CyanohydrinO-Phosphates with Organocuprates
  作者：Alejandro Baeza、Carmen Nájera、José M. Sansano

  DOI：10.1002/ejoc.200600822

  日期：2007.3

  This work has been supported by the DGES of the Spanish Ministerio de Educacion y Ciencia (MEC) (CTQ2004-00808/BQU), the Generalitat Valenciana (CTIOIB/2002/320, GRUPOS03/134 and GV05/144) and the University of Alicante.

  这项工作得到了西班牙教育部长和 Ciencia (MEC) (CTQ2004-00808/BQU)、Generalitat Valenciana (CTIOIB/2002/320、GRUPOS03/134 和 GV05/144) 和阿利坎特大学的 DGES 的支持.
• Levene; Marker, Journal of Biological Chemistry, 1931, vol. 91, p. 95
  作者：Levene、Marker

  DOI：——

  日期：——
• Pheromone synthesis. Part 258. Synthesis of the enantiomers of the beetle pheromones ethyl 4-methylheptanoate, 4-methyloctanoic acid and 4-methyl-1-nonanol, and HPLC analysis of their derivatives to determine their enantiomeric purities
  作者：Kenji Mori、Kazuaki Akasaka

  DOI：10.1016/j.tetasy.2016.01.014

  日期：2016.3

  The enantiomers of citronella) have been converted into the enantiomers of the following beetle Pheromones: ethyl 4-methylheptanoate (produced by male Nicrophorus vespilloides), 4-methyloctanoic acid (produced by male Oryctes elegans), and 4-methyl-1-nonanol (produced by female Tenebrio molitor). The enantiomeric purities of the synthetic pheromones were determined by HPLC analysis of the corresponding acids after derivatization with Ohrui's reagent [(S)-1-(anthracene-2,3-dicarboximido)-2-propanol]. The enantiomers of 4-methyl-1-nonanol could also be analyzed employing another Ohrui's reagent [(1S,2S)-2-(naphthalene-2,3-dicarboximido)cyclohexane-l-carboxylic acid]. (C) 2016 Elsevier Ltd. All rights reserved.
• CARPITA, ADRIANO;DE, MAGISTRIS ELISABETTA;ROSSI, RENZO, GAZZ. CHIM. ITAL., 119,(1989) N, C. 99-105
  作者：CARPITA, ADRIANO、DE, MAGISTRIS ELISABETTA、ROSSI, RENZO

  DOI：——

  日期：——
• US9012500B2
  申请人：——

  公开号：US9012500B2

  公开（公告）日：2015-04-21